Application of cold-induced aggregation microextraction as a fast,simple, and organic solvent-free method for the separation and preconcentration of Se(IV) in rice and various water samples

The developed method is based on cold-induced aggregation microextraction of Se(IV) using the 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid as an extractant followed by spectrophotometry determination. The extraction of Se(IV) was performed in the presence of dithizone as the complexing agent. In this method, a very small amount of 1-butyl-3-methylimidazolium hexafluorophosphate was added to the sample solution containing Se-dithizone complex. Then, the solution was kept in a thermostated bath at 50 °C for 4 min. Subsequently, the solution was cooled in an ice bath and a cloudy solution was formed. After centrifuging, the extractant phase was analyzed using a spectrophotometric detection method. Some important parameters that might affect the extraction efficiency were optimized (HCl, 0.6 mol L^?1; dithizone, 4.0?×?10^?6 mol L^?1; ionic liquid, 100 μL). Under the optimum conditions, good linear relationship, sensitivity, and reproducibility were obtained. The limit of detection (LOD) (3S_b/m) was 1.5 μg L^?1, and the relative standard deviation (RSD) was 1.2 % for 30 μg L^?1 of Se(IV). The linear range was obtained in the range of 5–60 μg L^?1. It was satisfactory to analyze rice and various water samples.     

Performance of a hybrid solar collector system in days with stable and less stable radiative regime

The aim of this work is to analyse the performance of a solar energy collector system for water and air heating in real working conditions. Two coupled mathematical models have been developed. One of them describes the thermal behaviour of the Hybrid Solar Collector (HSC) and the second one describes the simultaneous operation of the HSC and of a fully mixed water storage tank. The dependence of the performance of the HSC system on the following three parameters has been studied: (1) water and air mass flow rate; (2) water pipe diameter and air channel height; (3) water storage tank volume. The mathematical models were used to evaluate the HSC system performance during 29 different days, covering all four seasons. A higher water flow rate generally enhances the thermal efficiency of the HSC system, but the enhancement became significantly smaller at higher air flow rates. Positive but small values are recommended for the difference between the fluid temperature at solar collectors exit and the water temperature in the tank. The thermal efficiency of the HSC system is higher on nearly clear sky and decreases in case the amount of clouds on the sky increases.