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941.
Xuan Zhang Zhongming Chen Hongli Wang Shuzhong He Daoming Huang 《Atmospheric environment (Oxford, England : 1994)》2009,43(29):4465-4471
The aqueous ozonolysis of α-pinene and β-pinene was conducted under simulated tropospheric conditions at different pHs and temperatures. Three kinds of products, peroxides, carbonyl compounds, and organic acids, were well characterized, and the detection of these products provides effective evidence for understanding the atmospheric aqueous reaction pathway. We have two interesting findings: (1) the unexpected formation of methacrolein (MACR), with a yield of ~40%, in the α-pinene–O3 aqueous reaction indicates a potentially new SOA formation pathway, because MACR is one of the important precursors of SOA; and (2) the surprisingly high yields of H2O2, ~60% for the α-pinene–O3 reaction and ~100% for the β-pinene–O3 reaction, indicates that H2O2 can be a significant contributor to the origin and transformation of oxidants in the atmosphere, especially in the humid regions. Moreover, we have determined the rate constant for aqueous reaction between MACR and H2O2 in pH 2 to 7 and obtained its upper limit as 0.13 M L?1 s?1. A mechanism concerning the formation of the species mentioned above is proposed, and it differs from that in the gas-phase reaction. We suggest that water plays a key role in the mechanism, by participating in the reactions as a direct reactant and by removing the excess energy of intermediates formed in the reactions. 相似文献
942.
Min Qin Pinhua Xie Hang Su Jianwei Gu Fumin Peng Suwen Li Limin Zeng Jianguo Liu Wenqing Liu Yuanhang Zhang 《Atmospheric environment (Oxford, England : 1994)》2009,43(36):5731-5742
The temporal behavior of HONO and NO2 was investigated at an urban site in Guangzhou city, China, by means of a DOAS system during the Pearl River Delta 2006 intensive campaign from 10 to 24 July 2006. Within the whole measurement period, unexpected high HONO mixing ratios up to 2 ppb were observed even during the day. A nocturnal maximum concentration of about 8.43 ± 0.4 ppb was detected on the night of 24 July 2006. Combining the data simultaneously observed by different instruments, the coupling of HONO–NO2 and the possible formation sources of HONO are discussed. During the measurement period, concentration ratios of HONO to NO2 ranged from (0.03 ± 0.1) to (0.37 ± 0.09), which is significantly higher than previously reported values (0.01–0.1). Surprisingly, in most cases a strong daytime correlation between HONO and NO2 was found, contrary to previous observations in China. Aerosol was found to have a minor impact on HONO formation during the whole measurement period. Using a pseudo steady state approach for interpreting the nocturnal conversion of NO2 to HONO suggests a non-negligible role of the relative humidity for the heterogeneous HONO formation from NO2. 相似文献
943.
Diversity of Soil Nematodes in Areas Polluted with Heavy Metals and Polycyclic Aromatic Hydrocarbons (PAHs) in Lanzhou,China 总被引:1,自引:0,他引:1
This study investigated the soil nematode community structure along the Yellow River in the Lanzhou area of China, and analyzed
the impact of heavy metals (Cd, Pb, Cr, Cu, and Zn) and polycyclic aromatic hydrocarbons (PAHs) on the nematode community.
Soil samples from five locations (named A–E), which were chosen for soil analysis, showed significant differences in their
heavy metal content (p < 0.01), as well as in the variety of nematodes (up to 41 genera) and families (up to 20) that were present. The different
samples also differed significantly in the total PAH content (p < 0.05), as well as the six types of PAH present. Sites A–C showed the most severe contamination with heavy metals and PAHs;
these sites had the lowest abundance of fungivores and omnivore/predators, but the proportion of bacteriovores was the highest
(p < 0.05). Site E, in contrast, showed only minor pollution with heavy metals and PAHs, and it contained the highest abundance
of plant parasites (p < 0.05). Several nematode ecological indicators were found to correlate with concentration of soil pollutants at all the
sites tested: the maturity index (MI, in addition to plant parasites), plant parasite index (PPI), ΣMI (including all the
soil nematodes), Shannon-Wiener diversity index (H′′), and Wasilewska index (WI). Disturbance to the soil environment was more severe when MI, ΣMI, and H′ values were lower. The results of the study show that the abundance and structure of the soil nematode communities in the
sampling locations were strongly influenced by levels of heavy metals and PAHs in the soil. They also show that the diversity
index H′ and the maturity index can be valuable tools for assessing the impact of pollutants on nematodes. 相似文献
944.
An Interval-Parameter Waste-Load-Allocation Model for River Water Quality Management Under Uncertainty 总被引:1,自引:0,他引:1
A simulation-based interval quadratic waste load allocation (IQWLA) model was developed for supporting river water quality
management. A multi-segment simulation model was developed to generate water-quality transformation matrices and vectors under
steady-state river flow conditions. The established matrices and vectors were then used to establish the water-quality constraints
that were included in a water quality management model. Uncertainties associated with water quality parameters, cost functions,
and environmental guidelines were described as intervals. The cost functions of wastewater treatment units were expressed
in quadratic forms. A water-quality planning problem in the Changsha section of Xiangjiang River in China was used as a study
case to demonstrate applicability of the proposed method. The study results demonstrated that IQWLA model could effectively
communicate the interval-format uncertainties into optimization process, and generate inexact solutions that contain a spectrum
of potential wastewater treatment options. Decision alternatives can be generated by adjusting different combinations of the
decision variables within their solution intervals. The results are valuable for supporting local decision makers in generating
cost-effective water quality management strategies. 相似文献
945.
946.
Influence of titanium dioxide nanoparticles on speciation and bioavailability of arsenite 总被引:2,自引:0,他引:2
Sun H Zhang X Zhang Z Chen Y Crittenden JC 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1165-1170
In this study, the influence of the co-existence of TiO2 nanoparticles on the speciation of arsenite [As(III)] was studied by observing its adsorption and valence changing. Moreover, the influence of TiO2 nanoparticles on the bioavailability of As(III) was examined by bioaccumulation test using carp (Cyprinus carpio). The results showed that TiO2 nanoparticles have a significant adsorption capacity for As (III). Equilibrium was established within 30 min, with about 30% of the initial As (III) being adsorbed onto TiO2 nanoparticles. Most of aqueous As (III) was oxidized to As(V) in the presence of TiO2 nanoparticles under sunlight. The carp accumulated considerably more As in the presence of TiO2 nanoparticles than in the absence of TiO2 nanoparticles, and after 25-day exposure, As concentration in carp increased by 44%. Accumulation of As in viscera, gills and muscle of the carp was significantly enhanced by the presence of TiO2 nanoparticles. 相似文献
947.
The establishment and development of the industrial symbiosis of eco-industrial park are affected by several factors. Based on the formed industrial symbiosis supporting system chart, this article analyzes the microcosmic supporting system and macroscopic supporting system. In the microcosmic supporting system, it elaborates five aspects including key enterprises, service intermediaries in the park, symbiotic enterprises, competitors and the public in detail. Then it describes the macroscopic supporting system from four aspects of governmental participation, technological innovation, educational promotion and cultural support. Finally, combining with the current construction status of the ecoindustrial park in China, it proposes the countermeasures and suggestions to build the supporting system for the eco-industrial park and provides theoretical support for the faster and better construction of the eco-industrial park in China. 相似文献
948.
Based on shift-share method, this article employs re- gional share, structural shift and competitive shift to analyze the structural benefit and competitive position of agricultural structure in western China by comparing with agriculture, foresting, stockbreeding and fishing before and after Conversion of Farmland to Forest and Grassland (CFFG). Then authors draw following conclusion: while CFFG program has been put in practice, the agricultural structure in western China has some typical characteristics, such as growth faster, structural predominance obvious and more competitive. But the contributiveness from the competition is not too much yet, and the structural benefit of forest estate and stockbreeding are restrained. 相似文献
949.
As part of a comprehensive environmental management system, many countries establish emission control targets for mass emissions of a pollutant. Such targets are often the key objective of an environmental policy, such as an emission trading program. In China, however, it is more than just an objective of one particular policy; it has become a concept that has influenced many national environmental policies and activities. The objective of this article is to review the implementation of the total emission c... 相似文献
950.