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701.
Jean P. Paré M.Sc 《Journal of the Air & Waste Management Association (1995)》2013,63(6):325-327
The lead acetate paper tape reagent method for the estimation of hydrogen sulfide in air has been reviewed with the conclusions that the colored spots on which the quantitative estimation is based are not stable and do not lend by themselves to accurate results. Although it may be retained for grab sampling work, the lead acetate paper tape reagent is not acceptable as a stoichiometric reagent in any case where long duration sampling periods are concerned like in air pollution studies. A new mercuric chloride paper tape reagent has been developed as a substitute. Due to the fact that the colored spots resulting from the action of hydrogen sulfide on mercuric chloride are sensitive and very stablet, this new paper tape reagent is proposed as an adequate and reliable analytical too for the estimation of hydrogen sulfide in air. Also, a more comprehensive application of the paper tape analytical system is proposed throughout a suitable control of the factor tape retention capacity vs sampling rate which imposes some restrictions in the selection of the practical working range of concentrations. Nevertheless this working range is still wide enough to encompass all the hydrogen sulfide concentrations normally encountered in the city atmosphere. 相似文献
702.
H. P. Sanderson R. Thomas Morris Katz 《Journal of the Air & Waste Management Association (1995)》2013,63(6):328-330
Field experience with the lead acetate impregnated paper tape sampler has indicated that large errors may arise in this method due to fading of the color of the precipitated lead sulfide spots. This fading is due to the action of light, sulfur dioxide, ozone, on other substances capable of oxidizing lead sulfide. The moisture content or relative humidity of the air sample must be maintained at an appropriate level to ensure reaction with the impregnated paper tape. The effects of the factors have been investigated in laboratory experiments with known concentrations of H2S. A number of antioxidants were studied in relation to the stability of the resultant spots to light and oxidation Orthophenyl phenol was found to be the most effective antioxidant for this purpose. A number of necessary precautions to be employed in the use of the lead acetate method are recommended and the limitations are discussed. 相似文献
703.
704.
705.
P. R. Miller J. R. Parmeter Jr. Brigitta H. Flick C. W. Martinez 《Journal of the Air & Waste Management Association (1995)》2013,63(6):435-438
Photochemical oxidant injury to ponderosa pine (Pinus ponderosa Laws) is a severe problem in the southern California mountains. Three-year-old ponderosa pines fumigated in controlled environment chambers with ozone at 0.15, 0.30, or 0.45 ppm had apparent photosynthesis rates reduced by 10, 70, and 85%, respectively, after 30 days exposure. A fumigation with 0.30 ppm ozone for 33 days depressed the cold perchloric acid extracted polysaccharides of both current and one-year-old needles by 40%. The 80% ethanol soluble sugar concentration of current year, ozone-injured needles increased 16% and that of the one-year-old needles decreased slightly. Both carbohydrate fractions of control trees in carbon-filtered air increased moderately. Higher, endogenous concentrations of ascorbic acid in needles did not protect the tissue from ozone injury. Apparent photosynthesis rate was a sensitive index for ozone dosage response. Needle carbohydrate depletion probably induces premature abscission. 相似文献
706.
H.P. Schuchmann K.J. Laidler 《Journal of the Air & Waste Management Association (1995)》2013,63(1):52-53
Recent studies of organic pyrolyses in the presence of nitric oxide have shown that various nitogen compounds, such as hydrogen cyanide (HCN) and aceto-nitrile (CH3CN) are formed. This suggests the possibility that such compounds will be found in internal combustion processes, and may be present in automobile exhaust gases. The present paper describes some gas-chromatographic and wet analyses of exhaust gases. It is concluded that the amounts of hydrogen cyanide are less than 1 ppm, but that various organic nitrogen compounds may reach a level of about 100 ppm. The significance of these results is discussed. 相似文献
707.
N.C.G. Freeman T. Wainman P.J. Lioy A.H. Stern S.I. Shupack 《Journal of the Air & Waste Management Association (1995)》2013,63(8):604-605
Honorary Memberships are conferred by the Air Pollution Control Association on persons of widely recognized eminence in some part of the field of air pollution control or who have rendered especially meritorious service to the Association. Honorary Memberships were awarded this year to Dr. Leonard Greenburg and Mr. Milton Reizenstein, both past presidents of APCA. 相似文献
708.
R. A. Stoehr J. P. Pezze 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1119-1122
The evolution of H2S and SO2 from hot blast furnace slags by reaction with H2O has been found to be dependent upon the presence of O2 or H2 in the reaction zone as well as on the temperature. H2 has been found to produce a small increase in H2S and a small decrease in SO2 emission, while O2 has been found to produce a very great inhibiting effect on H2S emission and only a small increase in SO2 emission. The total emission of sulfur bearing gases is much less when H2O + air is blown at the slag than when H2O + Ar is blown at the slag, particularly at 1200°C and above. These effects may be useful in attempts to design systems for slag quenching which will produce less pollution. 相似文献
709.
William W. Moyer Fred P. Osman 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1155-1157
Portable air quality monitoring systems may be required to supplement fixed installations or to provide for quick response to a transient situation, possibly at a remote location. A microprocessor-based monitoring unit has been developed for use with existing sensors. The unit is portable and its operational sequence can be programmed to adapt it to any unique requirements existing at the deployment site. Selectable on-site calculations are performed on raw data, and a hard copy or tape record of results can be produced. 相似文献
710.