电-Fenton法降解TNT弹药销毁废水

2,4,6-三硝基甲苯(TNT)弹药销毁废水的色度高、毒性大、不易生化降解。采用电Fenton法降解TNT弹药销毁废水。研究了电压(U)、极板间距(D)、初始p H、H2O2投加量(M)、n(Fe2+)/n(H2O2)摩尔比及反应时间(T)对废水COD去除率的影响;优化了反应条件:在U=8 V,D=1 cm,初始p H=3,M(H2O2)=0.0916 mol/L,n(Fe2+)/n(H2O2)=1∶30,T=4 h的条件下,废水的COD去除率大于86%,出水的其余指标如色度、氨氮、p H、TNT含量等各指标经国标法测量均达标。通过对反应动力学方程的分析,得出该实验基本符合二级反应动力学。该法操作简单实用,是处理该废水行之有效的方法。     

固定化小球藻与活性污泥的共生系统处理含锌废水

研究固定化小球藻与活性污泥的共生系统对含锌废水中Zn2+的去除效果,分析菌藻状态、初始Zn2+浓度、pH、固定化菌藻小球投加量和菌藻体积比等5个因素对固定化菌藻共生系统去除Zn2+的影响。结果表明,固定化活性污泥、固定化小球藻和固定化菌藻对Zn2+的去除效果均优于悬浮小球藻,其中固定化菌藻对Zn2+的去除效果最好;废水中初始Zn2+浓度小于100 mg/L时,固定化菌藻系统对废水中Zn2+的去除率达到90.5%;固定化菌藻系统去除废水中Zn2+的最佳条件是:初始Zn2+浓度为80 mg/L,pH=7,固定化小球投加量为80 mL,菌藻体积比为1∶2。     

基于湖北省12个中小型湖泊的水环境遥感监测应用示范

以《湖北省水环境遥感监测示范系统》为数据处理平台,对2012—2014年湖北省大东湖水网、梁子湖水系和汤逊湖水系共计12个湖泊的水质类别以及营养状态级别进行遥感监测,并对比实测数据进行精度评价。结果表明:遥感监测的梁子湖、豹澥湖和严西湖水质相对较好,杨春湖、北湖和南湖水质相对较差且富营养化状况较为严重。该系统能很好地实现对水质优良达标湖泊以及富营养化湖泊的识别。对示范区域各湖泊水质类别和营养状态级别的遥感监测,基本上能满足业务化运行的需求。个别湖泊遥感监测精度较低,主要表现为遥感监测的湖泊水质类别和营养状态级别均要优于实测的结果。系统对于面积相对较大的湖泊遥感监测精度更高。     

Effects of Permafrost Degradation on Soil Hydrological Processes in Alpine Steppe on the Qinghai-Tibet Plateau

Permafrost degradation is prevalent on the Qinghai-Ti-bet Plateau. This may lead to changes in water and heat transition in soils and thus affect the structure and function of ecosystems. In this paper...     

Identifying sources and assessing potential risk of heavy metals in soils from direct exposure to children in a mine-impacted city, Changsha, China

Heavy metal pollutants in soils can usually enter the human body and pose heath risks through a soil-crop-human body pathway (indirect exposure) or soil-human body pathway (direct exposure). Previous studies often neglected the direct exposure in human health risk assessment, especially for children. We collected surface soil samples from urban and suburb areas in Changsha City, China, to analyze the content ofAs, Cd, Hg, Ni, Pb, and Zn. A combination of principal component analysis, geostatistics, and triangulated irregular network (TIN) model was successfully used to discriminate the sources of heavy metals. The direct exposure method, sequential indicator simulation, and geographical information system (GIS) technologies were used to perform a health risk assessment of heavy metal exposure to children living in the study area. Results show that heavy metal contamination in Changsha may originate from coal usage and industrial activities. One thousand equiprobable realizations suggest that not all sites within the study area may be suitable for housing or allotments without remediation. Most high hazard indexes are located in the suburb and mining areas. Moreover, arsenic presents a high health risk in comparison with other elements. Compared with inhalation and dermal contact in direct soil exposure, soil ingestion is the largest contribution to potential health risks for children. This study indicates that we should attach great importance to the direct soil exposure for children's health.     

Sulfur dioxide induces apoptosis via reactive oxygen species generation in rat cardiomyocytes

Environmental Science and Pollution Research - Epidemiological evidence suggests that the incidence and mortality of cardiovascular diseases are closely related to sulfur dioxide (SO2). In the...     

实际污水与模拟污水活性污泥系统的特性差异

实验中经常采用人工配置的模拟生活污水,为了研究其与实际生活污水活性污泥系统的特性差异,采用2个序批式间歇反应器(SBR)进行平行实验(厌氧、好氧方式运行),系统地考察了在进水主要组分和运行参数相同的情况下,不同原水对活性污泥系统脱氮、除磷、比好氧速率、污泥絮体形态和出水水质等方面的影响。结果表明,模拟污水系统的硝化活性强于实际污水系统,两者的平均硝化速率分别为7.43 mg NH4+-N/(L.h)和5.55 mg NH4+-N/(L.h)。在前置厌氧段,模拟污水系统的释磷量比实际污水系统高出36.45%。两者在后续好氧阶段都能够充分吸磷。模拟污水系统的平均比好氧速率(SOUR)高达64.54 mg O2/(g MLSS.h),而实际污水系统的则只有32.81 mg O2/(g MLSS.h)。模拟污水系统的污泥絮体疏松,粒径小,形状不规则,沉降性差,沉后出水平均悬浮物浓度(SS)为20 mg/L;而实际污水系统的污泥絮体则密实、粒径大,沉降性好,沉后水十分清澈,SS几乎检测不出。     

基于荧光素酶发光检测体系的几种工业污染物综合毒性评价

利用化工污染物能抑制荧光素酶催化发光反应这一特性,对水质中6种化工化合物分别进行毒性测试,建立一种快速检测水质中化工污染物毒性的生物学方法。实验结果表明,对苯二酚、4-氨基酚、苯胺、氯仿、盐酸邻联甲苯胺和硫柳汞的EC50值分别为:5.563、10.225、20.236、38.432、8.827和0.6 mg/L,6种污染物毒性大小依次为:硫柳汞>对苯二酚>盐酸邻联甲苯胺>4-氨基酚>苯胺>氯仿,相关系数>0.95。该方法为进一步研究基于荧光素酶反应体系检测水质中化工污染物综合毒性的生物传感器方法奠定基础。     

电除尘器阳极板振打加速度分布规律与仿真设计

应用有限元分析软件LS-DYNA对影响电除尘器阳极板振打效果的锤头质量、锤臂长、悬挂方式及极板厚度等因素进行了数值仿真,分析了各因素对阳极板振打加速度分布的影响;利用分析结果对振打装置的结构进行了改进设计,结果表明可以较好地满足工业除尘的要求。本研究提出的电除尘器阳极板振打仿真方法为电除尘器振打装置的参数设计提供了一条新的途径。     

矿化垃圾生物反应床处理含酚废水工艺研究

研究了矿化垃圾生物反应床处理含酚废水的工艺参数.矿化垃圾生物反应床在经过驯化后,形成了稳定的微生物系统,反应床对有机酚具有较高的去除率.有机酚的去除率受湿干比影响较大,随着配水速率的提高,反应床对有机酚的去除率逐渐下降,配水速率大于0.342 cm/min时,去除率急速下降.在进水有机酚质量浓度为20 mg/L,连续配水时间6 h,湿干比为1∶8,配水速率为0.254 cm/min的条件下,反应床出水可达到或接近国家三级排放标准.