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161.
Jun-Ling Wang Hao-Jun Zhang Hui-Ling Wang Ju-Wei Wang Pan-Hong Gou Zhong-Hui Ye 《毒物与环境化学》2015,97(10):1394-1407
The molecular basis of male reproduction for cross-regulation between androgen and thyroid hormone axes is still rudimentary. This study aims to define a possible mechanism of hypothyroidism-induced reproductive influence with respect to sex hormone, mineral, sperm motility, oxidative stress, c-Fos expression, cell cycle, and apoptosis in rat testes. The Wistar rats were randomly divided into control group (NS) and hypothyroidism group [1 ml/100g BW/day, 0.1% propylthiouracil (PTU)] by intragastric gavage for 60 days. Blood samples were collected to measure the serum levels. The epididymis was excised to measure sperm motility and testes were excised to measure mineral, oxidative stress, c-Fos expression, cell cycle, and apoptosis. After 60 days, body weight, relative testes weight, triiodothyronine, and total thyroxine were all significantly decreased, whereas thyroid stimulating hormone was increased in the hypothyroidism group. A significant increase in sex hormone level of estradiol (E2) and significant decreases in testosterone (T) and T/E2 ratio were observed following PTU treatment. And sperm quality was also significantly changed. There were significant decreases in the contents of calcium (Ca2+) and zinc (Zn2+). On the other hand, malondialdehyde and hydrogen peroxide contents significantly increased, whereas the activity of superoxide dismutase, catalase and nitric oxide synthase and nitric oxide content significantly decreased in hypothyroid rats. The mRNA and protein expressions of c-Fos decreased significantly. The cell percentage in G0/G1 phase increased significantly, whereas decreased significantly in S and G2/M phases. Also, a significant increase in testicular cell apoptosis was observed in hypothyroid-treated rats. These results suggested that hypothyroidism could affect reproductive function in the form of changed sex hormone levels, sperm motility and testicular Ca2+ and Zn2+, and enhanced oxidative stress leading to c-Fos abnormal expression and increased apoptosis. 相似文献
162.
Liu YANG Ye WU Jiaqi LI Shaojie SONG Xuan ZHENG Jiming HAO 《Frontiers of Environmental Science & Engineering》2015,9(4):675
Mass concentrations of PM10, PM2.5 and PM1 were measured near major roads in Beijing during six periods: summer and winter of 2001, winter of 2007, and periods before, during and after the 2008 Beijing Olympic Games. Since the control efforts for motor vehicles helped offset the increase of emissions from the rapid growth of vehicles, the averaged PM2.5 concentrations at roadsides during the sampling period between 2001 and 2008 fluctuated over a relatively small range. With the implementation of temporary traffic control measures during the Olympics, a clear “V” shaped curve showing the concentrations of particulate matter and other gaseous air pollutants at roadsides over time was identified. The average concentrations of PM10, PM2.5, CO and NO decreased by 31.2%, 46.3%, 32.3% and 35.4%, respectively, from June to August; this was followed by a rebound of all air pollutants in December 2008. Daily PM10 concentrations near major roads exceeded the National Ambient Air Quality Standard (Grade II) for 61.2% of the days in the non-Olympic periods, while only for 12.5% during the Olympics. The mean ratio of PM2.5/PM10 near major roads remained relatively stable at 0.55 (±0.108) on non-Olympic days. The ratio decreased to 0.48 (±0.099) during the Olympics due to a greater decline in fine particles than in coarse-mode PM. The ratios PM1/PM2.5 fluctuated over a wide range and were statistically different from each other during the sampling periods. The average ratios of PM1/PM2.5 on non-Olympic days were 0.71. 相似文献
163.
Guixiang ZHANG Xitao LIU Ke SUN Ye ZHAO Chunye LIN 《Frontiers of Environmental Science & Engineering》2010,4(4):421-429
Batch sorption experiments were conducted to evaluate the sorption behavior of tetracycline (TC, H3L) on sediments and soils in the presence and absence of cadmium (Cd), as affected by pH and properties of sediments and soils. The results indicated stronger nonlinearity and higher capacity of TC sorption on sediments than on soils. Sorption of TC also strongly depended on environmental factors and sediment/soil properties. Lower pH facilitated TC sorption through a cation exchange mechanism, which also took place at pH values above 5.5, where TC existed as a zwitterion (H2L0) or anions (HL- and L2-). When pH was above 7, however, ligand-promoted dissolution of TC might occur due to TC weakening the Al-O bond of aluminum oxide and the Fe-O bond of iron oxide. Natural organic matter (NOM) plays a more important role in TC sorption than cation exchange capacity (CEC) and clay contents. The presence of Cd (II) increased TC sorption on both sediments and soils, which resulted from the decrease of equilibrium solution pH caused by Cd2+ exchange with H+ ions of sediment/soil surfaces. The increase of TC sorption was also related to the formation of TC-Cd complexes, where Cd2+ acted as a bridge between the sediment/soil and TC. 相似文献
164.
沈阳地区霾的环境特征研究 总被引:6,自引:0,他引:6
利用沈阳市1961—2009年的气象资料,分析了霾天气出现的年季特征及其天气形势特征。利用边界层气象资料与污染物质量浓度资料对特定的霾过程从边界层到污染物质量浓度条件进行了分析。结果表明:沈阳地区霾的出现呈现逐年上升的趋势,近5 a平均每年为120 d左右,目前霾天数已经占到了全年的30%~40%。冬秋季节出现霾天气较多,秋冬两季霾日数占全年霾日总数的75%。凌晨到上午是霾出现的高发期,02—08时霾出现频率占总霾数的44.5%。霾的出现主要发生在冬秋季节冷空气势力不强,大气扩散能力较弱,边界层出现逆温时刻。接地逆温层厚度常常稳定在200~300 m高度左右,PM10质量浓度与能见度(霾)呈负相关,相关系数-0.402 7。风速与能见度(霾)呈正相关,相关系数为0.886 4。 相似文献
165.
Species immigration history can structure ecological communities through priority effects, which are often mediated by competition. As competition tends to be stronger between species with more similar niches, we hypothesize that species phylogenetic relatedness, under niche conservatism, may be a reasonable surrogate of niche similarity between species, and thus influence the strength of priority effects. We tested this hypothesis using a laboratory microcosm experiment in which we established bacterial species pools with different levels of phylogenetic relatedness and manipulated the immigration history of species from each pool into microcosms. Our results showed that strong priority effects, and hence multiple community states, only emerged for the species pool with the greatest phylogenetic relatedness. Community assembly also resulted in a significant positive relationship between bacterial phylogenetic diversity and ecosystem functions. Interestingly, these results emerged despite a lack of phylogenetic conservatism for most of the bacterial functional traits considered. Our results highlight the utility of phylogenetic information for understanding the structure and functioning of ecological communities, even when phylogenetically conserved functional traits are not identified or measured. 相似文献
166.
建立了便携式顶空/气相色谱-质谱法测定硬质聚氨酯泡沫和组合聚醚中一氟三氯甲烷(CFC-11)、二氟二氯甲烷(CFC-12)、二氟一氯甲烷(HCFC-22)及一氟二氯乙烷(HCFC-141b)的定性分析方法,系统考察了色谱柱、顶空体系、顶空温度和顶空时间对测定结果的影响。结果表明,DB-WAX色谱柱对目标物质的分离效果最好,顶空温度为50℃、顶空时间为10 min条件下,目标物质的检测灵敏度最高。在优化条件下,硬质聚氨酯泡沫取样体积为1 cm3时,4种目标物的方法检出限为0.6~0.8μg;组合聚醚取样量为10 mg时,4种目标物的方法检出限为0.5~0.6μg。该方法具有较高的灵敏度,定性准确,适用于实际样品的现场快速定性分析。 相似文献
167.
The microscopic reaction mechanisms of diphenylether (DPE) and 4-bromodiphenylether (4-BrDPE) with nitrous acid (HNO(2)) in the absence of O(2) have been explored by the 355nm laser flash photolysis. It was proposed that OH radical, from the photolysis of HNO(2), added to DPE forms the C(12)H(10)O-OH adduct while added to 4-BrDPE forms the 4-BrDPE-OH and 4-BrOH-DPE adducts. The first-order decay rate constants of the C(12)H(10)O-OH adduct, 4-BrDPE-OH adduct and 4-BrOH-DPE adduct were measured to be (1.86+/-0.14)x10(5)s(-1), (2.19+/-0.04)x10(5)s(-1) and (1.56+/-0.03)x10(5)s(-1), respectively. The final photolysis products of DPE and HNO(2) identified by GC/MS analysis were phenol, o-hydroxydiphenylether, p-hydroxydiphenylether and p-nitrodiphenylether, while the final photolysis product of 4-BrDPE and HNO(2) identified by LC/MS analysis was mainly the dimer. 相似文献
168.
169.
170.
Bifenthrin is a chiral synthetic pyrethroid insecticide that has been commonly used for agricultural and domestic pest control over the past decades. Due to its widespread application, residues of bifenthrin has been frequently detected in environmental media, residential areas and biota, thus posing potential risks to the health of wildlife and humans. In particular, bifenthrin exhibits high acute lethal toxicity to aquatic species, and it is the primary contributor to the toxicity of insecticides in waters. Additionally, bifenthrin can also cause sublethal toxic effects on various non-target organisms, including developmental toxicity, neurobehavioral toxicity, oxidative damage, immune toxicity and endocrine disrupting effects. Here we review recent studies about the fate of bifenthrin in the environment and biological systems, the toxicity of the chiral parent compound bifenthrin and the toxic effects of main metabolites. The adverse effects of bifenthrin, identified from both in vitro and in vivo studies, and the potential underlying mechanisms are presented. We discuss the enantiomeric difference in the toxicological effects of bifenthrin, since enantiomers of chiral compounds show different interactions with biological systems. Pyrethroid insecticides metabolites are not acutely toxic, but they have sublethal toxicity, such as endocrine disrupting effects and immunotoxicity. We provide emerging evidence for toxic effects of several main metabolites. 相似文献