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991.
Feasibility study of photoelectrochemical degradation of methylene blue with three-dimensional electrode-photocatalytic reactor 总被引:14,自引:0,他引:14
The photoelectrochemical degradation of methylene blue in aqueous solution was investigated with three-dimensional electrode-photocatalytic reactor. It was found that the methylene blue could be degraded more efficiently by photoelectrochemical process than by photocatalytic oxidation or electrochemical oxidation alone. The decolorization efficiency and COD reduction were 95% and 87% for a photoelectrochemical process, respectively, while they were only 78% and 68% for a single electrochemical process and 89% and 71% for a single photochemical process. The TOC reduction of the former also reached as high as about 81% within a reaction time of 30.0 min. And these degradation reactions conformed to pseudo-first-order kinetics. 相似文献
992.
Comparison of models for describing measured VOC emissions from wood-based panels under dynamic chamber test condition 总被引:7,自引:0,他引:7
Measured emission factors are the experimental data used to represent emission characteristics of volatile organic compounds (VOCs) from testing materials under dynamic chamber test conditions. A simple empirical model that describes the measured emission factors will be very useful for practical purposes. In this study, a power law model was compared with a widely used first-order exponential decay model in their ability to describe measured emission factors of wood-based panel materials. It was demonstrated that the power law model is a better choice than the first-order model for describing emission characteristics for short-term (less than 100 h) experimental data. The power law model was also more superior in predicting long-term (up to 900 h) emission factors. 相似文献
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998.
vis/H2O2/草酸铁处理活性艳红染料的实验研究 总被引:1,自引:0,他引:1
采用vis/H2O2/草酸铁法,对活性艳红染料废水进行处理.研究了H2O2、K2C2O4和Fe2(SO4)3·7H2O的投加量、pH值和光照时间等因素对染料废水处理效果的影响和最佳处理条件.结果表明,pH值2.5;30%H2O2的投加量0.1 mL;0.1 mol/L Fe2(SO4)3·7H2O的投加量1.0 mL;0.1 mol/L K2C2O4的投加量1.5 mL;光照时间40 min的最佳条件下,70 mg/L的活性艳红模拟染料废水脱色率可达99.82%.通过对vis/H2O2/草酸铁法和Fenton法、H2O2法、草酸铁法等方法进行对比实验,vis/H2O2/草酸铁法明显优于其他方法,是一项有研究价值和开发应用前景的污染治理新技术. 相似文献
999.
以渗滤液回灌为核心的填埋场生化反应器是当今国际固体废物研究的新方向 ,其具有减少渗滤液处理难度和加速填埋场稳定化的作用 ,其中控制填埋场水分是关键。本文通过对填埋场水分运移特征的分析 ,建立了渗滤液回灌条件下 ,生化反应器填埋场水分迁移的饱和 -非饱和三维非稳定数学模型 ,并求其有限单元数值解 ,定量模拟和预报不同回灌条件下填埋场水分的时空分布规律并进行实用研究。针对重庆市长生桥卫生填埋场设计情况和实际条件 ,运移模拟模型分析了水平沟和竖式井回灌条件下填埋场内水分的分布规律 ,证明了协同回灌方式的有效性 相似文献
1000.
Jiang W Zhang S Shan XQ Feng M Zhu YG McLaren RG 《Environmental pollution (Barking, Essex : 1987)》2005,138(2):278-284
Laboratory batch experiments were carried out to study the adsorption of arsenate on 16 Chinese soils with different physicochemical properties. Wide differences in arsenate adsorption were observed, and the Jiangxi and Hubei soils were more effective sorbents for arsenate than other soils. The Langmuir one-surface and two-surface equations were used to model the arsenate adsorption data. Except for the Jiangxi and Hubei soils, the Langmuir one-surface equation gave reasonably good fits to the arsenate adsorption data. However, the Langmuir two-surface equation generally provided a better fit than the Langmuir one-surface equation. For soils with relative high organic matter (OM), dissolved organic carbon (DOC) or extractable phosphate, the Langmuir one-surface and two-surface equations described the adsorption isotherms similarly. In contrast, for soils with relatively low contents of OM, DOC or extractable phosphate, the Langmuir two-surface equation gave the better fit to the arsenate adsorption data. 相似文献