An observational study of the HONO–NO2 coupling at an urban site in Guangzhou City,South China

The temporal behavior of HONO and NO₂ was investigated at an urban site in Guangzhou city, China, by means of a DOAS system during the Pearl River Delta 2006 intensive campaign from 10 to 24 July 2006. Within the whole measurement period, unexpected high HONO mixing ratios up to 2 ppb were observed even during the day. A nocturnal maximum concentration of about 8.43 ± 0.4 ppb was detected on the night of 24 July 2006. Combining the data simultaneously observed by different instruments, the coupling of HONO–NO₂ and the possible formation sources of HONO are discussed. During the measurement period, concentration ratios of HONO to NO₂ ranged from (0.03 ± 0.1) to (0.37 ± 0.09), which is significantly higher than previously reported values (0.01–0.1). Surprisingly, in most cases a strong daytime correlation between HONO and NO₂ was found, contrary to previous observations in China. Aerosol was found to have a minor impact on HONO formation during the whole measurement period. Using a pseudo steady state approach for interpreting the nocturnal conversion of NO₂ to HONO suggests a non-negligible role of the relative humidity for the heterogeneous HONO formation from NO₂.     

中国环境管理干部学院教师健康现状的动态分析

主要采用调查法、访问法等,对中国环境管理干部学院教师健康现状进行了调查研究,并根据教师每周参加体育活动情况,教师经常参加体育活动内容及地点,教师的闲暇时间与体育支出,学院教师体检等情况,建议我院教师注重身体健康,增强健身意识,建议学院为教职工的健康工作和生活创造健身条件和环境。     

基于信息熵评价决策模型的突发公共事件应急处置指挥方案优选

提出基于信息熵评价决策模型对突发公共事件应急处置指挥决策中的作战方案进行优选的方法。首先介绍应急处置指挥决策的概念和过程;其次,分析了信息熵以及基于信息熵评价模型的多属性决策方法;最后,给出基于信息熵的评价决策模型在突发公共事件应急处置指挥方案优选中的应用。实地演练表明,该决策模型在应急指挥决策方案排序与优选是客观合理、切实可行的,能够为应急处置指挥决策提供一定的参考。     

特种设备管理中存在的问题与对策措施

对特种设备管理中的问题进行了深入的分析,并提出了针对性的解决办法。     

近10 a武汉市城市热岛效应演变及其#br# 与土地利用变化的关系

城市化进程的加快,农村人口大量涌入城市,城市布局及局部气候改变等因素使得城市热岛效应问题日益突出,已成为当前城市环境研究热点之一。以武汉市为例,应用遥感技术与地理信息系统技术,选取2004~2015年5个时相Landsat系列影像数据,利用单窗算法反演地表温度,并以此为基础进行热岛强度分级,获取了近10 a武汉市城市热岛效应变化结果,并分析了武汉市11个辖区城市热岛效应动态变化特征及热岛效应与土地利用变化的关系。研究结果表明：（1）自2007年后,武汉市老城区热岛面积持续减少,而新城区热岛面积则持续增加,呈现出以老城区为中心向新城区扩张的趋势,至2015年,新老城区热岛面积仅相差20.74 km2;（2）东西湖区、蔡甸区、江夏区与洪山区是近些年城市热岛面积增长较为显著的辖区,其中江夏区的热岛面积年际变化最大,最高值达95.42 km2;（3）城市热岛效应与土地利用类型的面积年际平均值拟合关系显示,2004~2015年,城市热岛效应与建筑用地的R2值最大,为0.681 2,建筑用地面积的增加是城市热岛强度面积扩张的重要影响因素。     

Experimental assessment of characteristic turbulent scales in two-phase flow of hydraulic jump: from bottom to free surface

A hydraulic jump is a turbulent shear flow with a free-surface roller. The turbulent flow pattern is characterised by the development of instantaneous three-dimensional turbulent structures throughout the air–water column up to the free surface. The length and time scales of the turbulent structures are key information to describe the turbulent processes, which is of significant importance for the improvement of numerical models and physical measurement techniques. However, few physical data are available so far due to the complexity of the measurement. This paper presents an investigation of a series of characteristic turbulent scales for hydraulic jumps, covering the length and time scales of turbulent flow structures in bubbly flow, on free surface and at the impingement point. The bubbly-flow turbulent scales are obtained for Fr = 7.5 with 3.4 × 10⁴ < Re < 1.4 × 10⁵ in both longitudinal and transverse directions, and are compared with the free-surface scales. The results highlight three-dimensional flow patterns with anisotropic turbulence field. The turbulent structures are observed with different length and time scales respectively in the shear flow region and free-surface recirculation region. The bubbly structures next to the roller surface and the free-surface fluctuation structures show comparable length and time scales, both larger than the scales of vortical structures in the shear flow and smaller than the scales of impingement perimeter at the jump toe. A decomposition of physical signals indicates that the large turbulent scales are related to the unsteady motion of the flow in the upper part of the roller, while the high-frequency velocity turbulence dominates in the lower part of the roller. Scale effects cannot be ignored for Reynolds number smaller than 4 × 10⁴, mainly linked to the formation of large eddies in the shear layer. The present study provides a comprehensive assessment of turbulent scales in hydraulic jump, including the analyses of first data set of longitudinal bubbly-flow integral scales and transverse jump toe perimeter integral scales.     

重金属Cr(Ⅵ)、Pb及Cu胁迫对双齿围沙蚕体腔细胞的DNA损伤

为探讨重金属Cr(Ⅵ)、Pb以及Cu对沙蚕体腔细胞DNA的毒性效应,以双齿围沙蚕为受试动物,重金属按不同剂量水平,Cr(Ⅵ):10、100和200 mg· L-1,Pb:5、50和100 mg·L-1,Cu:1、10和20 mg· L-1,分别胁迫沙蚕24 h,以不加任何重金属离子的海水为对照,采用单细胞凝胶电泳技术,检测其体腔细胞DNA损伤程度.结果表明,与空白对照组相比,3种重金属离子的各浓度组都能引起沙蚕体腔细胞DNA损伤,且3种重金属胁迫浓度与细胞DNA损伤程度之间存在显著的剂量-效应关系.双齿围沙蚕可以作为单细胞凝胶电泳的实验材料用于重金属所致环境污染的生物监测指示生物.     

重金属Cr(VI)、Pb及Cu胁迫对双齿围沙蚕体腔细胞的DNA损伤

为探讨重金属Cr(VI)、Pb以及Cu对沙蚕体腔细胞DNA的毒性效应,以双齿围沙蚕为受试动物,重金属按不同剂量水平,Cr(VI):10、100和200 mg·L~(-1),Pb:5、50和100 mg·L~(-1),Cu:1、10和20 mg·L~(-1),分别胁迫沙蚕24 h,以不加任何重金属离子的海水为对照,采用单细胞凝胶电泳技术,检测其体腔细胞DNA损伤程度。结果表明,与空白对照组相比,3种重金属离子的各浓度组都能引起沙蚕体腔细胞DNA损伤,且3种重金属胁迫浓度与细胞DNA损伤程度之间存在显著的剂量-效应关系。双齿围沙蚕可以作为单细胞凝胶电泳的实验材料用于重金属所致环境污染的生物监测指示生物。     

微生物调控对牛粪堆肥的生物特性影响

研究了微生物调控对牛粪堆肥生物特性的影响.结果表明:(1)与对照相比,接菌(添加HM菌剂)处理可使牛粪堆肥提前2d进入高温期,高温持续时间延长2d.即接菌处理的堆肥温度在第4天达到50.5℃,并保持50℃以上的温度14 d;而对照在第6天达到50.0℃,并保持50℃以上的温度12 d.(2)2种处理堆肥的pH总体呈先升高后降低的趋势,接菌处理的堆肥pH上升幅度不大,比对照低0.1～0.5个pH单位.(3)接菌处理有利于提高牛粪堆肥的纤维素酶、蔗糖酶、脲酶活性水平和峰值.(4)脲酶活性与其他因素之间呈显著负相关(p＜0.01),而温度、pH、蔗糖酶活性和纤维素酶活性之间呈显著正相关(p＜0.01).     

Carbonyl emissions from vehicular exhausts sources in Hong Kong

Vehicular emission (VE) is one of the important anthropogenic sources for airborne carbonyls in urban area. Six types of VE-dominated samples were collected at representative locations in Hong Kong where polluted by a particular fueled type of vehicles, including (i) a gas refilling taxis station (liquefied petroleum gas [LPG] emission); (ii) a light-duty passenger car park (gasoline emission); (iii) a minibus station (diesel emission); (iv) a single-deck-bus depot (diesel emission); (v) a double-deck-bus depot (diesel emission); and (vi) a whole-food market entrance for light- and heavy-duty vehicles (diesel emission). A total of 15 carbonyls in the samples were quantified. Formaldehyde was the most abundant carbonyl among the VE-dominated samples, and its contribution to the total quantified amount on a molar basis ranged from 54.8% to 60.8%. Acetaldehyde and acetone were the next two abundant carbonyls. The carbonyls were quantified at three roadside locations in Hong Kong. The highest concentrations of formaldehyde and acetaldehyde, 22.7 +/- 8.4 and 6.0 +/- 2.8 microg/m3, respectively, were determined in the samples collected at a main transportation gate for goods between Hong Kong and Mainland China. The total quantified carbonyl concentration, 37.9 +/- 9.3 microg/m3, was the highest at an entrance of a cross-harbor tunnel in downtown area. The theoretical carbonyls compositions of the three roadside locations were estimated according to the VE-dominated sample profiles and the statistics on vehicle numbers and types during the sampling period. The measured compositions of formaldehyde were much higher than the theoretical compositions in summer, demonstrating that photochemical reactions significantly contributed to the formaldehyde production in the roadsides.