With the rapid urbanization, the southeast coastal cities of China are facing increasing air pollution in the past decades. Large emissions of VOCs from vehicles and petrochemical factories have contributed greatly to the local air quality deterioration. Investigating the pollution characteristics of VOCs is of great significance to the environmental risk assessment and air quality improvement. Ambient VOC samples were collected simultaneously from nine coastal cities of southeast China using the Tedlar bags, and were subsequently preprocessed and analyzed using a cryogenic preconcentrator and a gas chromatography–mass spectrometry system, respectively. VOC compositions, spatial distributions, seasonal variations and ozone formation potentials (OPFs) were discussed. Results showed that methylene chloride, toluene, isopropyl alcohol and n-hexane were most abundant species, and oxygenated compounds, aromatics and halogenated hydrocarbons were most abundant chemical classes (62.5–95.6 % of TVOCs). Both industrial and vehicular exhausts might contribute greatly to the VOC emissions. The VOC levels in the southeast coastal cities of China were sufficiently high (e.g., 6.5 μg?m?3 for benzene) to pose a health risk to local people. A more serious pollution state was found in the southern cities of the study region, while higher VOC levels were usually observed in winter. The B/T ratio (0.26?±?0.09) was lower than the typical ratio (ca. 0.6) for roadside samples, while the B/E (1.6–7.6) and T/E (7.2–26.8) ratios were higher than other cities around the world, which indicated a unique emission profile in the study region. Besides, analysis on ozone formation potentials (OFPs) indicated that toluene was the most important species in ozone production with the accountabilities for total OFPs of 22.6 to 59.6 %. 相似文献
Ambient levels of phosphine (PH3) in the air, phosphine emission fluxes from paddy fields and rice plants, and the distribution of matrix-bound phosphine (MBP) in paddy soils were investigated throughout the growing stages of rice. The relationships between MBP and environmental factors were analyzed to identify the principal factors determining the distribution of MBP. The phosphine ambient levels ranged from 2.368 ± 0.6060 ng m−3 to 24.83 ± 6.529 ng m−3 and averaged 14.25 ± 4.547 ng m−3. The highest phosphine emission flux was 22.54 ± 3.897 ng (m2 h)−1, the lowest flux was 7.64 ± 4.83 ng (m2 h)−1, and the average flux was 14.17 ± 4.977 ng (m2 h)−1. Rice plants transport a significant portion of the phosphine emitted from the paddy fields. The highest contribution rate of rice plants to the phosphine emission fluxes reached 73.73% and the average contribution was 43.00%. The average MBP content of 111.6 ng kg−1fluctuated significantly in different stages of rice growth and initially increased then decreased with increasing depth. The peak MBP content in each growth stage occurred approximately 10 cm under the surface of paddy soils. Pearson correlation analyses and stepwise multiple regression analysis showed that soil temperature (Ts), acid phosphatase (ACP) and total phosphorus (TP) were the principal environmental factors, with correlative rankings of Ts > ACP > TP. 相似文献
Remobilization of 16 polycyclic aromatic hydrocarbons (PAHs) during sediment resuspension was investigated using a particle entrainment simulator at shear stress from 0.2 to 0.5Nm(-2), typical of the energy levels present in many tidally driven aquatic environments. The results suggested that desorption from the entrained particles was the primary source of dissolved PAHs. summation operatorPAHs concentrations in particles on volume normalization increased about four times. However, on mass weight basis, summation operatorPAHs concentrations decreased from 6039.74+/-138.28microgkg(-1) to 1665.39+/-112.26microgkg(-1). The same trend was observed for individual PAHs. Dissolved concentrations of PAHs demonstrated significant differences depending on molecular weight and applied shear. The distribution of PAHs between particle and water phase suggested that for three-ring PAHs, the amounts of PAHs in particles were higher than the predicted values during our experiments. This might be due to presence of another active sorbent. 相似文献
Objective: This study explores the influence of mobile phone secondary tasks on driving from the perspective of visual, auditory, cognitive, and psychomotor (VACP) multiple resource theory, and it is anticipated to benefit the human-centered design of mobile phone use while driving.
Methods: The present study investigated 6 typical phone use scenarios while driving and analyzed the effects of phone use distractions on driving performance. Thirty-six participants were recruited to participate in this experiment. We abandoned traditional secondary tasks such as conversations or dialing, in which cognitive resources can become interference. Instead, we adopted an arrow secondary task and an n-back delayed digit recall task.
Results: The results show that all mobile phone use scenarios have a significant influence on driving performance, especially on lateral vehicle control. The visual plus psychomotor resource occupation scenario demonstrated the greatest deterioration of driving performance, and there was a significant deterioration of driving speed and steering wheel angle once the psychomotor resource was occupied.
Conclusions: Phone use distraction leads to visual, cognitive, and/or motor resource functional limitations and thus causes lane violations and traffic accidents. 相似文献
Environmental Science and Pollution Research - Nitrogen (N) is an essential nutrient limiting life, and its biochemical cycling and distribution in rivers have been markedly affected by river... 相似文献