阳极溶出伏安法、石墨炉原子吸收法测定海水中总铬的方法比较研究

铬是海洋水体中的痕量重金属之一,海水的高盐基体对铬的测定有严重的干扰,而且海水中同时存在Cr(Ⅲ)和Cr(Ⅵ),两种不同价态给测定也带来了一定难度。文章从Cr(Ⅲ)的氧化率、方法检出限、精密度、实际样品加标等方面对过氧化氢氧化-阳极溶出伏安法与传统的MIBK萃取-无火焰原子吸收分光光度法进行了比较研究,发现两种方法在测试结果上无显著差异,但是过氧化氢氧化-阳极溶出伏安法具有更高的精密度,更低的检出限,且对Cr(Ⅲ)的回收率略有提升。     

废水中硝基苯类化合物测定方法的探讨及新方法研究

探讨了废水中硝基苯类化合物的气相色谱法测定方法中的水样预处理操作繁琐,实验耗时长,且萃取时使用易挥发有毒有害的有机物二氯甲烷。另一种常见的测定方法还原-偶氮分光光度法,而染料、印染制革等工业废水的颜色较深,对测定造成干扰,通常通过蒸馏预处理消除水样颜色带来的干扰,而在蒸馏过程中因硝基苯类沸点较高不能将水样中的硝基苯类化合物全部蒸出,导致检测结果偏低。提出了一种经聚己内酰胺脱色,简单又快捷地消除水样中颜色的干扰,又避免了硝基苯类化合物蒸馏不完全的问题,再利用还原-偶氮分光光度法准确测定废水中硝基苯类化合物的方法。     

青年群体对传统绿色生态文化回归的影响研究

传统方法对青年群体绿色生态文化回归的影响分析中,存在青年群体分析影响片面,影响分析计算准确率较低的问题。为此提出青年群体对传统绿色生态文化回归的影响与思考。通过勒布朗斯回归数学影响方程确定影响因子,建立青年群体主观因子与客观因子之间的动态关联;采用大数据分析,构建大数据影响因子数据分析模型;依托绿色生态文化回归影响算法,从而完成青年群体对传统绿色生态文化回归的影响分析。该影响分析方法比传统方法平均准确度提升3.55倍,且能够实现青年群体对传统绿色生态文化回归的影响分析。     

Energy-saving benefits from plug-in hybrid electric vehicles: perspectives based on real-world measurements

Promoting plug-in hybrid vehicles (PHEV) is one important option to mitigate greenhouse gas emissions and air pollutants for road transportation sector. In 2015, more than 220,000 new PHEVs were registered across the world, indicating a 25-fold growth during 2011–2015. However, more criticizes have been put forward against the current energy efficiency regulations for vehicles that are mostly depended on laboratory measurements. To better understand the real-world energy-saving and emission mitigation benefits from PHEVs, we conducted on-road testing experiments under various operating conditions for two in-use PHEVs in Beijing, China. Our results indicate that air condition usage, congested traffic conditions, and higher loading mass could significantly increase energy consumption and shorten actual all-electric distance for PHEVs. For example, the worst case (14.1 km) would occur under harshest usage conditions, which is lower by at least 35% than the claimed range over 20 km. In charge sustaining (CS) mode, real-world fuel consumption also presents a large range from 3.5 L/100 km to 6.3 L/100 km because of varying usage conditions. Furthermore, various vehicle users have significantly different travel profiles, which would lead to large heterogeneity of emission mitigation benefits among individual PHEV adopters. Therefore, this study suggests that the global policy makers should use real-world energy efficiency of emerging electrified powertrain techniques as criteria to formulate relevant regulations and supportive policies.     

立体传质塔板在含硫污水汽提塔技改中的应用

采用新型高效立体传质塔板(CTST),对济南石化分公司的含硫污水汽提塔进行技术改造,在原塔外壳、降液管以及上部填料段等均不变的条件下,仅用CTST塔板替换原浮阀塔板,改造后处理能力由原来的100t/h提高到180t/h,净化水氨氮含量降低到50mg/L以下,实现了净化水的全部回用。     

Using supercritical carbon dioxide as solvent to replace water in polyethylene terephthalate (PET) fabric dyeing procedures

Dyeing fabrics in supercritical carbon dioxide (SCD) instead of water can save energy, reduce water use and prevent pollution. The special pilot plant was designed to test dyeing procedures in supercritical carbon dioxide and the analyses of the results indicate major benefits as compared to water based procedures. The dyeing of polyethylene terephthalate (PET) fabric in supercritical carbon dioxide using special pilot plant was investigated. Disperse dye, C.I. (color index) Disperse Blue 79, was used in this study. After dyeing, rinsing in supercritical carbon dioxide, which removes the excess dyes, was also discussed. At the same dyeing conditions, K/S (color yield) of dyed fabric significantly increased with increasing the dye concentration from 1% o.w.f. (on weight of fabric) to 5% o.w.f. Dyeing temperature and pressure had a strong influence on the color yield. When the temperature rose above 110 °C, the increase in color yield was obvious. At 20 MPa, 120–130 °C, dyeing reached equilibrium after 60 min. The excess dye of the dyed PET fabric was small. The suitable condition in supercritical carbon dioxide for removal of excess dye from the dyed fabric was 70 °C, 20 MPa. The PET fabric dyed in supercritical carbon dioxide had good fastness and physical properties.     

安徽省宁国市元竹枯死原因与防治对策研究

文章探讨了安徽省宁国市中溪镇元竹大面积枯死的原因.在现场调查、污染监测和综合分析的基础上,排除了污染、病虫害致死和元竹而开花死亡的可能性,得出该区元竹枯死是由于非污染生态工程道路改建、水利水电工程和河道采砂等人为活动所导致元竹区的局部生态系统破坏,致使该区地下水位的不正常变动,从而引起大面积不规则分布的元竹干枯或浸泡死亡.文中最后根据该区生态环境状况,给出了防治元竹枯死的生态对策与建议,为防治其它地区的元竹枯死提供了参考和经验.     

中国水环境非点源污染负荷的估算研究

中国已占水环境容量中,除了点源污染以外,非点源污染也占有相当比重,非点源污染负荷的定量化研究势在必行.国外对非点源污染的研究开始较早,成果也较成熟.从20世纪80年代以来,中国也逐渐认识到非点源污染的存在及其危害性,开始了非点源污染的控制研究.但是中国对非点源污染问题的研究现在尚处于初级阶段,多为借鉴国外模型.文章分析了国内外对非点源污染的研究方法和研究现状,介绍了适合中国国情的非点源污染负荷估算的方法,包括流域水文估算法、大尺度区域中非点源污染负荷估算的方法.     

经济全球化背景下中国环境问题及应对策略

文章从经济全球化的定义出发,论述了全球化使中国环境问题变成了世界的环境问题,因为中国的环境问题是由世界造成的,同时中国的环境问题也影响到世界.要从根本上解决中国环境问题,必须树立科学发展观,促进创新型国家的建设,重视对外贸易中的环境问题,严防国外环境污染向国内转移.     

城市污水厌氧处理技术研究进展

通过介绍厌氧处理技术在城市污水处理中的现状及研究焦点,论述了以微生物固定化和提高污泥与污水混合效率为基础的一系列高速厌氧反应器的特点,分别阐述了升流式厌氧污泥床、折流式厌氧反应器、内循环厌氧反应器及颗粒污泥膨胀床反应器的研究进展,提出高效率的厌氧处理系统应满足的条件,并与好氧处理技术作了对比,综述了新型反应器的研制及其组合工艺的应用在废水处理领域所发挥的重要作用.