某装置海洋环境下腐蚀失效分析及控制措施研究

目的 解决采用ZL205A制造的某装置在海洋环境下的腐蚀失效问题.方法 分析装置所处的海洋浪花飞溅区的使用环境,对腐蚀原因与机理进行深入查找、研究.针对腐蚀原因,制定针对性的腐蚀控制措施,并通过试验予以验证.结果 装置腐蚀失效的主要原因为在海洋高盐、高湿的使用环境下,防腐蚀设计不足,防腐措施不到位,产生了电偶腐蚀、缝隙腐蚀、点蚀、晶间腐蚀、应力腐蚀等.制定的腐蚀控制措施主要有更换耐腐蚀性能较好的ZL114A材料、采用异种金属隔离、完善结构设计与加强过程控制、加强表面涂覆和维护保养等4方面.验证试验表明,采用综合防护措施的ZL114A试样腐蚀轻微,防腐效果良好,而采用原技术状态的ZL205A试样,腐蚀严重,防腐效果差.结论 采取综合防护措施的ZL114A装置在海洋环境下的耐腐蚀性显著提高,实际使用效果良好.     

杂多化合物脱硫化氢动力学研究

在双搅拌、无浓度梯度气液反应器中考察了磷钼杂多化合物吸收H2S过程的宏观动力学行为.结果表明,吸收剂浓度提高,脱硫效果增强,当磷钼酸钠浓度超过6.25×10-3mol/L后,单一与复配体系对H2S的吸收速率均趋恒定.从工业操作角度来看,6.25×10-3mol/L是适宜的操作浓度温度提高,吸收效果略有降低,但变化幅度不大,实际操作温度可选择常温;进气H2S浓度提高,吸收效果增强.两种脱硫体系中,以复配体系脱硫性能为优.实验测得25℃下反应器中H2S的气、液相传质系数分别为:kGH-2S =8.201×10-10kmol/(m2.s.Pa),kLH-2S=3.440×10-4m/s.吸收反应对磷钼酸钠及硫化氢的反应级数分别为0.339与1.055.     

国家机动车排污控制管理数据库系统

介绍了“国家机动车排污控制管理系统”数据库的研制、特点及使用方法。该数据库存储了大量的城市环境概况、机动车排放因子、排放标准、燃油标准和排放控制对策等信息，能系统、准确的提供国家级相关数据及法律依据，使各级环保部门和政府决策部门能迅速、准确地掌握全国或某城市的有关机动车的静态或动态的污染排放综合情况     

铝、铁共聚作用的化学特征及晶貌研究

通过对铝，铁水解共聚物的合成制备及其水解共聚合过程电位滴定的研究，并通过扫描电镜对其共聚物样品的晶貌观测，ｎＡｌ／ｎＦｅ的点能谱及结构组成的红外光谱测定，对铝铁共聚作用的化学特征及其晶形貌象，共聚作用进行了研究及讨论，为深入研究铝无机共聚溶液体系化学形态组成及其絮凝剂的提供了的基础实验依据。     

珠江三角洲一些城市水体中微量有机氯化合物的初步分析

采用较快速、简便的方法，用ＧＣ／ＥＣＤ对珠江三角洲几个城市中的污水及深圳河，大沙河中的有机氯化合物进行了初步探查及半定量分析。结果表明，几种有机氯农药尽管已停止生产多年，但在污水及河水中仍有残留，其中ＤＤＴ及其衍生物ＤＤＥ含量在０．０２－０．５０μｇ／Ｌ范围内；ＢＨＣｓ在０．０４－０．７２μｇ／Ｌ范围内，氯苯类化合物及ＰＣＢｓ在污水及不中也被检出。     

浮选剂污染河段大型底栖无脊椎动物的群落特征及其对水质的评价

利用大型底栖动物的群落结构及其行为反应对有毒化合物——浮选剂污染河段水质进行评价,并提出了受浮选剂污染的污水生物系统评价标准.结果表明,主要污染物丁基磺药对涡虫(Dugesia gonocephala)的24h LC_51为78ppm.根据受污河段底栖动物群落的变化和涡虫在各断面河水中的行为反应,浮选剂污水生物系统可以划分成α-多污带,β-多污带,α-中污带,β-中污带和寡污带。并对所提出的浮选剂污水生物系统进行了讨论。     

Preliminary study on organic contaminants in the water of northwest part of the Lake Chao

The waterquality of the downstream of Nanfei River and the northwest area of Lake Chao is evaluated from organic analysis aspect. PAHs such as fluoranthene, pyrene are detected in the waters collected from downstream river and river mouth. More phenolic compounds are found in the river water. Some halogenated hydrocarbons are present in the river and lake waters. A great many of aliphatic hydrocarbons and benzene hydrocarbons found in all the water samples are about one third of the total organics detected. The hydrophobic components are found to be present not only in water but also in suspended sediment. The ratio of the amount existing is 0.4 in sediment and 1 in particle-free water. The quantity of humic materials existing in lake water is larger than that in river water. The proportion of the humic materials in lake water to that in river water is 1.9 to 1. In the lake water, some natural substances, such as dimethyl disulfide, alpha-pinene, azulene, and 6- methyl -2-heptanone are observed.     

The study for polyaromatic hydrocarbons decay on Chinese coal soot particles in atmosphere

A study for the photochemical behavior of some polyaromatic hydrocarbons (PAH), for example B(a )P, B( k )F and fluoranthene in coal smoke particles was performed by using indoor Teflon smog chamber.Experiments suggest that the photochemical reaction of PAH is first order reaction and kinetic rates of some PAH were obtained. It was shown that the reaction rate constant is proportional to light intensity and water vapor concentration. Temperature and PAH loading also have influence on PAH decay rate. A model for PAH loss has been set up on the basis of the results of our experiments and the simulating results of this model suggest that coal particle PAH half lives are of the order of a period of days in winter and a few hours in summer. Other factors which may have effect on the photochemical reaction of PAH have also been discussed.     

The hierarchy and spatial characteristics of ecosystems: A reconsideration of the ecosystem concept (II)

This paper, based on the autonomy concept, continues to investigate hierarchical forms and spatial structure of ecosystems. The former can lead to limits for the selection of the component parts of an ecosystem and a distinction between its endogenous and exogenous variables; and the latter can be lead to a hypothesis of the space of an ecosystem: the space of an ecosystem = its habitat area + supporting area + impact area, and two characteristics of ecosystems, space-overlapping and the area of ecosystem space, have been further studied referring to human activities.