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421.
随着拟除虫菊酯类农药使用量不断增加,产生的农药残留问题对生态环境和人类健康造成了危害.对降解拟除虫菊酯类农药的微生物种类、降解酶和降解机制及降解酶基因克隆和构建工程菌等方面进行综述,旨在为研究和开发微生物降解拟除虫菊酯类农药残留提供参考. 相似文献
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Liting Yang Chunlan Dai Lijun Ma Shaoquan Lin 《Journal of Polymers and the Environment》2011,19(1):189-195
The conjugated soybean oil was synthesized through the isomerization reaction of soybean oil to transformed the structure
of linoleic acid into conjugated linoleic acid structure, and Rhodium complexes (RhCl(Pph3)3) was used as catalyst. The efficiency on the conjugation of catalyst RhCl (Pph3)3, tin dichloride dehydrate (SnCl2·2H2O) and triphenylphosphine (Pph3) were evaluated. The results showed when RhCl(Pph3)3, SnCl2·2H2O and Pph3 are 9.25, 9.0 and 13.1 mg in 100 g soybean oil respectively, the highest conversion of conjugation achieved 96%. The free
radical copolymerization of conjugated soybean oil with acrylonitrile (AN) and dicyclopentadiene (DCP) was studied. AIBN was
used as the initiator. FT-IR and 1H-NMR results indicates that the conjugated soybean oil with AN and DCP did occur free radical copolymerization with the initiator
AIBN. The product is light yellow powder. The thermal properties of the soy-based copolymer were investigated by TG and DSC.
The initial degradation temperature of polymers is higher then 250 °C. 相似文献
424.
Unusual Salinity Conditions in the Yangtze Estuary in 2006: Impacts of an Extreme Drought or of the Three Gorges Dam? 总被引:1,自引:0,他引:1
During the extreme dry year of 2006, abnormal salinity conditions in the Changjiang Estuary of the Yangtze River occurred
in partial coincidence with the second impoundment phase of the TGD (Three Gorges Dam). Analysis of discharge observations
in the upper reaches of the estuary and of salinity observations in the estuary as a whole reveals that in 2006 salinity was
over 100 mg/l during 275 days, over 250 mg/l during 75 days and over 400 mg/l during 48 days. It is well known that this is
due to extreme low discharges from the upper catchment area into the estuary. Moreover, large amounts of water consumed along
the lower reaches of the Yangtze River can also aggravate the low discharges that lead to stronger saltwater intrusion in
the estuary. Of the 75 days that salinity was over 250 mg/l, the low discharge was decreased further by 10 to 20% due to water
consumption. The additional impact of the impoundment phase of the TGD (lasting 37 days in autumn) was noticeable only during
7 days in 2006. During that period, the relative contributions of the TGD and the water consumption in the lower reaches of
the Yangtze River amounted to 70 and 30%, respectively. It may be concluded that the impact of the second impoundment phase
of the TGD on salinity intrusion in the estuary was modest, while the extreme drought of 2006 was the dominant cause. 相似文献
425.
催化湿式氧化法处理高浓度唑螨酯生产废水的研究 总被引:2,自引:1,他引:1
对唑螨酯生产过程中产生的高浓度实际废水采用催化湿式氧化技术在鼓泡式固定床反应器连续反应装置上进行处理。实验表明,制备的复合负载型催化剂CuO-MnO2-Cr2O3/ZrO2-CeO2在处理该废水时具有较好的催化活性。通过对反应温度、反应压力、反应空速、气液比和进水pH等工艺条件的考察,得出最佳的工艺条件为:反应温度=220℃,反应压力=5.8 MPa,空速=1.8 h-1,V(气)∶V(水)=260∶1,进水pH=9,在此条件下COD去除率达到95.2%。 相似文献
426.
高职数学教学必须加强数学思想方法的教学 总被引:1,自引:0,他引:1
代伟 《中国环境管理干部学院学报》2008,18(4):109-111
数学思想方法是数学知识的核心,是数学的精髓和灵魂,是研究数学理论和运用数学解决实际问题的指导思想。本文针对目前高职数学教学中存在的数学思想方法教学重视不够以及教法上随意性的现状,提出通过加强数学史和基本数学思想方法的介绍,以及倡导“问题解决”的教学模式来提高学生的数学素养。 相似文献
427.
Yang DB Wang YQ Liu WX Tao S 《Journal of environmental science and health. Part. B》2008,43(4):307-313
Recent studies have focused on enantiomeric behaviors of chiral organochlorine pesticides (OCPs) in biotic matrix because they provide insights into the biotransformation processes of chiral OCPs. In the present paper, a double in-line column chromatographic method was developed to effectively remove the lipid impurity in different biotic samples for clean-up of OCPs. After an initial Soxhlet extraction of OCPs from the biotic samples by a mixture of acetone and dichloromethane (DCM), dimethyl sulfoxide (DMSO) was directly added to the extract, and low boiling point solvents (acetone and DCM) were then evaporated. OCPs remained in DMSO were eluted via column 1 filled with silicon gel, and subsequently passed through column 2 packed with 15% deactivated florisil. This novel method was characterized by significant time and solvent savings. The recovery rates of alpha-HCH (hexachlorocyclohexane), beta-HCH, gamma-HCH and delta-HCH were 78.5+/-3.1%, 72.4+/-7.7%, 72+/-4.0% and 70.0+/-8.7%, respectively, and 92.5+/-3.8%, 79.7+/-6.7% and 83.4+/-6.5% for 1,1-dichloro-2-(2-chlorophenyl)-2-(4- chlorophenyl) ethylene (o,p'-DDE), 1,1-dichloro-2-(2-chlorophenyl)-2-(4-chloro phenyl)ethane (o,p'-DDD) and 1,1,1-trichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl) ethane (o,p'-DDT), separately. In addition, the separation efficiencies of the target compounds by both achiral and chiral gas chromatographic columns were satisfactory using the established method. Therefore, the double in-line column chromatography was a useful alternative method for pretreatment of OCPs in different biotic samples. 相似文献
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Fourteen surface sediment samples were collected from Lanzhou Reach of Yellow River, China in July 2005. The concentrations of 16 priority polycyclic aromatic hydrocarbons (PAHs) were determined by gas chromatography equipped with a mass spectrometry detector (GC-MS). Total concentrations of the PAHs ranged from 464 to 2621 ng/g dry weight. Sediment samples with the highest PAH concentrations appeared at the downstream of Lanzhou City, where there was the biggest wastewater discharge pipeline from Lanzhou Oil Refinery Factory and Lanzhou Chemical Industry Company. Municipal sewage also contributed to the PAH contamination in the sediments. A correlation existed between the sediment organic carbon content (f(oc)) and the total PAH concentrations (r(2)=0.57), suggesting that sediment organic carbon content played an important role in controlling the PAHs levels in the sediments. According to the observed molecular indices, PAHs contamination in Lanzhou Reach of Yellow River originated both from the high-temperature pyrolytic processes and from the petrogenic source, showing a mixed PAH input pattern, which was also confirmed by the results of a principal component analysis (PCA). According to the numerical effect-based sediment quality guidelines (SQGs) of the United States, the levels of PAHs at most studied sites in Lanzhou Reach of Yellow River should not exert adverse biological effects. Although at some sites (such as S10, S12, etc.) one PAH may exceed the effects range low (ERL), individual PAH did not exceed the effects range median (ERM). The results indicated that sediments in all sites should have potential biological impact, but should have no impairment. 相似文献