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331.
Qiuzhun Chen Xiang Zhang Bing Li Shengli Niu Gaiju Zhao Dong Wang Yue Peng Junhua Li Chunmei Lu John Crittenden 《Frontiers of Environmental Science & Engineering》2021,15(5):92
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333.
粉煤灰和二灰(粉煤灰与石灰的混合料)均为改良软土地基的添加材料。以掺粉煤灰和二灰的上海软土为研究对象,进行次固结试验和直剪试验,研究了掺入率和养护龄期对掺粉煤灰和二灰上海软土的次固结特性和强度特性的影响。次固结试验结果表明,掺粉煤灰和二灰上海软土的次固结系数随着粉煤灰和二灰掺入量的增加而大幅减小,且在相同掺入率条件下,二灰的掺入对其次固结系数影响较大。直剪试验结果表明,粉煤灰和二灰的掺入均能提高上海软土的抗剪强度,与纯上海软土相比,其抗剪强度随着养护龄期的增长而显著增大,最后均会在某一养护龄期趋于稳定。掺粉煤灰的上海软土抗剪强度随粉煤灰掺入率基本成线性增长,最佳养护龄期建议为56 d,二灰的掺入率在10%即可有效提高上海软土的抗剪强度,其最佳养护龄期建议为28 d。上述试验结论可为科学和经济的处理软土地基提供参考。 相似文献
334.
Electrochemical degradation of 2,4-dichlorophenol (2,4-DCP) in aqueous solution was investigated over Ti/SnO2-Sb anode. The factors influencing the degradation rate, such as applied current density (2-40 mA/cm2), pH (3-11) and initial concentration (5-200 mg/L) were evaluated. The degradation of 2,4-DCP followed apparent pseudo first-order kinetics. The degradation ratio on Ti/SnO2-Sb anode attained > 99.9% after 20 min of electrolysis at initial 5-200 mg/L concentrations at a constant current density of 30 mA/cm2 with a 10 mmol/L sodium sulphate (Na2SO4) supporting electrolyte solution. The results showed that 2,4-DCP (100 mg/L) degradation and total organic carbon (TOC) removal ratio achieved 99.9% and 92.8%, respectively, at the optimal conditions after 30 min electrolysis. Under this condition, the degradation rate constant (k) and the degradation half-life (t1/2) were 0.21 min-1 and (2.8±0.2) min, respectively. Mainly carboxylic acids (propanoic acid, maleic acid, propanedioic acid, acetic acid and oxalic acid) were detected as intermediates. The energy efficiencies for 2,4-DCP degradation (5-200 mg/L) with Ti/SnO2-Sb anode ranged from 0.672 to 1.602 g/kWh. The Ti/SnO2-Sb anode with a high activity to rapid organic oxidation could be employed to degrade chlorophenols, particularly 2,4-DCP in wastewater. 相似文献
335.
Involvements of chloride ion in decolorization of Acid Orange 7 by activated peroxydisulfate or peroxymonosulfate oxidation 总被引:1,自引:0,他引:1
The effects of Cl- on the decolorization of AO7 by SO4·- based-peroxydisulfate or peroxymonosulfate oxidation under various activated conditions were different. 相似文献
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337.
Persulfate(PS)-based oxidation technologies are attracting increasing attentions in water treatment due to their high efficiency and stability.In this study,a novel diatomite supported MnCeO_x composite(MnCeO_x/diatomite) was prepared and characterized for activation of PS to degrade organic pollutants.Results indicated that diatomite not only dispersed MnCeO_x and increased the specific surface area of catalyst,but also improved the low-valence metal site(Mn~(2+)and Ce~(3+)) and reactive oxygen species site(-OH) of MnCeO_x,thus enhancing the activities of MnCeO_x.MnCeO_x/diatomite/PS showed high efficiency for multiple dyes and pharmaceutical pollutants.Constant rate(k) of MnCeO_x/diatomite(k_(MnCeOx/diatomite)) was three times higher than the sum of constant rate of MnCeOx(k_(MnCeO_x))and constant rate of diatomite(k_(diatomite)).In addition,MnCeO_x/diatomite showed wide pH application(5-9).Cl~- and NO_3~(2-) had no effect while SO_4~(2-) and humid acid had slightly negative effects on MnCeOx/diatomite/PS system.Moreover,MnCeOx/diatomite showed good reusability and stability.Mechanism analyses indicated that electron transfer of Mn and Ce attributed to the activation of PS and oxygen to produce free radicals.SO_4·~-,·OH and O_2·~-on the surface of catalyst were the main active free radicals to attack pollutants. 相似文献
338.
通过综合学习借鉴发达国家不同历史阶段污染防治的历程与积累的经验,有助于我国在比较的视野中正确认识我国重金属污染防治中存在的问题,以及学习借鉴他国的经验教训,探索属于自己的跨越式发展道路,包括污染防治政策制度设计、环境管理经验、各国的协调合作等。 相似文献
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340.
Guoying Wang Shiming Jia Ruihong Li Shangrong Ma Xuefu Chen Zhijun Wu Gaofeng Shi Xiuli Niu 《环境科学学报(英文版)》2020,32(9):58-64
Hydroxyl free radicals(OH radicals) play the main role in atmospheric chemistry and their involving reactions are the dominant rate determining step in the formation of secondary fine particulate matter and in the removal of air pollutants from the atmosphere.In this paper,we studied the seasonal variation characteristics of OH radicals during the daytime in Lanzhou and explored the potential formation mechanism of high concentration OH radicals.We found that the OH radicals in four seasons was ... 相似文献