Factors affecting trace-metal bioaccumulation in Finnish headwater lakes

Fourteen unpolluted Finnish headwater lakes with pH values varying from 4.8 to 7.0 were studied for trace-metal concentrations in water, sediment, aquatic plants (Nuphar luteum L., Sparganium sp.), aquatic insect larvae (Limnophilus sp., Phryganea sp.) and fish (Esox lucius L., Perca fluviatilis L., Coregonus sp., Salvelinus fontinalis L., Salmo trutta L.). Trace-metal deposition was estimated by analysing the snowpack. Non-parametric correlation analysis was carried out between trace metal concentrations in biota and pH, ANC, TOC, CA + Mg concentration in water and a given metal concentration in water and sediment. Bioaccumulation of several trace metals increased with increasing acidity and decreasing ANC in water. This was especially true for Pb and Cd. Aquatic plants were, in general, the best indicator group concerning differences in trace-metal bioaccumulation in lakes with different acidity. There was some evidence that a higher concentration of TOC in water may reduce bioaccumulation of Pb, Cd and Zn in aquatic plants and fish. The copper concentration in sediment was the only background variable explaining Cu concentration in aquatic insects. Multivariate analysis of the whole background data gave comparable preliminary results. Over 80% of the trace metal concentrations in biota of different lakes was explained by the background variables. In general, elevated concentrations of most of these trace metals can be expected to occur in the biota of acidified low calcareous lakes.     

A review of the likely causal pathways relating the reduced density of breeding dippers Cinclus cinclus to the acidification of upland streams

Previous work has shown that the breeding density of a bird characteristic of upland streams, the dipper Cinclus cinclus, is markedly reduced at low pH in both Wales and Scotland. Populations also declined when streams became more acidic. Evidence of causal explanation for these relationships is that: (1) Food quantity is reduced in acidic streams, and important prey, including those rich in calcium, are scarce; (2) Blood chemistry in pre-breeding birds differs between acid and circumneutral streams, with plasma calcium reduced in those breeding at low pH. Skeletal sources of calcium are probably limited; (3) The time spent foraging by pre-breeding birds on acidic streams is markedly increased, even though overall energy costs on acidic and circumneutral streams are similar. Body condition is inferior to birds on circumneutral streams; (4) Egg laying is significantly delayed on acidic streams irrespective of an effect on laying of altitude, and clutch and brood sizes are significantly reduced; (5) Eggs are lighter and shells thinner at low pH; (6) Chick growth is reduced at low pH; (7) Contamination by heavy metals and persistent organochlorines is low in the populations on acidic streams and cannot explain the impaired breeding performance. None of these features can exclude the possibilities that acidic streams either hold populations of poor quality birds, which show the above features, or that acidity affects the breeding ecology of all dippers that attempt to breed at low pH. The qualitative outcome of these two alternatives is identical.     

潜力的兑现还是赢者的诅咒——来自跨区域能源项目电价反向招标的证据(2006—2020年)北大核心CSCDCSSCI

能源项目反向招标作为替代统一上网电价的市场自由化政策在全球范围内有效提高了各类能源的降本效率,但近年来项目投标运营主体却陷入了盈利瓶颈。针对这一现象,该研究修正关联价值模型,构建动态竞标决策框架,评估项目成本和产出不确定时能源投资企业附加动态预期的最优投标电价决策,并利用2006—2020年欧美和亚太地区3000余个大型电站电价招标及项目后期运营的样本数据进行检验。结果显示:①几乎全球能源投资企业都会陷入“过分乐观”预期导致的“赢者诅咒”怪圈,最终所持项目的实际运营收益远低于预期。投标主体往往更容易低估项目建设和运营的成本压力和风险,并高估项目的电力产出和收入稳定性,尤其在联合投标机制被取消和禁止以后,招标结果甚至变得更加激进。由于经历过超预期技术进步的持续修正,过度乐观的预期超越了行业内生性的技术进步,成为持续施压电价下降的重要动力。②当前的能源产业特别是风、光新能源未能有效发挥行业潜力,随着新能源行业技术革新,它较之火电项目表现出更加激进的竞标策略。在内卷化竞标压力下,内生性的成本优化阻碍了新能源项目的潜力发挥,当期成本是导致其陷入“赢者诅咒”的最重要原因。③在考虑学习曲线效应等诸多因素以后,除了企业的融资成本优势以外,样本数据并未发现包括经验、市场环境等内外部因素能使企业跳出这一怪圈。甚至在过去的5年左右时间里,“赢者诅咒”导致的项目投资利润下降超过市场技术进步因素,一度成为风电和太阳能项目电力价格下降的最主要因素。因此,健康可持续的能源产业政策需要立足于上游持续的技术革新,完善绿色金融为基础的资本市场体系,确保提供优质项目服务能源消费者,并为能源项目投资者提供来自资本市场的认可和支持。     

江苏省环境监测系统进行监测分析质量大检查

由江苏省环保局、省监测站具体领导、并由省和各市监测站质量管理人员组成的“江苏省环境监测质量管理组”,于今年9月1日至13日分南北两片对全省十一个省辖市监测站实验室的监测分析质量进行了全面检查。     

湖北省召开大气环境监测网站工作会议

会议对全省网络建设基本情况、网站设置内容落实情况、监测质量保证及网站建设中存在的问题等作了全面总结,讨论和修订了《湖北省大气环境例行监测技术规定》.省中心站还表扬了多年来不间断监测、上报数据齐全、报表清晰和规矩的网站,同时对今后网站工作提出了要求.     

用新制蒸馏水代替重蒸蒸馏水配制测定亚硝酸盐氮、氨氮、酚的试液

用新制蒸馏水代替重蒸蒸馏水配制测定亚硝酸盐氮、氨氮、酚的试液ＣｏｍｐｏｕｎｄｅｄＴｈｅＳｏｌｕｔｉｏｎＮｉｔｒｉｔｅ－Ｎ，Ａｍｍｏｎｉａ－ＮａｎｄＰｈｅｎｏｌＷｉｔｈＮｅｗ－ｍａｄｅＤｉｓｔｉｌｅｄＷａｔｅｒｉｎｓｔｅａｄｏｆＡｆｒｅｓｈＤｉｓｔｉｌ...     

山东省首家县级环境监测网在博山成立

为提高博山地区的整体环境监测能力,准确、及时、全面地掌握环境质量和污染源变化动态,根据《中华人民共和国环境保护法》、《全国环境监测网络管理规定》、《全国环境监测管理条例》等法律、法规的要求,山东省淄博市博山区于1996年1月19日率先在省内成立首家地区性环境监测网,即博山地区环境监测网(以下简称博山网)。     

微量铊~(Ⅲ)的螯合滴定

本文比较了4-(2-吡啶偶氮)间苯二酚(PAR)、1-(2-吡啶偶氮)-2-萘酚(PAN)、2-(2-噻唑偶氮)-5-二乙氨基苯酚(TAF)、二甲酚橙(XO)、2-(2-苯骈噻唑偶氮)-5-二乙氨基苯酚(BAE)、1-(2-噻唑偶氮)-2-萘酚(TAN)、4-(2-噻唑偶氮)间苯二酚(TAR)、甲基百里酚兰(MTB)等八种金属指示剂于直接螫合滴定微量铊(Ⅲ)的适宜酸度范围、适宜温度范围和可测范围。其中以PAR、PAN XO和TAE更适宜于微量铊(Ⅲ)的滴定,其测定最低限可达4微克铊(Ⅲ),且酸度范围也较广,终点变色敏锐。本文还讨论了以PAR、XO、TAE为指示剂滴定铊(Ⅲ)时,其它离子干扰情况以及部分干扰离子的消除方法。最后还以PAR为指示剂螫合滴定测定天然水和工厂废水中微量铊,以及铊(Ⅲ)和铊(Ⅰ)共存时的连续测定。     

用广义λ—分布拟合空气污染数据

广义λ-分布是一个四参数可变通的概率模型,包括多种单变量分布,这一模型可用于表示空气污染浓度的频率分布。本文采用土耳其安卡拉每日的烟和SO_2监测数据,来证明广义λ-分布具有良好的拟合性质。这里还讨论了与分位数估计和拟合优度有关的一些结果,并与经典对数正态分布进行了比较。     

新疆核试验场周围各类土壤中~(90)Sr、~(137)Cs分布与迁移

本文对新疆核试验场周围10个调查地区和5个对照地区采集180个土壤样品进行了~(90)Sr、~(137)Cs放射性含量的分析,结果表明,在各类土壤中~(90)Sr、~(137)Cs的放射性含量除黄粘土与潮土、盐土及风沙土有非常显著性差异外(p<0.01),其余各类土壤之间均无显著性差异(p>0.05)。~(90)Sr、~(137)Cs在各类土壤中的垂直分布随深度的增加而含量减少。0～10Cm剖层中的~(137)Cs含量高于~(90)Sr的含量,而在10～20Cm和20～30Cm剖层中则~(90)Sr含量高于~(137)Cs的含量。其迁移速度,潮土、盐土、风沙土之间看不出多大的差别,但黄粘土较慢。~(90)Sr、~(137)Cs在各类土壤中均呈现出~(90)Sr的迁移比~(137)Cs快的总趋势。