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951.
污水处理中紫外消毒方法与传统消毒方法相比之下具有不需要投加化学药剂、不产生有毒有害副产物、消毒效率高、操作简单、便于运行管理等特点。本文着重介绍了目前用于消毒的紫外灯的种类,并阐述了浊度、微生物种类、光复活性能等影响紫外消毒效果的因素,最后对未来紫外消毒方法发展的前景做出了分析。 相似文献
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955.
利用含铬废水和含铅废水制备铬黄 总被引:2,自引:1,他引:1
利用净化后的含铬废水和含铅废水制备铬黄.采用沉淀法对废水进行净化预处理,最佳工艺条件:100mL含铬废水中加入20 g Na_2CO_3,及10 mL H_2O_2,用NaOH调节含铬废水pH为10.00;用NaOH调节含铅废水pH为2.65.将净化后的10 mL含铬废水和25 mL含铅废水混合,在55-60℃条件下反应10 min,合成的铬黄达到GB/T 3184-2008<铬酸铅颜料和钼铬酸铅颜料>的质量标准.经重金属吸附剂处理Pb~(2+)后铬黄合成滤液中的Cr~(6+)和Pb~(2+)质量浓度均达到GB8978-1996<污水综合排放标准>的指标. 相似文献
956.
分别以γ-Al_2O_3和活性炭(AC)为载体,采用浸渍法制备了Ru质量分数均为2.0%的Ru/γ-Al_2O_3和Ru/AC催化剂,并用X射线衍射仪和透射电子显微镜等方法对催化剂结构进行了表征.实验结果表明:Ru/AC中Ru沉积在AC表面,分散度较低;而Ru/γ-Al_2O_3中Ru进入到γ-Al_2O_3内部,形成了一种高度分散体系.Ru/γ-Al_2O_3对氨的催化活性高于Ru/AC,氨在Ru/γ-Al_2O_3和Ru/AC上的起活温度分别为200 ℃和266 ℃,T_(90)(氨去除率达90%时的反应温度)分别为267℃和320 ℃.随混合气体空速增大,Ru/γ-Al_2O_3催化剂的T_(90)逐渐升高,气体空速分别为3 600,4 800,5 400 h~(-1)时,T_(90)分别为235,266,303 ℃.随反应前混合气体中氨质量分数增加,氨的去除率降低. 相似文献
957.
采用反相微悬浮乳液聚合技术制备了β-环糊精(β-CD)微球,用丁二酸酐对β-CD微球进行化学改性,制备了pH敏感性β-CD(pH-β-CD)微球.通过傅里叶红外光谱仪和扫描电子显微镜对微球的结构、粒径和形貌进行了表征.探讨了亚甲基蓝模拟染料废水pH、吸附时间和微球加入量对亚甲基蓝吸附性能的影响.实验结果表明,在亚甲基蓝模拟染料废水pH为10.0、吸附时间为90 min的条件下,当pH-β-CD微球加入量为50 mg时,pH-β-CD微球吸附量为16.1 mg/g;当pH-β-CD微球加入量为250 mg时,pH-β-CD微球对亚甲基蓝的脱色率达96.2%. 相似文献
958.
Penggang Ren Tingting Shen Fang Wang Xing Wang Zhengwei Zhang 《Journal of Polymers and the Environment》2009,17(3):203-207
The thermoplastic starch (TPS) and nanocomposite(TPS/OMMT) was prepared with 15% carbamide, 15% ethanolamine and different
contents of organic activated montmorillonite (OMMT) by twin-screw extruder with a 130 °C barrel temperature. Fourier transforms
infrared spectroscopy and wide angle X-ray diffraction shown that the alkylamine in dodecyl benzyl dimethyl ammonium bromide
could react with MMT via cation exchange reaction. After treated, the d(001)space distance of MMT increased from 1.5 to 1.7 nm. Scanning electron microscope revealed that the lower contents of
OMMT could disperse well in the matrixes of TPS. The carbamide, ethanolamine and the OMMT could destroy the crystallization
behavior of starch, but only the OMMT restrained this behavior for long-term storing. Mechanical properties investigation
indicated that the tensile strength and modulus of TPS/OMMT nanocomposites were better than those of TPS, while the elongation
at break was descended with the increasing of OMMT contents. When the content of OMMT was 4%, the tensile strength and modulus
of TPS was improved from 4.2 and 42 MPa to 6.0 and 76 MPa, respectively. 相似文献
959.
Hai Zhao Dexiang Zhang Fangfang Wang Tingting Wu Jinsheng Gao 《Process Safety and Environmental Protection》2009,87(4):274-280
In order to develop highly active sorbent for COS removal, Fe–Mn mixed oxides doped with CeO2, La2O3 or Sm2O3 were studied. The effects of these promoters on the structural properties of Fe–Mn oxides were investigated by XRD, BET, TPR and TEM techniques. XRD results revealed that the degree of crystallinity of Fe–Mn oxide phase decreased due to the addition of rare-earth oxides. Doping with CeO2, La2O3 or Sm2O3 led to an increase in BET surface area of the sample. TPR studies showed that the reactivity of the reduction of doped samples increased in the temperature range of 300–450 °C. In addition, the desulfurization test was performed at 325 °C with a gas hourly space velocity of 1000 h−1. It was found that the addition of 3% La2O3 greatly improved the absorption sulfur capacity of the sorbent, while the sorbent doped 3% CeO2 achieved a sufficiently high purifying degree before breakthrough. 相似文献
960.
Naman Cissoko Zhen Zhang Jinghui Zhang Xinhua Xu 《Process Safety and Environmental Protection》2009,87(6):395-400
The Cr(VI) removal from simulative contaminated groundwater using zero-valent iron (Fe0) filings, Fe0 powder and nanoscale Fe0 in batch experimental mode was studied. Cr(VI) is a primary pollutant of some soils and groundwater. Zero-valent iron, an important natural reductant, could transform Cr(VI) to Cr(III) which is much less toxic and immobile. The Cr(VI) removal percentage was 87% at a metal to solution ratio of 6 g l−1 for commercial iron powder (200 mesh) in 120 min, and 100% Cr(VI) was removed when the metal to solution ratio was 10 g l−1. The results demonstrates that the Cr(VI) removal percentage was affected apparently by pH, the amount of Fe powder and the reaction temperature. The Cr(VI) removal percentage with nanoscale Fe0 was much higher than those with Fe0 filings or Fe0 powder at the same reaction time. Electrochemical analysis of the reaction process led to the conclusion that the Cr(VI) trended to form Cr(III) hydroxide under the reaction conditions. The kinetics analysis showed that Cr(VI) reduction by Fe0 could be described as a pseudo-first-order kinetics model. 相似文献