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561.
In the present study, the magnitude of contamination of vegetables with heavy metals (Pb, Zn, Cd, Cr, Cu and Zn) was determined in a long-term wastewater-irrigated agricultural land. Heavy metal concentrations in vegetables were several folds higher in wastewater-irrigated site compared to clean water-irrigated area. The wastewater-irrigated crops analysed in this study are heavily contaminated with heavy metals. Concentrations of Pb, Zn, Cd and Cr in all the sewage-fed vegetables were beyond the safe limit of FAO/WHO and Indian standard. Contamination is at its highest level in radish and spinach. Daily intake values of Pb, Cd and Ni through consumption of sewage-fed vegetables exceeded the recommended oral dose of metal for both adult and children. The study concludes that wastewater irrigation led to accumulation of heavy metals in vegetables causing potential health risk to consumers. 相似文献
562.
Rakesh Kumar Ghosh Zareen S. Khan C. V. N. Rao Kaushik Banerjee D. Damodar Reddy T. G. K. Murthy Nalli Johnson Deb Prasad Ray 《Environmental monitoring and assessment》2014,186(8):5069-5075
Presence of pesticide residues in tobacco increases health risk of both active and passive smokers, apart from the imminent potential health problems associated with it. Thus, monitoring of pesticide residue is an important issue in terms of formulating stringent policies, enabling global trade and safeguarding the consumer’s safety. In this study, a gas chromatography-single quadrupole mass spectrometry (GC-MS) method based upon quantifier-qualifier ions (m/z) ratio was employed for detecting and assessing ten organochlorine pesticide residues (α-HCH, β-HCH, γ-HCH, δ-HCH, 2,4-DDT, 4,4-DDT, endrin, α-endosulfan, β-endosulfan and endosulfan sulphate) in 152 flue-cured (FC) tobacco leave samples from two major tobacco growing states, Karnataka and Andhra Pradesh, of India. In the majority of samples, pesticide residue levels were below the limit of quantification (LOQ). In few samples, pesticide residues were detected and they found to comply with the guidance residue levels (GRL) specifications of the Cooperation Center for Scientific Research Relative to Tobacco (CORESTA). Detection of the phase out pesticides like DDT/HCH might be due to transfer of persistent residues from the environmental components to the plant. This is the first report on these ten organochlorine pesticide residues in Indian FC tobacco. 相似文献
563.
Study of harmful algal blooms in a eutrophic pond, Bangladesh 总被引:2,自引:0,他引:2
Roksana Jahan Saleha Khan Md. Mahfuzul Haque Joong Ki Choi 《Environmental monitoring and assessment》2010,170(1-4):7-21
The purpose of this research was to analyze the underlying mechanisms and contributing factors related to the seasonal dynamic of harmful algal blooms in a shallow eutrophic pond, Bangladesh during September 2005–July 2006. Two conspicuous events were noted simultaneously throughout the study period: high concentration of phosphate–phosphorus (>3.03; SD 1.29 mg l???1) and permanent cyanobacterial blooms {>3,981.88 × 103 cells l???1 (SD 508.73)}. Cyanobacterial blooms were characterized by three abundance phases, each of which was associated with different ecological processes. High nitrate–nitrogen (>2.35; SD 0.83 mg l???1), for example, was associated with high cyanobacterial abundance, while low nitrate–nitrogen (0.36; SD 0.2 mg l???1) was recorded during moderate abundance phase. Extremely low NO3–N/PO4–P ratio (>3.55, SD 2.31) was recorded, and all blooming taxa were negatively correlated with this ratio. Cyanobacterial blooms were positively correlated with temperature (r?=?0.345) and pH (0.833; p?=?0.05) and negatively correlated with transparency (r?=???0.956; p?=?0.01). Although Anabaena showed similar relationship with water quality parameters as cyanobacteria, the co-dominant Microcystis exhibited negative relationship with temperature (r?=???0.386) and nitrate–nitrogen (r?=???0.172). This was attributed to excessive growth of Anabaena that suppressed Microcystis’s growth. Planktothrix was the third most dominant taxa, while Euglena was regarded as opportunistic. 相似文献
564.
K. G. Mohamed Thameemul Ansari S. Manokaran S. Raja P. S. Lyla S. Ajmal Khan 《Environmental monitoring and assessment》2014,186(1):293-305
Free-living marine nematode diversity was analyzed between Avicennia marina and Rhizophora mucronata mangrove covers of the Vellar Estuary (southeast coast of India). A total of 4,976 specimens of free-living marine nematodes were collected in 56 species. Comparatively, a higher species richness was obtained for A. marina (52 species) than for R. mucronata (44 species), whereas 40 species commonly existed in both mangrove covers. A higher density of nematodes was found in sediments of sandy nature, whereas there was lower total organic carbon compared to silt/clay composition; epigrowth feeders were dominant over the other feeding groups based on organic enrichment in surface sediments. Principal component analysis clearly explained the relationship between the environmental parameters of various months. Higher R values of analysis of similarities revealed significant differences in nematode assemblages between months, and it was quite evident by non-metric multidimensional scaling. Diversity indices showed higher values in the dry months. RELATE analysis explained serial changes in nematode species composition between months, and a relationship between biotic and abiotic variables was clarified using the BIO-ENV procedure. Viscosia spp., Metachromadora spp., Theristus spp., and Sphaerolaimus spp. were candidate species of A. marina leaf interaction by observation. 相似文献
565.
Assessment of phenanthrene bioavailability in aged and unaged soils by mild extraction 总被引:2,自引:0,他引:2
Khan MI Cheema SA Shen C Zhang C Tang X Shi J Chen X Park J Chen Y 《Environmental monitoring and assessment》2012,184(1):549-559
It has become apparent that the threat of an organic pollutant in soil is directly related to its bioavailable fraction and
that the use of total contaminant concentrations as a measure of potential contaminant exposure to plants or soil organisms
is inappropriate. In light of this, non-exhaustive extraction techniques are being investigated to assess their appropriateness
in determining bioavailability. To find a suitable and rapid extraction method to predict phenanthrene bioavailability, multiple
extraction techniques (i.e., mild hydroxypropyl-β-cyclodextrin (HPCD) and organic solvents extraction) were investigated in soil spiked to a range of phenanthrene levels (i.e.,
1.12, 8.52, 73, 136, and 335 μg g − 1 dry soil). The bioaccumulation of phenanthrene in earthworm (Eisenia fetida) was used as the reference system for bioavailability. Correlation results for phenanthrene suggested that mild HPCD extraction
was a better method to predict bioavailability of phenanthrene in soil compared with organic solvents extraction. Aged (i.e.,
150 days) and fresh (i.e., 0 day) soil samples were used to evaluate the extraction efficiency and the effect of soil contact
time on the availability of phenanthrene. The percentage of phenanthrene accumulated by earthworms and percent recoveries
by mild extractants changed significantly with aging time. Thus, aging significantly reduced the earthworm uptake and chemical
extractability of phenanthrene. In general, among organic extractants, methanol showed recoveries comparable to those of mild
HPCD for both aged and unaged soil matrices. Hence, this extractant can be suitable after HPCD to evaluate risk of contaminated
soils. 相似文献
566.
Shah MH Iqbal J Shaheen N Khan N Choudhary MA Akhter G 《Environmental monitoring and assessment》2012,184(3):1243-1252
Selected trace metals were estimated by atomic absorption spectrometry in the water and soil samples collected from the remote
region of Himalaya. The soil samples were analysed for soluble and acid extractable fraction of trace metals. In water samples,
Ca, Na, Mg and K emerged as dominant contributors, whereas, Ca, Na, K, Mg, Fe and Pb were estimated at comparatively higher
levels in the water extract of the soil. In case of acid extract of the soil samples, Ca, K, Fe, Mg, Mn and Na were found
at elevated concentrations. Based on mean levels of the metals, following decreasing concentration order was observed in water
samples: Ca > Na > Mg > K > Pb > Co > Cu > Zn > Mn > Cr > Fe > Cd > Li, however, in the acid extract of the soil, following
order was noted: Ca > K > Fe > Mg > Mn > Na > Pb > Zn > Cr > Li > Cu > Co > Cd. The correlation study revealed appreciably
diverse mutual relationships of trace metals in the water and soil samples. The multivariate cluster analyses exhibited divergent
apportionment of trace metals in water and soil samples. Among the trace metals, Cd, Pb, Li, Zn, Cr, Cu, Mn and Co exhibited
extreme to significant anthropogenic enrichment in the soil samples, while the rest of the metals were mostly contributed
by the natural processes. 相似文献
567.
Shbbir R. Khan Satish K. Singh Neelkamal Rastogi 《Environmental monitoring and assessment》2017,189(4):195
The present study focuses on the abundance, heavy metal content, and the impact of ecosystem engineering activities of two coal mine site-inhabiting ant species, Cataglyphis longipedem and Camponotus compressus. The abundance of Ct. longipedem increased while that of C. compressus decreased, with increasing soil pollution. Correspondence analysis reveals a close association between soil heavy metal concentrations and Ct. longipedem abundance, but this association is lacking in the case of C. compressus. Cataglyphis ants which occupy stress-characterized niches appear to be pre-adapted to tolerate heavy metal pollution. Higher concentrations of Zn and Mn in Ct. longipedem may contribute to the strengthening of the cuticular structures, necessary for nest excavation in the hard, arid soil and for single load carrying. C. compressus ants appear to be pollution sensitive. Their higher Fe content may be related to metal uptake via plant-derived liquids and species-specific regulatory mechanisms. The metal pollution index and biota-to-soil accumulation factors, calculated by using the ant body metal content of the two species, indicate an overall decrease of soil heavy metal concentrations with increase of the site age, which reflects the degree of pollution related to the mine site age. The concentrations of total and available heavy metals (Fe, Zn, Mn, Pb, and Cu) were significantly lower in the ant nest debris soil as compared to the reference soil. The results of the present study highlight the role of ants as bioindicators and in bioremediation of contaminated soil. 相似文献
568.
A series of laboratory-based incubations using a stable isotope tracer technique was applied to measure the net and gross fluxes of CH(3)Cl and CH(3)Br as well as the net fluxes of CHCl(3) from surface soils of the Sacramento-San Joaquin Delta of California. Annually averaged flux measurements show that these mineral/oxidized peat soils are a net source of CH(3)Cl (140 ± 266 nmol m(-2) d(-1)) and CHCl(3) (258 ± 288 nmol m(-2) d(-1)), and a net sink of CH(3)Br (-2.3 ± 4.5 nmol m(-2) d(-1)). Gross CH(3)Cl and CH(3)Br fluxes are strongly influenced by both soil moisture and temperature: gross production rates of CH(3)Cl and CH(3)Br are linearly correlated with temperature, whereas gross consumption rates exhibit Gaussian relationships with maximum consumption at soil moisture levels between 20 and 30% volumetric water content (VWC) and a temperature range of 25 to 35 °C. Although soil moisture and soil temperature strongly affect consumption rates, the range of gross consumption rates overall is limited (-506 ± 176 nmol m(-2) d(-1) for CH(3)Cl and -12 ± 4 nmol m(-2) d(-1) for CH(3)Br) and is similar to rates reported in previous studies. CHCl(3) fluxes are not correlated with methyl halide fluxes, temperature, or soil moisture. The annual emission rates of CHCl(3) from the Sacramento-San Joaquin Delta are found to be a potentially significant local source of this compound. 相似文献
569.
Amin U. Khan 《Environmental monitoring and assessment》2010,163(1-4):171-184
This paper summarizes the findings obtained in a monitoring study to understand the sources and processes affecting the quality of shallow and deep groundwater near central air conditioning plant site in Trombay region by making use of physicochemical and biological analyses. All the measured parameters of the groundwaters indicate that the groundwater quality is good and within permissible limits set by (Indian Bureau of Standards 1990). Shallow groundwater is dominantly of Na–HCO3 type whereas deep groundwater is of Ca–Mg–HCO3 type. The groundwater chemistry is mainly influenced by dissolution of minerals and base exchange processes. High total dissolved solids in shallow groundwater compared to deeper ones indicate faster circulation of groundwater in deep zone preferably through fissures and fractures whereas groundwater flow is sluggish in shallow zone. The characteristic ionic ratio values and absence of bromide point to the fact that seawater has no influence on groundwater system. 相似文献
570.
Mohd Shahnawaz Khan Medha Priyadarshini Aaliya Shah Shams Tabrez Haseeb Jagirdar Abdulrahman M. Alsenaidy Bilqees Bano 《Environmental monitoring and assessment》2013,185(10):8005-8010
Cystatins are thiol proteinase inhibitors ubiquitously present in the mammalian body. They serve a protective function to regulate the activities of endogenous proteinases, which may cause uncontrolled proteolysis and damage. In the present study, the effect of benzo(a)pyrene [BaP] on lung cystatin was studied to explore the hazardous effects of environmental pollutant on structural and functional integrity of the protein. The basic binding interaction was studied by UV-absorption, FT-IR, and fluorescence spectroscopy. The enhancement of total protein fluorescence with a red shift of 5 nm suggests structural scratch of lung cystatin by benzo(a)pyrene. Further, ANS binding studies reaffirm the unfolding of the thiol protease inhibitor (GLC-I) after treating with benzo(a)pyrene. The results of FT-IR spectroscopy reflect perturbation of the secondary conformation (alpha-helix to β-sheet) in goat lung cystatin on interaction with BaP. Finally, functional inactivation of cystatin on association with BaP was checked by its papain inhibitory activity. Benzo(a)pyrene (10 μM) caused complete inactivation of goat lung cystatin. Benzo(a)pyrene-induced loss of structure and function in the thiol protease inhibitor could provide a caution for lung injury caused by the pollutants and smokers. 相似文献