Pyrolysis characteristics of the mixture of printed circuit board scraps and coal powder

Thermogravimetric (TG) analysis and infrared spectroscopy were used to analyze the pyrolysis characteristics of printed circuit board scraps (PCBs), coal powder and their mixtures under nitrogen atmosphere. The experimental results show that there is a large difference between waste PCBs and coal powder in pyrolysis processing. The pyrolysis properties of the mixing samples are the result of interaction of the PCBs and coal powder, which is influenced by the content of mixture. The degree of pyrolysis and pyrolysis properties of the mixture are much better than that of the single component. The TG and the differential thermogravimetric (DTG) curves of the PCBs mixed with coal powder move towards the high-temperature zone with increasing amount of coal powder and subsequently the DTG peak also becomes wider. The Coats–Redfern integral method was used to determine the kinetic parameters of pyrolysis reaction mechanism with the different proportion of mixture. The gas of pyrolysis mainly composes of CO₂, CO, H₂O and some hydrocarbon. The bromide characteristic absorption peak has been detected obviously in the pyrolysis gas of PCBs. On the contrary, the absorption peak of the bromide is not obvious in pyrolysis gas of the PCBs samples adding 40% coal powder.     

Reliability analysis of subsea blowout preventer control systems subjected to multiple error shocks

Two configurations of subsea blowout preventer (BOP) distributed control systems, which are triple modular redundancy (TMR) control system and double dual modular redundancy (DDMR) control system, are presented. With respect to common-cause failures, the performances of the two systems are evaluated by using Markov method with multiple error shock model. Due to the complexity, each system is split into three independent modules, and the corresponding Markov models are proposed subsequently. The probability of failure on demand, availability and reliability of the systems are evaluated by merging the independent Markov modules by Kronecker product approach. The results indicate that a same safety integrity level of SIL3 can be attained for the two configurations, which satisfies the requirement of subsea BOP control system, even though both of them have some advantages and shortcomings. In addition, for TMR control system, the effects of multiplicity distribution of multiple error shock and mean time to repair on reliability performances are studied.     

气相色谱法测定饮用水中三氯乙烯含量的不确定度评定研究

分析和评定气相色谱法测定饮用水中三氯乙烯含量过程中引入的不确定度,分析了标准物质、分析操作、重复性测定等方面对不确定度的影响,实验表明在置信水平95%,包含因子k=2时,水中三氯乙烯测量结果的相对扩展不确定度为8.31%,三氯乙烯含量为3.17μg/L,扩展不确定度为0.263μg/L,测试过程的随机效应引入的不确定度对合成不确定度的贡献最大.     

新乡市声环境质量现状及其改善对策研究

以中原城市群强市-新乡市为例,介绍城市环境噪声的声源构成主要以工业噪声和社会生活噪声为主。随着城镇化规模的扩大,近年来的噪声监测值总体呈下降趋势,但道路交通噪声和社会生活噪声有增高趋势。结合声环境质量现状,提出了合理规划功能区布局、加强声环境管理、利用城市绿地降低噪声、提高单体建筑规划设计水平等改善对策措施。     

Impacts of Human Behavioral Heterogeneity on the Benefits of Probabilistic Flood Warnings: An Agent‐Based Modeling Framework

Flood forecasts and warnings are intended to reduce flood‐related property damages and loss of human life. Considerable research has improved flood forecasting accuracy (e.g., more accurate prediction of the occurrence of flood events) and lead time. However, the delivery of improved forecast information alone is not necessarily sufficient to reduce flood damage and loss of life, as people have varying responses and reactions to flood warnings. This study develops an agent‐based modeling framework that evaluates the impacts of heterogeneity in human behaviors (i.e., variation in behaviors in response to flood warnings), as well as residential density, on the benefits of flood warnings. The framework is coupled with a traffic model to simulate evacuation processes within a road network under various flood warning scenarios. The results show the marginal benefit associated with providing better flood warnings is significantly constrained if people behave in a more risk‐tolerant manner, especially in high‐density residential areas. The results also show significant impacts of human behavioral heterogeneity on the benefits of flood warnings, and thus stress the importance of considering human behavioral heterogeneity in simulating flood warning‐response systems. Further study is suggested to more accurately model human responses and behavioral heterogeneity, as well as to include more attributes of residential areas to estimate and improve the benefits of flood warnings.     

我国跨区域水环境行政管理体制之检讨与完善

我国对水资源实施的是流域管理与行政区域管理相结合的管理体制。流域管理机构的地位不明确,在监督管理中没有完全独立的权限,基本上属于一种协调机构,因此完善我国的跨区域水环境行政管理体制具有重要的现实意义。从尽早完善水环境保护管理体制立法、明确各环境监督管理部门的具体职责、健全环境保护跨部门以及中央与地方的协调机制、成立跨区域环境保护管理协调机构、明确流域管理机构在流域水环境保护中的行政执法地位等方面作出了探讨,以利于更好地保护跨区域的水资源。     

Dithizone-functionalized C18 online solid-phase extraction-HPLC-ICP-MS for speciation of ultra-trace organic and inorganic mercury in cereals and environmental samples

A simple and efficient dithizone-functionalized solid-phase extraction (SPE) procedure, online coupled with high-performance liquid chromatography (HPLC)-inductively coupled plasma mass spectrometry, was developed for the first time for enrichment and determination of ultra-trace mercury (Hg) species (inorganic divalent Hg (Hg(II)), methylmercury (CH₃Hg(II)) and ethylmercury (C₂H₅Hg(II)) in cereals and environmental samples. In the proposed method, functionalization of the commercial C₁₈ column with dithizone, enrichment, and elution of the above Hg species can be completed online with the developed SPE device. A simple solution of 2-mercaptoethanol (1% (V/V)) could be used as an eluent for both the SPE and HPLC separation of Hg species, significantly simplifying the method and instrumentation. The online SPE method was optimized by varying dithizone dose, 2-mercaptoethanol concentration, and sample volume. In addition, the effect of pH, coexisting interfering ions, and salt effect on the enrichment was also discussed. Under the optimized conditions, the detection limits of Hg species for 5 mL water sample were 0.15 ng/L for Hg(II), 0.07 ng/L for CH₃Hg(II), and 0.04 ng/L for C₂H₅Hg(II) with recoveries in the range of 85%–100%. The developed dithizone-functionalized C₁₈ SPE column can be reused after a single functionalization, which significantly simplifies the enrichment step. Moreover, the stability of Hg species enriched on the SPE column demonstrated its suitability for field sampling of Hg species for later laboratory analysis. This environment-friendly method offers a robust tool to detect ultra-trace Hg species in cereals and environmental samples.     

浅谈陆上石油钻井现场安全监督的考核与管理

石油行业,特别是石油钻井行业历来被认为是个高风险、多事故的行业.受钻井公司HSE 管理委员会的委派,安全监督对所负责施工现场的QHSE 管理实施全员、全方位、全天候、全过程的监督管理;监督现场所有的施工单位、人员、施工作业严格执行钻井公司QHSE 管理体系的相关规定,对生产现场违章指挥、违章操作、违反劳动纪律及其它违反企业安全管理规章制度、体系文件的现象进行纠正、制止并给予经济处罚.为了规范安全监督人员的行为和管理工作,公正、合理地评价每位驻井安全监督的工作业绩和管理水平,应通过加大对安全监督的考核力度,激励安全监督人员加强理论知识的学习和责任心,不断提高生产现场的监督管理水平.     

玉米淀粉废水的处理技术

本文介绍玉米淀粉废水的特性,废水处理工艺路线,工艺设计中应着重考虑的问题及设计参数的选择。     

一株产黑色素海洋细菌的筛选、鉴定及发酵条件优化

从山东近岸海域海水中分离得到一株产黑色素细菌Sl,通过对S1菌株的菌落形态观察、生理生化性质检验及16SrDNA序列测定,初步鉴定为明亮发光杆菌(Photobacterium phosphoreum).为了提高S1菌株黑色素产量,采用单因素实验设计对S1菌株进行发酵条件优化,结果表明当发酵条件为L-酪氨酸0.75 g/...