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121.
Li Yongmei Li Wenshu Gu Guowei 《Frontiers of Environmental Science & Engineering in China》2007,1(4):493-497
Batch experiments were carried out to investigate the promotive effect of pyridine on indole degradation under denitrifying
conditions. The seed sludge was obtained from a local coal-coking wastewater treatment facility and was acclimated in the
laboratory. Indole and pyridine were supplemented to the synthetic wastewater at different ratios. The optimum ratio of chemical
oxygen demand (COD) to nitrate (C/N) was 8.4–8.9 for both denitrification and indole and pyridine degradation. At a temperature
of 28°C and pH of 7.0–7.5, the nitrate reductase activity (NRA) was in the best state. The addition of pyridine could promote
NRA and the degradation of indole. When the initial concentration of indole was 150 mg/L, the concentration ratio of indole
to pyridine was in the range of 1–10. Under optimum C/N conditions, the degradation of indole could be described with pseudo-zero-order
kinetics. There was no accumulation of nitrite during the reaction. When the concentration ratio of pyridine to indole was
less than 0.25 with an increase in the pyridine proportion, there were more significant augment rates for NRA and the degradation
of indole than the situation when the concentration ratio was more than 0.25.
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Translated from Environmental Science, 2006, 27(2): 300–304 [译自: 环境科学] 相似文献
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不同地域天然伊利石表面酸碱特性的比较 总被引:3,自引:2,他引:3
利用电位滴定技术和恒定容量表面络合模式表征不同来源天然伊利石的表面酸碱性质。鉴于固体基质在酸量滴定过程中发生溶解,相应的滴定上清液被视为体系空白。考虑到水解铝、硅酸和伊利石表面活性位之间的表面络合或沉淀反应,提出两种表面质子反应模型。对其中的特例,还考虑了表面离子交换反应。模拟程序的拟合结果显示两种模型对水解伊利石体系的滴定行为均可获得满意的描述。相的的表面固有酸度常数表明样品的酸碱性质之间存在一些共性。 相似文献
125.
为掌握致酸大气污染物SO2 和NOx 的空间浓度分布,并探讨上述污染物扩散、迁移和传输规律,进而研究其在酸性降水形成过程中的作用,在“八五”期间酸性降水的研究中,针对中国华北地区城市和工业集中以及SO2 和NOx 等酸性大气污染物排放量大的特点,以石家庄及其以东地区为飞行区域,进行了华北地区冬季空中SO2 和NOx 污染特征的航空测量。通过测定发现在华北地区1-5 km 左右的空中存在着SO2 和NOx 高浓度污染空域,同时SO2 存在着高浓度汇集区 相似文献
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Recent drinking water regulations have lowered the disinfection by-product standards as well as added new disinfection by-products for regulation. Natural organic matter (NOM) plays a major role in the formation of undesirable organic by-products following disinfection/oxidation of drinking water. It is suspected that most precursors to disinfection by-products are humic, although nonhumic substances are also suspected of contributing to these by-products. Many of the disinfection by-products have adverse health effects in humans (i.e., carcinogenic or mutagenic effects). The primary chlorinated disinfection by-products of concern include trihalomethanes, haloacetic acids, and haloacetonitrile. Fluorescence spectroscopy was used to study humic and fulvic acids. The two fractions of humic substances, humic and fulvic acids, were characterized by a double-peak phenomena in an overlapping fluorescing region. Disinfection by-product formation potentials of humic and fulvic acids have been correlated with total organic carbon, UV absorbance at 254 nm, specific absorbance and fluorescence. River humic and fulvic acid was found to have the highest reactivity to disinfection by-product formation as compared to soil and peat humic and fulvic acid. Fluorescence spectroscopy has shown to be a rapid and predictive tool for disinfection by-products formation potential of humic and fulvic acids. 相似文献
130.
Land use as a mitigation strategy for the water-quality impacts of global warming: a scenario analysis on two watersheds in the Ohio River Basin 总被引:4,自引:0,他引:4
This study uses an integrative approach to study the water-quality impacts of future global climate and land-use changes. In this study, changing land-use types was used as a mitigation strategy to reduce the adverse impacts of global climate change on water resources. The climate scenarios were based on projections made by the Intergovernmental Panel on Climate Change (IPCC) and the United Kingdom Hadley Centre's climate model (HadCM2). The Thornthwaite water-balance model was coupled with a land-use model (L-THIA) to investigate the hydrologic effects of future climate and land-use changes in the Ohio River Basin. The land-use model is based on the Soil Conservation Service's curve-number method. It uses the curve number, an index of land use and soil type, to calculate runoff volume and depth. The ArcView programming language, Avenue, was used to integrate the two models into a geographic information system (GIS). An output of the water-balance model, daily precipitation values adjusted for potential evapotranspiration, served as one of the inputs into the land-use model. Two watersheds were used in the present study: one containing the city of Cincinnati on the main stem of the Ohio River, and one containing the city of Columbus on a tributary of the Ohio River. These cities represent two major metropolitan areas in the Ohio River Basin with different land uses experiencing different rates of population growth. The projected hypothetical land-use changes were based on linear extrapolations of current population data. Results of the analyses indicate that conversion from agricultural land use to low-density residential land use may decrease the amount of surface runoff. The land-use practices which generate the least amount of runoff are forest, low-density residential, and agriculture; whereas high-density residential and commercial land-use types produce the highest runoff. The hydrologic soil type present was also an important factor in determining the amount of runoff and non-point-source pollution. A runoff-depth matrix and total nitrogen matrix were created for Cincinnati and Columbus to describe possible land-use mitigation measures in response to global climate change. The differences in Cincinnati and Columbus were due to differences in geographic location, air temperature, and total runoff. The results of this study may be useful to planners and policy makers for defining the possible impacts of future global climate and land-use changes on water resources. 相似文献