混凝-Fenton试剂氧化工艺处理机械厂洗涤废水

对某厂机械洗涤废水,采用混凝-Fenton试剂进行处理。结果表明,用聚铝（w（PAC）=5%）对废水进行絮凝沉淀,PAC最佳投加量为1.5 mL/L（废水）,絮凝后的COD去除率为29.6%;芬顿试剂最佳操作条件为：n（H2O2）∶n（Fe2＋）=5∶1,m（H2O2）∶m（COD）=2.5∶1,废水pH=5,温度为30℃,反应时间为2 h,经氧化后,COD的去除率为78.5%;经过混凝沉淀-芬顿氧化处理,COD的总去除率为84.9%,去除效果良好。     

中国高碳资源低碳化利用的环保思索

我国煤炭资源的不合理开发利用以及煤化工过热无序的发展,已经引发了诸多环境问题,如气候变暖、酸雨、汞污染、灰霾等,本文在对煤炭利用与煤化工产业发展存在的环保问题进行深入分析后,提出了相应的对策建议。分析认为,我国煤炭利用存在方式单一、资源利用率低、与水资源和消费市场逆向分布的矛盾突出、环境污染严重等问题,现有煤化工企业落后产能比重大、能耗高、污染重。文章通过介绍新型煤化工,指出其是实现高碳资源低碳化的有效途径,不仅可替代能源和石油化工产品,而且通过多联产可以削减电力、石化、建材、冶炼等行业的污染源和民用分散污染源以及汽车的污染排放,可有效利用劣质资源和回收大量资源,实现循环经济。文章建议,应本着循环经济与可持续发展的理念,站在推动能源替代的战略高度,前瞻性地规划布局,推广高碳资源低碳化的实用技术,建设超大型、循环经济型、多联产新型煤化工综合产业群,制定资源、贸易与环境经济政策,引导煤炭及相关资源合理利用,用可持续的绿色理念优化经济发展。     

城市规划区内集体土地房屋拆迁制度研究

由于国家层面统一立法的缺失,我国各地城市规划区内集体土地房屋拆迁制度,如房屋拆迁是否涉及土地征收、房屋拆迁许可的条件及实施、拆迁法律关系的内容及争议的解决等方面存在较大差异,并且在是否适用、如何适用国务院《城市房屋拆迁管理条例》方面也不相同。这种状况一方面体现了各地方不同经济社会发展水平的要求,说明城市规划区内集体土地房屋拆迁与国有土地房屋拆迁存在区别,具有一定的合理性;另一方面对这种差异若不给予必要的规控和调整,也有可能对我国的法制统一造成负面影响。因此,通过对地方立法文本的比较与分析,将有助于各地方在制度完善中相互取长补短,进而为该领域的统一立法奠定坚实基础。依照国务院修改《城市房屋拆迁管理条例》的基本思路,城市规划区内集体土地房屋拆迁立法应当尽可能地全国统一立法,并做到先补偿再征收、先征收再拆迁,并强化拆迁许可证的管理。     

我国农产品贸易中的虚拟耕地交易分析

虚拟耕地是指隐含在农产品贸易中,生产这些农产品过程中所必需占用的土地资源,有意识的在国际农产品贸易中实施虚拟耕地战略,对于平衡国内耕地赤字、保障粮食安全,发挥我国农产品在国际市场上的竞争优势具有重要的理论指导意义。首先介绍了虚拟耕地的定义及其量化方法,接着分析计算了我国谷物、油籽、棉花等几类主要农产品单位重量的虚拟耕地含量,在此基础上,对当前农产品进出口贸易中虚拟耕地的交易现状及未来发展趋势作了分析和预测。结果显示：近10 a来虚拟耕地净进口量出现持续增长,2006年,通过农产品国际贸易净进口虚拟耕地16602903.1 hm²,约占当年全国耕地总面积的12.77%。同时,虚拟耕地净进口量在今后若干年仍将保持增长态势。     

江苏省能源可持续发展模式初探

针对目前江苏省能源可持续发展面临的挑战,以保障江苏能源综合供需平衡和实现能源 经济 环境协调发展为目标,以调整能源结构、优化能源供给体系、提高能源转化效率和清洁性为立足点,以充分利用省内不同区位的能源发展优势为主线,因地制宜地提炼出江苏省能源可持续发展的基本模式,包括自有资源优化开发模式和外部资源导入开发模式两大类型。其中,自有资源优化开发模式又可分为徐州煤炭工业综合体、苏北石油工业基地和沿海滩涂型可再生能源基地3种子模式;外部资源导入开发模式可分为沿江电力生产基地、苏南电力负荷中心和沿海临港型能源基地3种子模式。各种模式协同发展,有利于增强江苏省的能源可持续发展能力.     

An integrated approach to model the biomagnification of organic pollutants in aquatic food webs of the Yangtze Three Gorges Reservoir ecosystem using adapted pollution scenarios

The impounding of the Three Gorges Reservoir (TGR) at the Yangtze River caused large flooding of urban, industrial, and agricultural areas, and profound land use changes took place. Consequently, substantial amounts of organic and inorganic pollutants were released into the reservoir. Additionally, contaminants and nutrients are entering the reservoir by drift, drainage, and runoff from adjacent agricultural areas as well as from sewage of industry, aquacultures, and households. The main aim of the presented research project is a deeper understanding of the processes that determines the bioaccumulation and biomagnification of organic pollutants, i.e., mainly pesticides, in aquatic food webs under the newly developing conditions of the TGR. The project is part of the Yangtze-Hydro environmental program, financed by the German Ministry of Education and Science. In order to test combinations of environmental factors like nutrients and pollution, we use an integrated modeling approach to study the potential accumulation and biomagnification. We describe the integrative modeling approach and the consecutive adaption of the AQUATOX model, used as modeling framework for ecological risk assessment. As a starting point, pre-calibrated simulations were adapted to Yangtze-specific conditions (regionalization). Two exemplary food webs were developed by a thorough review of the pertinent literature. The first typical for the flowing conditions of the original Yangtze River and the Daning River near the city of Wushan, and the second for the stagnant reservoir characteristics of the aforementioned region that is marked by an intermediate between lake and large river communities of aquatic organisms. In close cooperation with German and Chinese partners of the Yangtze-Hydro Research Association, other site-specific parameters were estimated. The MINIBAT project contributed to the calibration of physicochemical and bathymetric parameters, and the TRANSMIC project delivered hydrodynamic models for water volume and flow velocity conditions. The research questions were firstly focused on the definition of scenarios that could depict representative situations regarding food webs, pollution, and flow conditions in the TGR. The food webs and the abiotic site conditions in the main study area near the city of Wushan that determine the environmental preconditions for the organisms were defined. In our conceptual approach, we used the pesticide propanil as a model substance.     

纳米钯?铝双金属对水中3-氯酚的脱氯降解研究

采用置换沉积法制备了纳米钯/铝双金属催化剂,氢解还原去除水相中难降解有毒有机物3-氯酚(3-CP),考察了溶液pH、钯负载量、纳米钯/铝双金属投加量、反应温度对脱氯效果的影响并解析相关反应机制。结果表明:(1)初始pH 3.0时,沉积液中93.25%(质量分数,下同)～96.67%的钯可有效负载于铝材上。(2)在pH为3.0、纳米钯/铝双金属投加量为2g/L、钯负载量为1.16%(质量分数)、反应温度为25℃下降解初始摩尔浓度为0.389mmol/L的3-CP,反应终了时脱氯率在99%以上。利用纳米钯/铝双金属降解氯代有机污染物具有高效低耗的优势,在实际应用上具有较好的前景。     

Kinetics and mechanism for omethoate degradation by catalytic ozonation with Fe(III)-loaded activated carbon in water

The kinetics and mechanism for degradation of omethoate (OMT) by catalytic ozonation with Fe(III)-loaded activated carbon (Fe@AC) were investigated in this study with focus on identification of degradation byproducts. The rate constants of OMT reacting with ozone and hydroxyl radical (OH) were determined to be 0.04 and 5.3 × 10⁸ M^?1 s^?1 at pH 7.5 and 20 °C, respectively. OMT was predominantly degraded by OH in the catalytic ozonation with Fe@AC. The high-molecular-weight degradation byproducts identified were O,O,O-trimethyl phosphoric ester (TMP), pyrrolidin-2-one, N-methyl-2-sulfanylacetamide, 2-(methylthio)acetamide, O,O,S-trimethylthiophosphate (STMP), and N-methyl-2-(methylthio)acetamide. Besides, low-molecular-weight organic acids and inorganic anions were also detected and quantified, including formic, acetic and oxalic acids as well as nitrate, sulfate and phosphate ions. In the catalytic ozonation, TMP and phosphate were two major P-containing byproducts resulting from OMT degradation. The toxicity of OMT solution gradually decreased during the catalytic ozonation, indicating that Fe@AC is a safe catalyst for OMT removal by ozone in water.     

青岛市餐厨垃圾现状调查及分析

通过问卷与实地跟踪形式调查青岛市4个主城区餐厨垃圾现状并提出关于餐厨垃圾管理和处置的建议,力求为该市餐厨垃圾的资源化利用提供参考.调查结果显示:餐厨垃圾产量为265.00 t/d,含水率为74.93％、含油率为6.06％、营养物为12.22％(质量分数);54.4％的调查餐饮单位将餐厨垃圾分为剩饭菜、废油和生活垃圾3类排放,需进一步加强餐厨垃圾分类放置的管理工作;所调查餐饮单位中有64.4％的剩饭菜、54.3％的废油由政府统一收运,统一收运率有待进一步提高;正规回收的餐厨垃圾为197.66 t/d,被用于堆肥或进行填埋处置.     

不同流量分配比对多级A/O工艺去除有机物及脱氮的影响

采用三级A/O工艺分段进水工艺处理低碳源生活污水,考察了进水流量分配比对系统去除有机物、硝化反硝化能力以及去除TN的影响。通过对水质指标沿程监测结果表明,不同流量分配比(4∶3∶3,5∶3∶2,6∶3∶1)对系统去除有机物及硝化效率影响不大,出水COD、氨氮分别均在30 mg/L、1 mg/L以下。但反硝化效果受流量分配比的影响较大,在流量比为5∶3∶2时,有效利用原水中碳源进行反硝化,反硝化效果最好。在流量比为5∶3∶2的情况下,TN出水为5.7 mg/L去除率为82.9%,优于流量分配比为6∶3∶1和4∶3∶3时的脱氮效果。总体而言,分段进水工艺在对碳源的有效利用及能耗节省方面优于单点进水。