祁连—柴达木盆地北缘地区石炭系泥岩沉积地球化学特征

详细研究了祁连—柴达木盆地北缘地区石炭系泥岩的微量元素和稀土元素地球化学特征。各微量元素在各剖面及不同层位变化相当复杂 ,但仍有一定规律 ,这种变化与其物源供应和沉积成岩环境有关。各样品稀土总量变化较大 ,以甘肃永昌煤山子剖面总量最高 ;各泥岩样品轻稀土富集 ,Eu负异常 ,δEu介于 0 .4 4～0 .90之间。微量、稀土元素组合及比值的变化 ,显示物源区母岩为花岗岩和玄武岩的混合 ,稀土分布模式显示源岩为粘土岩、花岗岩和中性岩的混合 ,两者示物源一致。元素的丰度及其比值 ,反映当时水介质环境大部分为海相 ,亦有部分为陆相 ,与其它相标志所表征的结果是一致的。     

An approach to the fluctuation mechanism of ecotone

In this paper,the relationship among land productivity,population pressure and the fluctuation mechanism of ecotone is analyzed,taking coumties and banners of southeast Inner Mongolia plateau as an example,which is the most fragile part in the farming and husbandry interleaving belt of north China due to its severe desertification degree and low level of economic development.The Cv for the total output value of agriculture decreases from southeast to northwest,with the same rule as which the overloading population cumulated distributes,and both indicators have close relation with the high linear coefficient of 0.83.These reveal the fluctuation mechanism for ecotone:fluctuation of the level of economic development is a scientific and practical measure both to weakness degree and to instability of ecotone,because it is a synthesized response to the variation of climate as well as irrational land uses,which reinforce and magnify the fluctuation.In detail,the heavier the population overloading,the severer the grassland reclamation,the stronger the dependence of regional productivity on rainfall,the lower the level of economic development,the rougher the fluctuation of ecotone,but the weaker the PRED system.     

石英表面配合物与溶解动力学模型

阐述了石英表面配合物和溶解动力学机理之间的关系，指出了石英的反应性主要受负电性表面物种的控制，从而导致电解质、离子强度、pH等因素对石英溶解的催化效应．溶解达率的提高与反应活化能的降低成活化熵的增大有关。最后，介绍了在过渡态理论和表面反应模型基础上建立的石英溶解速率方程。     

离子对烷基化法在2,4-D和2,4,5-T残留分析中的应用

有机阴离子可以和长碳链的季胺盐阳离子结合生成可溶于高介电常数有机溶剂的离子对.在此溶剂中,它可以和某些卤代烃发生复分解反应,生成季铵盐阳离子的卤化物及有机阴离子的相应烷基化物,故称离子对烷基化反应.此反应条件温和,转化率高,被广泛地应用于酸性及其它含活泼氢的有机化合物的烷基衍生物合成中.在这类有机物的分析中也得到应用.但尚未见应用于农药及其降解物残留分析中的报道. 2,4-D,2,4,5-T是典型的酸性有机农药,广泛用作农田除草剂.在二者的残留分析中,通常用CH_2N_2、BF_3CH_3OH、(CH_3)_2SO_4将它们烷基化,然后用气相色谱加以分析.近几年也有人用多卤素取代醇的BCl_3络合物或五氟苄基溴化物同Na_2CO_3作为     

建设项目实施过程中的可行性研究与环境影响评价

作者根据多年的工作实践，分析了目前建设项目可行性研究与环境影响评价工作中存在的一些问题。提出了编写环境影响评价报告时如何有效地利用建设项目的可行性研究报告文本，以及在没有可行性研究报告的情况下怎样使环境影响评价报告能够准确地反映建设项目的环境问题，进而保证环境影响报告书的质量。总之，恰当处理这两者之间的关系，保证建设项目在建设期与运营期降低与防止建设项目对周边环境影响是本文的主要目的之一。     

Strategies of a bark beetle, Pityogenes bidentatus, in an olfactory landscape

 Volatiles from leaves or bark of nonhost birch (Betula pendula) and Norway spruce (Picea abies) dramatically reduced the attraction of the bark beetle, Pityogenes bidentatus (Coleoptera: Scolytidae), to their aggregation pheromone components (cis-verbenol and grandisol) in the field. In addition, odors from both the needles and bark of the host Scots pine (Pinus sylvestris) similarly inhibited attraction. Monoterpenes of pine and spruce (α-pinene, β-pinene, terpinolene, and 3-carene) as well as ethanol, chalcogran and some nonhost green leaf alcohols [(Z)-3-hexen-1-ol, (E)-2-hexen-1-ol, and 1-hexanol], also reduced catches. Collections of volatiles from the field-tested plant tissues indicated they released monoterpenes in amounts similar to the synthetics that inhibited responses. The various plant and insect sources of these inhibitory compounds indicate that P. bidentatus bark beetles have evolved several strategies to increase their fitness by avoiding nonhost and unsuitable host trees in a complex olfactory landscape. Received: 6 June 2000 / Accepted in revised form: 25 September 2000     

再论次生石英岩型非金属矿床

次生石英岩型非金属矿床明显受不同级别的火山构造控制,是中—酸性火山岩区一套很有特色的矿床组合;热源、水源、地层产状有机组合生成的环流热液是成矿的前提之一;成矿流体以重碳酸盐型、硫酸盐型为主,属中—低盐度热液;温度、pH值、fo_2等物理化学条件是矿床及矿种类刑的重要控制因素。本文在《次生石英岩容矿型非金属矿床系列的矿种、组合及其成矿作用特征》(1986)一文基础上,进一步总结这类矿床的成矿机理和地质地球化学模式。     

Dynamic fate modeling of γ-hexachlorocyclohexane in the lower reaches of the Liao River

A QWASI model dependent on temperature is parameterized to describe the long-term fate of persistent organic pollutants (POPs) in the Liao River. The model parameters, namely fugacity capacity, degradation rate, and transfer coefficient, are profoundly affected by temperature. This model is used to simulate the fate of γ-hexachlorocyclohexane (γ-HCH) in the lower reaches of the Liao River from 1998 to 2008. Modeling results show that γ-HCH fugacity capacities in air, water, and sediment increase as temperature decreases, and the transfer and transformation rate coefficients increase as temperature increases. The variations of transfer and transformation parameter D values depend on fugacity capacities, and transfer and transformation coefficients simultaneously. The performance of the model is evaluated by comparing the predicted and observed concentrations in the water and sediment of the Liao River. The predicted values agree well with the observed value in the order of magnitude, in most cases within the factor of 3. It is believed that the model is appropriate for simulating the long term fate of POPs in the Liao River. Translated from Environmental Science, 2006, 27(1): 121–125 [译自: 环境科学]     

Atmospheric particulate pollution of Lanzhou using magnetic measurements

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