东北玉米热量指数预测方法研究(Ⅳ)——均生函数预测方法

均生函数预测方法是开展环境要素变化趋势预测的有效方法之一。通过对东北地区玉米热量指数的分析,建立了热量指数时间变化趋势的均生函数预测模型,各模型预测的平均精度基本都达到95%以上,与逐步回归统计模型一致,但普遍要好于GM(1,1)模型,同样可以应用该模型的预测结果指导农业生产。     

Phosphine and methane generation by the addition of organic compounds containing carbon-phosphorus bonds into incubated soil

Formation of phosphine and methane in anaerobic incubation systems was investigated under stirred and unstirred conditions. The PH3 and CH4 levels in the headspace, as well as the matrix-bound PH3 content in the stirred soil, significantly increased upon the addition of phosphonoacetic acid (P(O)(OH)2CH2COOH). Both the levels of matrix-bound PH3 and CH4 are positively correlated to the buffered dithionite fraction of reactive phosphorus in the soil samples, while a negative correlation was observed between matrix-bound PH3/CH4 levels and the reactive phosphorus fraction.     

中国城市环境中空气负离子研究进展

空气负离子被誉为“空气维生素和生长素”,其浓度被列为衡量空气质量好坏的一个重要指标,对于城市空气质量的改善意义重大。综述了中国城市环境空气负离子研究方面的主要进展,对空气离子产生的机理机制、观测方法、时空特征、评价指标体系以及关键影响因子及其相互之间的关系等方面进行深入和系统的阐述。其中重点阐述了空气负离子与不同自然环境和建筑环境的关系。国内外主要研究结果表明,(1)不同环境场所下空气负离子浓度差别很大,呈现出由城市中心到郊区再到乡村逐渐增大的趋势。(2)空气负离子浓度的年变化和日变化均存在明显差异。(3)水体对空气负离子浓度影响较大,动态水的空气负离子浓度大于静态水,以瀑布为最大。同时离水体的距离越近,周边的空气负离子浓度越高。(4)空气负离子与风的关系最为密切,有风时空气负离子浓度高于无风时,且风速与空气中负离子浓度成正相关。其他因素如温湿度、天气状况、植物绿化、建筑材料以及建筑高度等都能影响空气负离子浓度的高低,从而影响城市环境的空气清新度,其中有研究者发现空气负离子能够降低空气中颗粒物的浓度,并与PM2.5的关系最大。这些研究为综合地指导和评价城市环境空气质量提供科学依据和设计思路。因此笔者结合中国城市化的进程,进一步提出了更多的想法：(1)在控制性详细规划的层面上,与城市设计和城市绿地系统等研究结合起来,开展周期性的空气负离子浓度实证研究。(2)尝试建立空气负离子浓度与城市住区通风关系的评估方法,为城市住区空气清新度与通风关系的评估做应用性基础研究。     

关于中国土壤环境监测分析方法标准的思考与建议

研究了中国土壤环境监测分析方法标准发展历程及现状。根据现行土壤环境监测分析方法标准的类型、数量和污染物控制项目,以及中国土壤环境监测分析方法标准的特点,分析了中国土壤环境监测分析方法标准存在的问题和不足。结合当前土壤环境管理需求,提出了完善中国土壤环境监测分析方法标准的建议:加快标准制修订,合理增加污染物项目的控制种类和检测方式;加强不同标准方法之间的可比性研究,使标准更具实用性和指导性;加大土壤监测技术基础性研究,借鉴国外先进经验,为标准制修订工作提供有力支撑。     

关于中国固体废物环境监测分析方法标准的思考与建议

研究了中国固体废物环境监测分析方法标准的发展历程及现状。通过分析现行固体废物环境监测分析方法标准现状与需求,发现中国固体废物环境监测分析方法标准存在不能完全满足现行固体废物污染控制标准和危险废物鉴别标准的测定需求,部分标准规范性有待提高,标准基础研究较为薄弱,同一污染物项目不同方法标准之间的可比性研究有待加强等诸多问题。针对存在的问题,建议从加快标准制修订,加强基础科研和顶层设计,加大可比性研究等方面完善中国固体废物环境监测分析方法标准,以期推动中国固体废物环境监测分析方法标准体系的建设与发展。     

Characterizations of temperature effects on sintered ceramics manufactured with waste foundry sand and clay

The objects of this study were to use waste foundry sand (WFS) to manufacture reclaimed resource tiles and to determine the effects of different kiln temperatures on the properties of the reclaimed WFS tiles. In this study, clay was replaced with 0 or 15 % WFS to manufacture tile specimens. Four different kiln temperatures (1000, 1050, 1100, and 1150 °C) were used in this study for the manufacture of tile specimens. The test results showed that using 15 % WFS in the tile specimens allowed the kiln temperature to be lowered by 50 °C. This temperature reduction is helpful for reducing costs and energy consumption and carbon reduction. Moreover, when the kiln temperature increased from 1000 to 1100 °C and the specimens were placed in acidic and alkaline solutions, the weight loss of the tile specimens containing 15 % WFS was half that of the specimens containing 0 % WFS. The acid-alkali resistance of the tile specimens containing 15 % WFS was also improved. This result suggested that the WFS replacement and kiln temperature affected the properties of the tile specimens.     

有机化合物动态定量结构—生物降解关系（QSBR）模型研究

本文通过分析影响有机物生物降解的基本因素,指出ＱＳＢＲ模型应综合反映影响有机物生物降解的四个方面：取代化合物的摄入、取代化合物的诱导作用,毒性物质的形成和基础酶的缺乏,在此基础之上给出了动态ＱＳＢＲ的概念模型及方法学基础,并利用其研究了氯代芳香化合物的生物降解性。     

全氟辛酸光催化材料应用及降解机理研究进展

全氟辛酸（PFOA）是一种广泛存在于环境介质中的典型全氟化合物,具有高毒性、难降解等特点,严重威胁生态环境安全及人类遗传、免疫、神经和生殖健康,其环境危害和风险防控引起广泛关注。光催化技术具有反应条件温和、处理效率高、应用成本低且无二次污染等优势,在PFOA的降解处理方面具有广阔应用前景。为研发活性强、可见光吸收性能好、稳定性高的新型光催化材料,实现水中PFOA的高效降解,系统梳理了近20年来PFOA光催化降解材料制备的相关研究,对不同光催化降解材料的降解特性及存在问题进行全面分析;结合现有材料对PFOA的光催化降解,总结光催化降解材料的反应机理及活性增强机制,阐明PFOA的光催化降解路径。

     

Impact of gas impurities on the Hg0 oxidation on high iron and calcium coal ash for chemical looping combustion

Environmental Science and Pollution Research - Coal-based mercury pollution from power plants has received increasing attention. In a previous study, high iron and calcium coal ash (HICCA) was...     

Comparisons of particulate-bound mercury (PBM) compositions in soil and vegetation at a traffic site

This investigation analyzes the particulate-bound mercury (PBM) compositions in soil and vegetation at a traffic sampling site in Taichung, Taiwan, during a sampling period from October to December, 2015. A direct mercury analyzer (DMA-80) was used to measure the particulate-bound mercury (PBM). A T-test was conducted to determine the mean differences between the PBM composition in soil and that in vegetation at the site. The results indicate that 1) the mean particulate-bound mercury compositions in soil and vegetation were the lowest in November, when the (mean OR average) wind speed was the highest (4.1 m/s); 2) Particulate-bound mercury compositions (PBM) in both soil and vegetation correlated weakly with temperature, humidity and wind speed; 3) T-test statistical results denoted that the PBM compositions did not significantly differ between soil and vegetation in the three-month sampling period.