二氧化钛对活性艳红X-3B的光催化降解研究

以TiO2作为光催化剂,研究了TiO2对活性艳红X-3B的光催化氧化降解行为。结果表明,以锐钛矿为主的混晶型Ti02的催化活性最好;X-3B的光催化降解动力学符合Langmuir-Hinshelwood动力学模式,并求出其动力学参数女(表观反应速率常数)为0．5921,KA(吸附平衡常数)为0．1725;温度对X-3B的降解影响很小,其活化能仅为6．04kJ／mol;溶液中盐度的增加会不断降低TiO2对X-3B的光催化降解速率。     

Characterization of the archaeal community fouling a membrane bioreactor

Biofilmformation, one of the primary causes of biofouling, results in reducedmembrane flux or increased transmembrane pressure and thus represents a major impediment to the wider implementation of membrane bioreactor (MBR) technologies for water purification. Most studies have focused on the role of bacteria in membrane fouling as they are the most dominant and best studied organisms present in the MBR. In contrast, there is limited information on the role of the archaeal community in biofilm formation in MBRs. This study investigated the composition of the archaeal community during the process of biofouling in an MBR. The archaeal community was observed to have lower richness and diversity in the biofilmthan the sludge during the establishment of biofilms at low transmembrane pressure (TMP). Clustering of the communities based on the Bray-Curtis similarity matrix indicated that a subset of the sludge archaeal community formed the initial biofilms. The archaeal community in the biofilm was mainly composed of Thermoprotei, Thermoplasmata, Thermococci, Methanopyri, Methanomicrobia and Halobacteria. Among them, the Thermoprotei and Thermoplasmata were present at higher relative proportions in the biofilms than they were in the sludge. Additionally, the Thermoprotei, Thermoplasmata and Thermococci were the dominant organisms detected in the initial biofilms at low TMP, while as the TMP increased, the Methanopyri, Methanomicrobia, Aciduliprofundum and Halobacteria were present at higher abundances in the biofilms at high TMP.     

我国海岸带灾害的加剧发展及其防御方略

中国大陆海岸带绵长1.8万公里,地跨12个省市,是我国人口密集、经济发展最快的地区。出现的严重灾害有台风、风暴潮、洪涝、地震海啸、海岸侵蚀、盐水入侵、海冰、地基下沉、污染、赤潮等十类,并互相叠加,形成年直接经济损失100亿元以上。全球海平面上升与人类活动加强,使海岸带灾害加剧发展,粗略估计到下世纪初中期,导致的损失可能达到1000亿元以上,是海岸带经济发展的重要制约因素。必须提高全民防灾意识,在调查研究基础上,拟订海岸带减灾规划;加强灾害的监测、预报和预警;加高加固防潮防洪大堤与护岸工程,疏浚内陆洼地和城市排洪河道,提高排水能力;保护地下水源,严格限制过量开采,以防止地面下沉和盐水入侵;合理开发海岸带资源,保护生态环境,严格限制超标排污;积极参加国际合作,逐步限制CO_2等温室气体的排放,和缓海平面上升趋势,争取大幅度减轻海岸带灾害。     

东北玉米热量指数预测方法研究(Ⅳ)——均生函数预测方法

均生函数预测方法是开展环境要素变化趋势预测的有效方法之一。通过对东北地区玉米热量指数的分析,建立了热量指数时间变化趋势的均生函数预测模型,各模型预测的平均精度基本都达到95%以上,与逐步回归统计模型一致,但普遍要好于GM(1,1)模型,同样可以应用该模型的预测结果指导农业生产。     

Phosphine and methane generation by the addition of organic compounds containing carbon-phosphorus bonds into incubated soil

Formation of phosphine and methane in anaerobic incubation systems was investigated under stirred and unstirred conditions. The PH3 and CH4 levels in the headspace, as well as the matrix-bound PH3 content in the stirred soil, significantly increased upon the addition of phosphonoacetic acid (P(O)(OH)2CH2COOH). Both the levels of matrix-bound PH3 and CH4 are positively correlated to the buffered dithionite fraction of reactive phosphorus in the soil samples, while a negative correlation was observed between matrix-bound PH3/CH4 levels and the reactive phosphorus fraction.     

中国城市环境中空气负离子研究进展

空气负离子被誉为“空气维生素和生长素”,其浓度被列为衡量空气质量好坏的一个重要指标,对于城市空气质量的改善意义重大。综述了中国城市环境空气负离子研究方面的主要进展,对空气离子产生的机理机制、观测方法、时空特征、评价指标体系以及关键影响因子及其相互之间的关系等方面进行深入和系统的阐述。其中重点阐述了空气负离子与不同自然环境和建筑环境的关系。国内外主要研究结果表明,(1)不同环境场所下空气负离子浓度差别很大,呈现出由城市中心到郊区再到乡村逐渐增大的趋势。(2)空气负离子浓度的年变化和日变化均存在明显差异。(3)水体对空气负离子浓度影响较大,动态水的空气负离子浓度大于静态水,以瀑布为最大。同时离水体的距离越近,周边的空气负离子浓度越高。(4)空气负离子与风的关系最为密切,有风时空气负离子浓度高于无风时,且风速与空气中负离子浓度成正相关。其他因素如温湿度、天气状况、植物绿化、建筑材料以及建筑高度等都能影响空气负离子浓度的高低,从而影响城市环境的空气清新度,其中有研究者发现空气负离子能够降低空气中颗粒物的浓度,并与PM2.5的关系最大。这些研究为综合地指导和评价城市环境空气质量提供科学依据和设计思路。因此笔者结合中国城市化的进程,进一步提出了更多的想法：(1)在控制性详细规划的层面上,与城市设计和城市绿地系统等研究结合起来,开展周期性的空气负离子浓度实证研究。(2)尝试建立空气负离子浓度与城市住区通风关系的评估方法,为城市住区空气清新度与通风关系的评估做应用性基础研究。     

Impact of gas impurities on the Hg0 oxidation on high iron and calcium coal ash for chemical looping combustion

Environmental Science and Pollution Research - Coal-based mercury pollution from power plants has received increasing attention. In a previous study, high iron and calcium coal ash (HICCA) was...     

Policy-making coordination of municipal solid waste policies in China: a content analysis

Journal of Material Cycles and Waste Management - Massive urbanization and rapid development of urban economy have increased the generation of municipal solid waste in China. Like all developing...     

胡敏素-赤铁矿复合物对外源添加镉污染富硒土壤的钝化

以本地富硒土壤提取的胡敏素(humin,HM)、制备的赤铁矿(hematite,α-Fe_2O_3)和胡敏素-赤铁矿复合物(HM-α-Fe_2O_3)作为钝化剂,对富硒土壤中的镉(Cd)进行钝化研究。结果表明,有效态Cd浓度与pH呈显著负相关(r=-0.729)(0.01P0.05)。与空白对照组(CK)处理对比,添加3种不同水平用量的HM(H1～H3),α-Fe_2O_3(F1～F3)和HM-α-Fe_2O_3 [(F-H)1～(F-H)3]处理并培养60 d后,土壤中有效Cd浓度分别降低14.21%～22.96%、21.25%～37.55%和13.45%～27.75%;可交换态Cd的浓度分别降低17.77%～23.34%、33.93%～45.39%和18.56%～22.07%。比较不同钝化剂的钝化效果,发现单独钝化剂中最佳处理组为F2(20 d),有效态Cd浓度的降低幅度最大(37.55%),但施加量也最大,易导致土壤碱性化;HM钝化剂在5 d达到最佳效果(H2);HM-α-Fe_2O_3中最佳处理组为(F-H)3(60 d),有效态Cd浓度的降低量与钝化剂用量、钝化时间都呈极显著正相关(r=0.631,0.428)(P0.01),说明其钝化效果与钝化剂用量、钝化时间呈现较好的线性增长关系,施用率低且效果明显。因此,HM适用于短期修复,而HM-α-Fe_2O_3适用于长期修复。HM与α-Fe_2O_3复合应用为充分利用土壤腐殖质和控制重金属流动性提供了新途径。     

Comparisons of particulate-bound mercury (PBM) compositions in soil and vegetation at a traffic site

This investigation analyzes the particulate-bound mercury (PBM) compositions in soil and vegetation at a traffic sampling site in Taichung, Taiwan, during a sampling period from October to December, 2015. A direct mercury analyzer (DMA-80) was used to measure the particulate-bound mercury (PBM). A T-test was conducted to determine the mean differences between the PBM composition in soil and that in vegetation at the site. The results indicate that 1) the mean particulate-bound mercury compositions in soil and vegetation were the lowest in November, when the (mean OR average) wind speed was the highest (4.1 m/s); 2) Particulate-bound mercury compositions (PBM) in both soil and vegetation correlated weakly with temperature, humidity and wind speed; 3) T-test statistical results denoted that the PBM compositions did not significantly differ between soil and vegetation in the three-month sampling period.