武汉市湖泊侵占现状分析与洪涝灾害

湖泊是集提供水源、补充地下水、调节径流、抵御洪涝灾害、改善微小气候等功能为一体的重要水域,是湿地的重要组成部分。分析武汉市湖泊侵占与洪涝灾害现状发现,武汉市湖泊侵占现状严重,面积锐减,从而影响了湖泊在防洪排涝体系中的重要作用,是造成了武汉市历年遭受特大洪涝灾害的原因之一。2016年的洪涝灾害应该进一步敲醒警钟,保护武汉市湖泊资源迫在眉睫。为政府决策部门、职能部门、科研机构保护武汉市湖泊资源提供依据。     

Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments of rivers and an estuary in Shanghai, China

Concentrations, spatial distribution and sources of 17 polycyclic aromatic hydrocarbons (PAHs) and methylnaphthalene were investigated in surface sediments of rivers and an estuary in Shanghai, China. Total PAH concentrations, excluding perylene, ranged from 107 to 1707 ng/g-dw. Sedimentary PAH concentrations of the Huangpu River were higher than those of the Yangtze Estuary. The concentration of the Suzhou River was close to the average concentration of the Huangpu River. PAHs source analysis suggested that, in the Yangtze Estuary, PAHs at locations far away from cities were mainly from petrogenic sources. At other locations, both petrogenic and pyrogenic inputs were significant. In the Huangpu and Suzhou Rivers, pyrogenic input outweighed other sources. The pyrogenic PAHs in the upper reaches of the Huangpu River were mainly from the incomplete combustion of grass, wood and coal, and those in the middle and lower reaches were from vehicle and vessel exhaust.     

分光光度法测定测田废水中的COD_(Cr)

为了快速监测油田废水中的化学需氧量ＣＯＤＣｒ,因此采用ＴＬ－１（Ａ）型污水ＣＯＤＣｒ速测仪进行加热催化消解,然后再用分光光度比色法测定ＣＯＤＣｒ,实验中进行了方法的准确度、精确度及Ｃｌ－影响实验,并与标准的重铬酸钾法进行了对比实验,结果说明分光光度法简单快速、重现性较好、准确度较高,对同一产品的测定结果与重铬酸钾法非常一致。因此,本方法可用于油田废水中的ＣＯＤＣｒ监测。     

湿热水解处理餐厨垃圾氮素转化规律

为了研究餐厨垃圾湿热水解过程中氮素的变化规律,设计了10、30、60、90和120℃5个温度水平以及30、60、90、120、150和180min6个加热时间水平,进行了30组完全实验,对不同湿热条件下餐厨垃圾粗蛋白、TN、NH4＋-N、NO3-N、有机氮及氨基酸等氮的不同存在形式的变化规律进行实验研究。结果表明,10、30及60℃条件下蛋白质的高级结构不会改变,利于粗蛋白的积累,且在温度120℃,加热时间90min条件下粗蛋白百分含量最高,占干物质的31．34％;随温度的升高和加热时间的延长TN、NHf-N和有机氮含量均上升;当温度达到120℃,由于水解反应,各温度处理下NHf．N浓度超过有机氮浓度,而NO3-N始终维持较低水平。氨基酸总量随温度的升高和水解时间的延长呈上升趋势,当温度达90％,加热时间达180min时,处理后餐厨垃圾总氨基酸百分含量最高,达164％,但温度达到120℃时,随着处理时间的延长,餐厨垃圾总氨基酸含量明显降低。     

绿化树种叶片中硫元素的含量特征

于2003年研究了昆明市的11个绿化树种叶片中S元素的含量，结果表明，大多数树种叶片中S含量与空气SO2污染的程度有明显的正相关性，可以做为大气中SO2污染监测的树种。     

A novel approach of preparing press-powders for cleaner production of ceramic tiles

China produces almost half of ceramic tiles in the world. However, serious air pollution and high energy consumption in the preparation of ceramic press-powders by traditional wet process (WP) have become major barriers for the sustainable development of ceramic tile manufacturing industry. A novel cleaner production process, named by the authors as Droplet-Powder Granulation Process (DPGP), was proposed and tested in this work. Droplet-powder granulator, a key facility of DPGP, was designed. In the granulator, ceramic suspension was directly sprayed to form fine suspension droplets and ceramic dry powder was simultaneously jetted and dispersed to enwrap, insulate and adsorb the suspension droplets so as to form coarse granules that were then rolled, tamped and dried into press-powders. Lab experiments of preparing press-powders by DPGP were carried out. The as-prepared DPGP press-powders consist of solid granules with nearly spherical shape and approximately normal grain size distribution, and present favorable flowability and relatively high bulk density, with the similar properties of the press-powders as those prepared by WP. Moreover, as compared with WP, DPGP can reduce both pollutant emission of 98% dust, 65% sulfur oxides and 71% nitrogen oxides and resource consumption of 24% energy and 69% water. Therefore, DPGP is an innovative approach for cleaner production of ceramic press-powders.     

Seasonal variation effects on the formation of trihalomethane during chlorination of water from Yangtze River and associated cancer risk assessment

For the system of water samples collected from Yangtze River,the effects of seasonal variation and Fe(III) concentrations on the formation and distribution of trihalomethanes (THMs) during chlorination have been investigated.The corresponding lifetime cancer risk of the formed THMs to human beings was estimated using the parameters and procedure issued by the US EPA.The results indicated that the average concentration of THMs (100.81 μg/L) in spring was significantly higher than that in other seasons,which ...     

BiVO4催化剂的离子液体辅助水热合成及其可见光催化活性

采用溴化1-丁基-3-甲基咪唑([Bmim]Br)离子液体辅助水热合成法制备了光催化剂BiVO4。以高压氙灯作为可见光源,亚甲基蓝为目标污染物,考察反应温度、pH、反应时间和离子用量等制备条件对BiVO4的可见光催化活性的影响,确定了最佳制备条件。并采用XRD、SEM和UV-Vis漫反射等分析手段对催化剂的晶相、形貌和光学特性进行了表征。结果表明,在离子液体加入量为2 mL、pH=4、反应温度为180℃、反应时间为4 h 的条件下,制得的BiVO4催化剂的可见光光催化活性最高。制得的BiVO4为单斜相,呈分散的、大小均匀的片状,在200~500 nm范围有一个较宽的强吸收平台,具有良好的可见光催化活性,在可见光照射下对浓度为5 mg/L的亚甲基蓝的光催化脱色率达97%以上。     

增城市生态城市建设的探讨研究

当前,中国正处于城市化高速发展时期,城市规划在生态城市建设过程中起着非常重要的作用。本研究目的:探讨城市规划中的生态建设方法,并对增城市城市规划中的生态建设实践进行思考,为科学引导增城市社会、经济、文化、生态协调发展提供参考。研究方法:案例研究法,时间序列分析法和比较研究法相结合。研究结果:增城市生态建设得益于准确科学的规划控制引导,基于时代发展的制度设计和规划保障是增城市取得生态建设重大成果的根本原因。研究结论:城市规划中的生态建设是城市发展的重要命题,是实现人与自然和谐共存的基础,是实现工业文明向生态文明转变的根本保证。     

脉冲调制介质阻挡放电和催化联用技术降解甲苯

利用低温等离子体处理挥发性有机化合物(VOCs)废气是目前国内外研究的热点。研究利用脉冲调制介质阻挡放电和催化联用技术降解甲苯,对比分析了连续放电和脉冲调制对去除甲苯的影响;研究了脉冲调制后在有无催化剂的情况下的能量效率,比较了两种情况下的臭氧浓度以及中间产物的不同。结果表明:脉冲调制有效提高了甲苯的降解能效,其能量效率几乎是连续放电时的2倍～3倍;在有催化剂的情况下,能量效率是没催化剂的1.5倍～2倍,臭氧浓度明显降低,结焦产物中含苯环的衍生物的量少于无催化的结焦产物。