WETLAND BOUNDARIES IN THE NEW JERSEY PINELANDS: ECOLOGICAL RELATIONSHIPS AND DELINEATION1

Wetland protection regulations and guidelines often require the delineation of precise wetland boundaries on a case-by-case basis. In this study, conducted in the New Jersey Pinelands, an ecological characterization of vegetation composition, soil and hydrologic relationships along upland to wetland Pinus rigida - dominated transittions provided the basis for a multiparameter approach to wetland boundary delineation. The transitional data set was analyzed by direct gradient analysis, cluster analysis and ordination. It is concluded that vegetation composition can be a principal factor in delineating wetland boundaries along natural upland to wetland transitions. However, where distinct vegetation changes are not observed, a feature of our study sites, a multiparameter approach should be used.     

Effect of the Pretreatment with UV and Gamma Radiations on the Modification of Plywood Surface by Photocuring with Epoxy Acrylate

In order to further improve the physical properties of plywood surface that was pretreated with UV and Gamma radiation at different radiation intensities before photocuring. After pretreatment with radiation the plywood surface was coated with different prepared formulations containing epoxyacrylate (EA-1020) as an oligomer, difunctional monomers such as tripropylene glycol diacrylate (TPGDA), 2-hexadioldiacrylate (HDDA), Ethylene Glycol dimethacrylate (EGDMA) and trifunctional monomer trimethyl propen triacrylate (TMPTA) with photoinitiator Darocur 1664. Thin polymer films were prepared on glass plate with these formulated solutions and cured under UV radiation. Pendulum hardness (PH) and gel content of the film were studied for selecting the formulations as top coat and as base coat. The polished plywood surface was coated with selected formulation and cured under UV radiation. Various rheological properties of UV cured plywood surface such as pendulum hardness, scratch hardness, microgloss, adhesion strength, percentage chipped off area and abrasion resistance were studied.     

Action and composition of the alarm pheromone of the bedbugCimex lectularius L.

The Science of Nature -     

Vertical and horizontal movement of phorate and its metabolites in field soil under cropped and uncropped conditions

Vertical and horizontal movement of phorate and its metabolites in field microplots was studied under cropped and uncropped conditions in winter and summer seasons. Phorate bands were placed 2.5 cm below the soil surface and were subject to leaching by irrigation and rain. The crops used were peas, in winter, and maize, in summer. Periodic analyses of samples showed that total phorate residues (TPR) were significantly more mobile under cropped conditions than in fallow conditions in both seasons. The peak concentration depth remained at 7.5 cm throughout most of the experimental period. Irrespective of treatments, downward movement of TPR was greater in winter. Horizontal movement of TPR was greater under cropped conditions in summer. Differences in lateral mobility were insignificant in two seasons under cropped conditions. However, under uncropped conditions, horizontal movement was relatively more in the summer season. TPR persisted in the soil for 120 and 90 days in winter and summer, respectively. The TPR persistence was almost the same in the two crops. Maize and pea plants at harvest had residues below the legal health tolerance limit. Half-life values of TPR in maize and pea plants were 38 and 42 days, respectively.     

The effects of crude and fuel oils on the growth, chlorophyll 'a' content and dry matter production of a green alga Scenedesmus quadricauda (Turp.) bréb

The growth of Scenedesmus quadricauda algae in a batch culture was examined in the presence of crude oil and fuel oil, added to the cultivation medium in the form of a water-soluble fraction (WSF), water extract (WE) and oil-water dispersion (OWD). On applying various concentrations of oils, a decrease in the number of cells, dry matter and chlorophyll 'a' production, with respect to the cell population, was observed. The extent of this decrease depended on the kind and concentration of the soluble and dispersed hydrocarbon fractions and on the proportions in which these occurred in the culture medium. On the other hand, the water extracts of both oils stimulated dry mass and chlorophyll 'a' content with respect to a single cell. This effect was accompanied by increased size of the algal cells. The WSF, WE and OWD of fuel oil, prepared from 200, 50 and 1 cm(3) of oil per dm(3) of BBM medium, respectively, had a similar inhibitory effect, which points to the dominant role of oil dispersion in the reduction of algal growth. Chemical analysis of the water extracts of fuel oil revealed the presence of 35 hydrocarbons of various kinds, mainly n-alkanes and polycyclic aromatic hydrocarbons.     

Chromium occurrence in the environment and methods of its speciation

This article includes a survey of chromium (Cr) occurrence in different environmental compartments, its pathways in the environment and the cross-sectional presentation of Cr speciation methods against the background of Cr chemistry. The aim of the article is to demonstrate that knowledge of interconversion processes between different Cr forms is necessary to understand its behaviour and role in the environment, in addition to enabling reliable Cr speciation analysis to be performed. The current methods of Cr speciation are presented, characterized and their usefulness discussed. These must rely on superior separation and detection capabilities since Cr in environmental compartments is mostly at trace or ultra-trace level. The need for using unique techniques of sampling, storage, handling and separation for Cr speciation is documented.     

Sustainable recovery of nickel from spent hydrogenation catalyst: economics, emissions and wastes assessment

Economic viability, carbon emission profile and waste management associated with nickel recovery from spent hydrogenation catalysts are studied from sustainability perspectives. The purpose is to determine and compare the economic, environmental and social implications of different nickel reclamation techniques towards clean, safe and sustainable recovery of nickel from spent catalysts. Sustainability evaluation models are formulated to understand and improve the cost, carbon footprint and resource efficiency of a closed-loop nickel recovery process. The economic viability of the process highly depends on market values of recovered nickel and the production batch size. At a selling price higher than $12.60/kg, an operation with a batch size as small as 50 kg/batch would be profitable. The current rising nickel market, at ∼$18-24/kg, favors recovery operations although it also casts a dual effect on production costs. About 73-82% of carbon emission of the process is from the use of energy in the recovery operation. Energy efficiency is therefore identified as the most critical factor to improve the carbon footprint. The closed-loop process also improves resource use efficiency and minimizes toxic waste generation.     

Determination of the specific alpha activity of thick sources with a large area ZnS(Ag) scintillation detector

A method for determining the specific alpha activity of thick sources using a large area ZnS(Ag) scintillation detector is presented. In this method a quadratic relationship between the detector response and window thickness is assumed. This method provides a quick estimation of alpha activity in the sample, so it is an indicative method. The aim of this experimental work is to approve theoretical assumption and to develop a standard routine method for absolute alpha measurements of thick contaminated environmental sources. For this purpose reference material U(3)O(8) and spiked standards of soil were used. Measurements of contaminated soil samples from south Serbia showed the practical application of this method.