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排序方式: 共有830条查询结果,搜索用时 15 毫秒
821.
应用13种醛酮类气体标准物质绘制工作曲线,采用超高效液相色谱-二极管阵列检测器(DAD)测定环境空气中13种醛酮类化合物的含量。使用13种醛酮类气体标准物质作为采样对象模拟大气采样,对2,4-二硝基苯肼(DNPH)采样管反应时间、气体环境温度、采样流量等条件进行优化。以气体标准物质为样本,采样体积设定为5 L,在采样温度为25℃、采样流量为0.5 L/min的条件下进行样品采集。采集完毕后,将采样管密封避光保存150 min,随后进行前处理。实验结果显示,大部分化合物的衍生化反应效率可以达到70%以上。该实验条件下,在25~500 nmol/mol浓度范围内绘制工作曲线,所得曲线线性关系良好,相关系数(r)大于0.995。该工作曲线定量方式适用于环境空气中醛酮类化合物的分析。  相似文献   
822.
Environmental Science and Pollution Research - In the present study, the oral bioavailability of cadmium (Cd) in earthworms and leeches was investigated through in vitro physiologically based...  相似文献   
823.
Environmental Science and Pollution Research - Microbial electrolysis cells (MECs) have been applied for antibiotic degradation but simultaneously induced antibiotic resistance genes (ARGs), thus...  相似文献   
824.
Journal of Polymers and the Environment - To improve the interfacial compatibility of wheat straw/polylactic acid (WS/PLA) composites, nano-TiO2 with different particle sizes was blended with...  相似文献   
825.

The quantitative assessment of landfill gas emissions is essential to assess the performance of the landfill cover and gas collection system. The relative error of the measured surface emission of landfill gas may be induced by the static flux chamber technique. This study aims to quantify effects of the size of the chamber, the insertion depth, pressure differential on the relative errors by using an integrated approach of in situ tests, and numerical modeling. A field experiment study of landfill gas emission is conducted by using a static chamber at one landfill site in Xi’an, Northwest China. Additionally, a two-dimensional axisymmetric numerical model for multi-component gas transport in the soil and the static chamber is developed based on the dusty-gas model (DGM). The proposed model is validated by the field data obtained in this study and a set of experimental data in the literature. The results show that DGM model has a better capacity to predict gas transport under a wider range of permeability compared to Blanc’s method. This is due to the fact that DGM model can explain the interaction among gases (e.g., CH4, CO2, O2, and N2) and the Knudsen diffusion process while these mechanisms are not included in Blanc’s model. Increasing the size and the insertion depth of static chambers can reduce the relative error for the flux of CH4 and CO2. For example, increasing the height of chambers from 0.55 to 1.1 m can decrease relative errors of CH4 and CO2 flux by 17% and 18%, respectively. Moreover, we find that gas emission fluxes for the case with positive pressure differential (?Pin-out) are greater than that of the case without considering pressure fluctuations. The Monte Carlo method was adopted to carry out the statistical analysis for quantifying the range of relative errors. The agreement of the measured field data and predicted results demonstrated that the proposed model has the capacity to quantify the emission of landfill gas from the landfill cover systems.

  相似文献   
826.
Environmental Science and Pollution Research - Improving the NOx conversion efficiency and particulate combustion efficiency under cold-start conditions (low-temperature conditions) is still the...  相似文献   
827.
Environmental Science and Pollution Research - The widespread usage of per- and polyfluoroalkyl substances (PFASs) has led to their ubiquitous co-existence with hydrocarbon surfactants in the...  相似文献   
828.
Environmental Science and Pollution Research - Achieving simultaneous determination of antibiotic multiresidues in environmental waters by solid phase extraction (SPE) coupled with...  相似文献   
829.
椅式桩板结构在高陡边坡路基工程中应用广泛,研究其高烈度地震下的响应特征对抗震分析具有重要意义.以拟建川藏铁路某斜坡椅式桩板结构路基支挡工程为背景,建立有限差分三维数值计算模型,研究了结构的静、动力学响应特性,分析了结构最不利状态响应物理量的取值方法,探讨了结构传力分担机制及重要受力部位,提出了结构地震响应简化计算方法....  相似文献   
830.
Han  Dequan  Wang  Hui  Lu  Tingting  Cao  Luya  Dai  Yufei  Cao  Hongzhang  Yu  Xiaoli 《Journal of Polymers and the Environment》2022,30(6):2516-2533
Journal of Polymers and the Environment - As a plastic that can be prepared from biomass resources, polylactic acid (PLA) has the characteristics of being degradable and renewable, and has shown...  相似文献   
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