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1.
白洋淀地区的多氯联苯污染研究   总被引:14,自引:0,他引:14       下载免费PDF全文
对白洋淀地区不同类型纸厂排水口底泥及保定市排污渠底泥进行了GC/ECD分析,可萃取有机氯(EOCl)含量测定,检出了多氯联苯和有机氯农药。用截止分子量为1000道尔顿的透析袋方法对相应地区的水体进行了检测,发现水体中可检出含氯农药六六六,但多氯联苯等由于水中存在浓度低未能检出,同样样品的GC/MS/COM结果表明,水体中主要存在的亲脂性有机污染物为:蒽酮、蒽二酮、苯胺、氯代烃、邻苯二甲酸酯类和苯系物。  相似文献   
2.
Herein,a one-step co-pyrolysis protocol was adopted for the first time to prepare a novel pyrogenic carbon-Cu0/Fe3O4 heteroatoms (FCBC) in CO2 ambiance to discern the roles of each component in PDS activation.During co-pyrolysis,CO2 catalyzed formation of reducing gases by biomass which facilitated reductive transformation of Fe3+ and Cu2+ to Cu0 and Fe3O4,respectively.According to the a...  相似文献   
3.
Per-and polyfluoroalkyl substances(PFASs) are ubiquitous in sludge and water from waste water treatment plants, as a result of their incorporation in everyday products and industrial processes. In this study, we measured several classes of persistent PFASs,precursors, transformation intermediates, and newly identified PFASs in influent and effluent sewage water and sludge from three municipal waste water treatment plants in Sweden, sampled in 2015. For sludge, samples from 2012 and 2014 were analyzed as well.Levels of precursors in sludge exceeded those of perfluoroalkyl acids and sulfonic acids(PFCAs and PFSAs), in 2015 the sum of polyfluoroalkyl phosphoric acid esters(PAPs) were 15–20 ng/g dry weight, the sum of fluorotelomer sulfonic acids(FTSAs) was 0.8–1.3 ng/g,and the sum of perfluorooctane sulfonamides and ethanols ranged from non-detected to 3.2 ng/g. Persistent PFSAs and PFCAs were detected at 1.9–3.9 ng/g and 2.4–7.3 ng/g dry weight, respectively. The influence of precursor compounds was further demonstrated by an observed substantial increase for a majority of the persistent PFCAs and PFSAs in water after waste water treatment. Perfluorohexanoic acid(PFHxA), perfluorooctanoic acid(PFOA), perfluorohexane sulfonic acid(PFHxS), and perfluorooctane sulfonic acid(PFOS)had a net mass increase in all WWTPs, with mean values of 83%, 28%, 37% and 58%,respectively. The load of precursors and intermediates in influent water and sludge combined with net mass increase support the hypothesis that degradation of precursor compounds is a significant contributor to PFAS contamination in the environment.  相似文献   
4.
Seepage from Hg mine wastes and calcines contains high concentrations of mercury (Hg). Hg pollution is a major environmental problem in areas with abandoned mercury mines and retorting units. This study evaluates factors, especially the hydrological and sedimentary variables, governing temporal and spatial variation in levels and state of mercury in streams impacted by Hg contaminated runo . Samples were taken during di erent flow regimes in theWanshan Hg mining area in Guizhou Province, China. In its headwaters the sampled streams/rivers pass by several mine wastes and calcines with high concentration of Hg. Seepage causes serious Hg contamination to the downstream area. Concentrations of Hg in water samples showed significant seasonal variations. Periods of higher flow showed high concentrations of total Hg (THg) in water due to more particles being re-suspended and transported. The concentrations of major anions (e.g., Cl??, F??, NO3?? and SO4 2??) were lower during higher flow due to dilution. Due to both sedimentation of particles and dilution from tributaries the concentration of THg decreased from 2100 ng/L to background levels (< 50 ng/L) within 10 km distance downstream. Sedimentation is the main reason for the fast decrease of the concentration, it accounts for 69% and 60% for higher flow and lower flow regimes respectively in the upper part of the stream. Speciation calculation of the dissolved Hg fraction (DHg) (using Visual MINTEQ) showed that Hg(OH)2 associated with dissolved organic matter is the main form of Hg in dissolved phase in surface waters in Wanshan (over 95%).  相似文献   
5.
<正>今年入秋以来,支原体肺炎就呈现出抢占各地百姓生活头条的趋势,尤其在儿童青少年中发病率居高不下,家长们也特别焦虑,一有风吹草动就要去医院,客观上加剧了当前医院儿科门诊患者扎堆、就诊量居高不下的现象。立冬后气温还会进一步降低,我们如何科学应对支原体肺炎,保持健康的身体?笔者这里就和大家说说有关支原体肺炎及其预防康复事宜。  相似文献   
6.
湖泊颜色是黄龙自然保护区喀斯特景观的核心美景.以黄龙自然保护区喀斯特湖泊和高原非喀斯特湖泊(措琼海、夏茹措)为研究对象,通过高光谱设备测定离水辐亮度量化湖泊水色,对比分析黄龙自然保护区与其他高原非喀斯特湖泊水色特征及其水环境因子,进而探究黄龙自然保护区湖泊水色特征及其影响因素.结果显示:(1)黄龙自然保护区喀斯特湖泊水体呈现蓝绿色,湖泊归一化离水辐亮度反射波长主要集中在420-570 nm.(2)黄龙喀斯特湖泊水化学类型为Ca2+-HCO3-和Mg2+-HCO3-型,具有高透明度和贫营养化等独特的水环境特征,对可见光的吸收、反射和散射具有强烈的波长选择性,而非喀斯特湖泊光谱曲线的变化没有黄龙喀斯特湖泊明显.(3)对黄龙喀斯特湖泊水色成因分析,黄龙喀斯特湖泊含有丰富的Ca2+、Mg2+、HCO3-,钙华沉积是喀斯特湖泊水色形成的核心过程.冗余分析和相关性分析中,不同的水环...  相似文献   
7.
This article presents the results of laboratory tests on the combined effect of whole-body vibration (WBV) and hand-arm vibration (HAV). The reactions of subjects exposed to various combinations of vibration were recorded. The vibrotactile perception threshold (VPT) test identified changes caused by exposure to vibration. Ten male subjects met the criteria of the study. There were 4 series of tests: a reference test and tests after exposure to HAV, WBV, and after simultaneous exposure to HAV and WBV. An analysis of the results (6000 ascending and descending VPTs) showed that the changes in VPTs were greatest after simultaneous exposure to both kinds of vibration. The increase in VPT, for all stimulus frequencies, was then higher than after exposure to HAV or WBV only.  相似文献   
8.
Noise measurements and questionnaire inquiries were carried out for 124 workers of a rolling stock plant to develop a hearing conservation program. On the basis of that data, the risk of noise-induced hearing loss (NIHL) was evaluated. Additionally, the workers' hearing ability was assessed with the (modified) Amsterdam inventory for auditory disability and handicap, (m)AIADH. The workers had been exposed to noise at A-weighted daily noise exposure levels of 74-110 dB for 1-40 years. Almost one third of the workers complained of hearing impairment and the (m)AIADH results showed some hearing difficulties in over half of them. The estimated risk of hearing loss over 25 dB in the frequency range of 3-6 kHz was 41-50% when the standard method of predicting NIHL specified in Standard No. ISO 1999:1990 was used. This risk increased to 50-67% when noise impulsiveness, coexposure to organic solvents, elevated blood pressure and smoking were included in calculations.  相似文献   
9.
为了解长江、嘉陵江(重庆段)源水有机提取物的类雌激素活性,分别于夏季和冬季采用GDX—120大孔树脂对位于城区上、中、下游5个断面长江、嘉陵江(重庆段)源水进行有机物的浓缩提取。用体外MCF—7细胞增殖试验检测有机提取物的类雌激素活性。结果显示,源水有机提取物均具有类雌激素活性。其类雌激素活性中、下游均高于上游,丰水期高于枯水期。  相似文献   
10.
Herein we study the economic performance of hydrochar and synthetic natural gas coproduction from olive tree pruning. The process entails a combination of hydrothermal carbonization and methanation. In a previous work, we evidenced that standalone hydrochar production via HTC results unprofitable. Hence, we propose a step forward on the process design by implementing a methanation, adding value to the gas effluent in an attempt to boost the overall process techno-economic aspects. Three differen...  相似文献   
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