不同工艺对含高浓度腐殖酸地下水处理的可行性

针对内蒙古农村地区高腐殖酸地下水的处理问题,分别对（pH调节）-PAC强化混凝、高锰酸钾预氧化／混凝、活性炭吸附／混凝、Fenton氧化等技术处理的可行性进行了研究,同时利用三维荧光和高效体积排阻色谱分析处理前后水中有机物的组成变化特征。有机分析结果显示,水中的有机物为腐殖酸类物质,分子量分别为1600和3500,腐殖酸类物质为水中色度的主要贡献者。原水PAC强化混凝、高锰酸钾预氧化／PAC混凝对有机物的去除效果不佳,处理前后水样DOC浓度无明显变化,而pH调节．PAC强化混凝、微米活性炭吸附和Fenton氧化均能有效去除有机物。将原水pH调节至6．5,经300mg／LPAC混凝后出水DOC降至5．99mg／L。活性炭投加量为0．6g／L时,DOC降至7．6mg／L,然后采用60mg／LPAC混凝出去高度分散而不易沉降的小颗粒活性炭。此外,当反应初始pH值为3,过氧化氢投加量为0．5％（v／v）,亚铁和双氧水摩尔比为0．05时,出水DOC降至5．6mg／L,氧化后有小分子有机物生成。     

大气汞的来源及其浓度分布特征研究进展

大气汞是全球性的污染物,其来源有自然源和人为源,亚洲地区是最大的人为大气汞排放源,占全球人为排汞量的67％(质量分数),其中又以中国为最.燃煤和有色金属冶炼对中国大气汞排放的贡献最大.环境界面的释汞通量是全球大气汞预算的重要组成部分,也是目前的研究热点之一.综述了不同环境界面的释汞通量及其影响因素,并比较了不同地区大气...     

高分辨率遥感影像在城市绿地信息提取中的应用研究

高分辨率卫星遥感图像数据量大、空间分辨率高、结构信息复杂、地物同物异谱现象更为突出等特征给专题信息提取技术带来了新的挑战。基于植被的光谱特征,利用监督分类、植被指数分类和目视解译等方法对QuickBird高分辨率卫星遥感影像的绿地信息进行提取,并对分类精度作了比对分析。研究结果表明,监督分类方法不能得到令人满意的结果,运用植被指数分类方法则有明显改善,其中归一化植被指数(NDVI)精度最高,因此NDVI能有效地对植被进行分类与识别。     

A novel pretreatment approach for fast determination of organochlorine pesticides in biotic samples

Recent studies have focused on enantiomeric behaviors of chiral organochlorine pesticides (OCPs) in biotic matrix because they provide insights into the biotransformation processes of chiral OCPs. In the present paper, a double in-line column chromatographic method was developed to effectively remove the lipid impurity in different biotic samples for clean-up of OCPs. After an initial Soxhlet extraction of OCPs from the biotic samples by a mixture of acetone and dichloromethane (DCM), dimethyl sulfoxide (DMSO) was directly added to the extract, and low boiling point solvents (acetone and DCM) were then evaporated. OCPs remained in DMSO were eluted via column 1 filled with silicon gel, and subsequently passed through column 2 packed with 15% deactivated florisil. This novel method was characterized by significant time and solvent savings. The recovery rates of alpha-HCH (hexachlorocyclohexane), beta-HCH, gamma-HCH and delta-HCH were 78.5+/-3.1%, 72.4+/-7.7%, 72+/-4.0% and 70.0+/-8.7%, respectively, and 92.5+/-3.8%, 79.7+/-6.7% and 83.4+/-6.5% for 1,1-dichloro-2-(2-chlorophenyl)-2-(4- chlorophenyl) ethylene (o,p'-DDE), 1,1-dichloro-2-(2-chlorophenyl)-2-(4-chloro phenyl)ethane (o,p'-DDD) and 1,1,1-trichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl) ethane (o,p'-DDT), separately. In addition, the separation efficiencies of the target compounds by both achiral and chiral gas chromatographic columns were satisfactory using the established method. Therefore, the double in-line column chromatography was a useful alternative method for pretreatment of OCPs in different biotic samples.     

生长于铬污染土壤上石榴产品铬污染评价

研究了攀西地区铬污染土壤和正常土壤铬含量分布及其石榴样品铬污染情况。结果表明攀枝花大田石榴基地土壤铬含量在23．1—504mg／kg,平均值高达184mg／kg,超标率为26％,而对该基地的石榴果实进行两年连续监测结果表明,铬含量在0．0012—0．067mg／kg之间,平均为0．016mg／kg,大大低于相应产品标准（0．5mg／kg）,超标率为0％;会理石榴基地土壤铬含量在34．5—99．1mg／kg,平均值为69．0mg／kg,超标率为0％,该基地的石榴果实铬含量在0．0075—0．104mg／kg之间,平均为0．024mg／kg,大大低于相应产品标准（0．5mg／kg）,超标率为0％。形态分析表明土壤中铬99％以上都是以不被植物利用的残渣态存在,因此土壤总铬再高,其被植物可吸收部分却很少,这就导致了受铬污染的土壤却不一定能生产出污染石榴的原因。     

Adsorption of Acid Red 73 on copper dithiocarbamate precipitate-type solid wastes

Three solid wastes, copper N,N'-bis(dithiocarboxy)piperazine ([CuBDP](n)), copper diethyldithiocarbamate (Cu(DDTC)(2)) and copper dimethyldithiocarbamate (Cu(DMTC)(2)), were prepared and tested as adsorbents to remove Acid Red 73 from wastewater. It was found that the three precipitates all could effectively adsorb the dye but their adsorption abilities were rather different. The maximum adsorption amounts of the coordination polymer precipitate [CuBDP](n) reached as high as 364mg g(-1), much greater than those of Cu(DDTC)(2) and Cu(DMTC)(2) (42.9 and 37.8mg g(-1), respectively). The investigation of adsorption models showed these adsorption processes followed the pseudo-second-order kinetic equation and the adsorption balances could be described with both Langmuir and Freundlich isotherms, but the latter seemed to be more suitable. Their adsorption nature was inferred to be physical adsorption and mainly depended on the hydrophobic interaction between these precipitates and Acid Red 73. This is the first example for the reutilization of metal dithiocarbamate precipitates as solid wastes to date.     

浅论“以新带老”在技改扩建项目环境影响评价中的运用

以氮肥厂为例，提出对以新带老在环境影响评价中的一些认识，并提供如何在化工类技改扩建项目环境影响评价中开展以新带老的方法和思路。     

干旱河谷地区农业产业结构的调整对环境及经济的影响分析--以汉源地区为例

中国农业产业结构的调整，是中国改革开放、市场化发展的集中体现。本文以汉源地区为例，总结分析了典型的干旱河谷地带农业产业结构的调整情况，不仅促进了当地农村发展方式的根本转变、改善了农村经济、提高了农民收入，同时还解决了当地剩余劳动力的就地消化问题。本文指出了农业产业结构的调整可能对当地生态环境造成的影响，其中诸如不舍理用药用肥造成的水污染、土壤和农产品的硝酸盐污染以及土壤退化、大气污染等环境问题。需要在实践中更加审慎地调整农业产业结构。     

铅锌矿业废弃地草本植物重金属耐性研究

本文调查了四川甘洛铅锌矿废弃矿区和尾矿库区自然生长的15种草本植物，分析了其体内重金属（Pb、Zn、Cd）的含量，并对植物的重金属耐受性作了初步探讨。研究表明，在所采集的15种草本植物中，地上部分以小飞蓬对Pb、Zn、Cd的富集量最高；地下部分富集量则表现出较大的种间差异性，野烟对Pb的积累量最高，假酸浆对Zn的积累量最高，水蓼对Cd的积累量最高，但均未达到“超积累植物”的标准。