液化石油气轿车实际道路污染物排放特征

利用PEMS对国2技术LPG出租轿车和汽油轿车的实际道路排放进行测试,基于测试数据对LPG轿车排放特征进行解析,并与汽油轿车的排放因子进行对比分析.结果显示:速度和行驶模式对LPG轿车污染物排放影响明显;LPG轿车CO 2、CO、HC和NOx污染物的实测排放因子分别为(169.5±22.2)、(2.18±2.38)、(...     

Heavy metal and Pb isotopic compositions of aquatic organisms in the Pearl River Estuary, South China

The accumulation of trace metals in aquatic organisms may lead to serious health problems through the food chain. The present research project aims to study the accumulation and potential sources of trace metals in aquatic organisms of the Pearl River Estuary (PRE). Four groups of aquatic organisms, including fish, crab, shrimp, and shellfish, were collected in the PRE for trace metal and Pb isotopic analyses. The trace metal concentrations in the aquatic organism samples ranged from 0.01 to 2.10 mg/kg Cd, 0.02 to 4.33 mg/kg Co, 0.08 to 4.27 mg/kg Cr, 0.15 to 77.8 mg/kg Cu, 0.17 to 31.0 mg/kg Ni, 0.04 to 30.7 mg/kg Pb, and 8.78 to 86.3 mg/kg Zn (wet weight). High concentrations of Cd were found in crab, shrimp and shellfish samples, while high concentration of Pb was found in fish. In comparison with the baseline reference values in other parts of the world, fish in the PRE had the highest elevated trace metals. The results of Pb isotopic compositions indicated that the bioaccumulation of Pb in fish come from a wide variety of food sources and/or exposure pathways, particularly the anthropogenic inputs.     

Use of historical and contemporary distribution of mammals in China to inform conservation

A systematic understanding of dynamic animal extinction trajectories for different regions in a nation like China is critically important to developing practical conservation strategies. We explored historical and contemporary changes in terrestrial mammalian diversity to determine how diversity in each of the 5 regions in China has changed over time and to examine the conservation potential of these regions. We used records from databases on Pleistocene mammalian fossils and historical distribution records (1175–2020) for Primates (as a case study) to reconstruct evolutionary and historical distribution trajectories of the 11 orders of terrestrial mammals and to predict their prospective survival based on the national conservation strategy applied. The results indicated that since the Pleistocene, 4–5 mammalian orders have been lost in the northeast, 3 in central China, 2 along the coast, and 1 in the northwest. In the southwest, all 11 orders were maintained. Contemporarily, the coast and southwest had the highest and second-highest species densities. The southwest region and southeastern sections of the northwest region were the most historically and contemporarily diverse areas, which suggests that they should be the first priority for protected area (PA) designation. The central and coastal areas should be secondarily prioritized. In these 2 regions, conservation should focus on human coexistence with nature. Less attention should be paid to the PA in the northeast and western northwest because in these areas ecosystems are depauperate and the climate is harsh. Conservation in these areas should focus principally on avoiding further human encroachment on natural areas. Article impact statement: Historical and contemporary patterns of extinction can be a basis for mammalian conservation strategies.     

Bio-drying and size sorting of municipal solid waste with high water content for improving energy recovery

Bio-drying can enhance the sortability and heating value of municipal solid waste (MSW), consequently improving energy recovery. Bio-drying followed by size sorting was adopted for MSW with high water content to improve its combustibility and reduce potential environmental pollution during the follow-up incineration. The effects of bio-drying and waste particle size on heating values, acid gas and heavy metal emission potential were investigated. The results show that, the water content of MSW decreased from 73.0% to 48.3% after bio-drying, whereas its lower heating value (LHV) increased by 157%. The heavy metal concentrations increased by around 60% due to the loss of dry materials mainly resulting from biodegradation of food residues. The bio-dried waste fractions with particle size higher than 45 mm were mainly composed of plastics and papers, and were preferable for the production of refuse derived fuel (RDF) in view of higher LHV as well as lower heavy metal concentration and emission. However, due to the higher chlorine content and HCl emission potential, attention should be paid to acid gas and dioxin pollution control. Although LHVs of the waste fractions with size <45 mm increased by around 2× after bio-drying, they were still below the quality standards for RDF and much higher heavy metal pollution potential was observed. Different incineration strategies could be adopted for different particle size fractions of MSW, regarding to their combustibility and pollution property.     

Simulation of substrate degradation in composting of sewage sludge

To simulate the substrate degradation kinetics of the composting process, this paper develops a mathematical model with a first-order reaction assumption and heat/mass balance equations. A pilot-scale composting test with a mixture of sewage sludge and wheat straw was conducted in an insulated reactor. The BVS (biodegradable volatile solids) degradation process, matrix mass, MC (moisture content), DM (dry matter) and VS (volatile solid) were simulated numerically by the model and experimental data. The numerical simulation offered a method for simulating k (the first-order rate constant) and estimating k₂₀ (the first-order rate constant at 20 °C). After comparison with experimental values, the relative error of the simulation value of the mass of the compost at maturity was 0.22%, MC 2.9%, DM 4.9% and VS 5.2%, which mean that the simulation is a good fit. The k of sewage sludge was simulated, and k₂₀, k_20s (first-order rate coefficient of slow fraction of BVS at 20 °C) of the sewage sludge were estimated as 0.082 and 0.015 d^?1, respectively.     

Application of response surface methodology to the treatment landfill leachate in a three-dimensional electrochemical reactor

The influence of different variables on the removal of ammonia nitrogen and COD from landfill leachate was investigated in a three-dimensional electrochemical reactor. Box–Behnken statistical experiment design and the response surface methodology were used to investigate operating condition effects, such as current density, activated carbon to water ratio and the reaction time, on ammonia nitrogen removal efficiency and COD removal efficiency. The positive and negative effects of variables and the interaction between variables on ammonia nitrogen removal and COD removal were determined. The response surface methodology models were derived based on the results and the response surface plots were developed accordingly.     

Crystallization and Mechanical Properties of Recycled Poly(ethylene terephthalate) Toughened by Styrene–Ethylene/Butylenes–Styrene Elastomer

Recycled poly(ethylene terephthalate) (R-PET) was blended with 15–30 wt% of styrene–ethylene/butylenes–styrene (SEBS) block copolymer and maleic anhydride grafted SEBS (SEBS-g-MA). Effects of nucleation and toughening of the elastomers were evaluated systematically by study of morphology, crystallization, thermal and mechanical properties of the blend. The addition of 30 wt% SEBS promoted the formation of co-continuous structure of the blend and caused the fracture mechanism to change from strain softening to strain hardening. Addition of SEBS-g-MA resulted in significant modification of phase morphology and obviously improved the impact strength. The compatibilization reaction of PET with SEBS-g-MA accelerated the crystallization of PET and increased the crystallinity. The shifts in glass transition temperature of PET towards that of SEBS-g-MA and the higher modulus for R-PET/SEBS-g-MA (70/30) blend found by DMA are also indications of better interactions under the conditions of compatibilization and interpenetrating structure.     

Environmentally Friendly Polyurethane Composites: Preparation, Characterization and Mechanical Properties

The waterborne polyurethane (PU) prepolymer was prepared based on isophorone diisocyanate (IPDI), polyester polyol (N220), dimethylol propionic acid (DMPA) and hydroxyethyl methyl acrylate (HEMA). The modified waterborne polyurethane–acrylate (PUA) emulsions were obtained with different proportions of acrylate (butyl acrylate and methyl methacrylate) and initiating agent by in situ dispersion technique. The structures and thermal properties of prepared PU and PUA were analyzed and characterized with FT-IR, UV–Vis spectroscopy and DSC. The PUA hybrid samples had lower glass transition temperature of hard segment and higher decomposition temperatures than PU sample. Performances of the emulsion and film were studied by means of apparent viscidity, particle size and polydispersity, surface tension and mechanical properties. The results indicated that the particle sizes of the PUA dispersions were larger than those of the pure PU and the solvent resistance, mechanical properties of PUA films was improved compare with the unmodified polyurethane film. The film had the biggest hardness and the least water absorption when the BA/MMA mass ratio 5:5 modified PU. The obtained PUA have great potential application such as coatings, leather finishing, adhesives, sealants, plastic coatings and wood finishes.     

Design and risk assessment tool for vegetative treatment areas receiving agricultural wastewater: Preliminary results

Vegetative treatment areas (VTAs) are commonly being used as an alternative method of agricultural process wastewater treatment. However, it is also apparent that to completely prevent discharge of pollutants to the surrounding environment, settling of particulates and bound constituents from overland flow through VTAs is not sufficient. For effective remediation of dissolved agricultural pollutants, VTAs must infiltrate incoming wastewater. A simple water balance model for predicting VTA soil saturation and surface discharge in landscapes characterized by sloping terrain and a shallow restrictive layer is presented and discussed. The model accounts for the cumulative effect of successive rainfall events and wastewater input on soil moisture status and depth to water table. Nash–Sutcliffe efficiencies ranged from 0.65 to 0.81 for modeled and observed water table elevations after calibration of saturated hydraulic conductivity. Precipitation data from relatively low, average, and high annual rainfall years were used with soil, site, and contributing area data from an example VTA for simulations and comparisons. Model sensitivity to VTA width and contributing area (i.e. barnyard, feedlot, silage bunker, etc.) curve number was also investigated. Results of this analysis indicate that VTAs should be located on steeper slopes with deeper, more-permeable soils, which effectively lowers the shallow water table. In sloping landscapes (>2%), this model provides practitioners an easy-to-use VTA design and/or risk assessment tool that is more hydrological process-based than current methods.