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61.
Ajay Kumar Sumit Sharma Rohit Mehra Priya Kanwar Rosaline Mishra Inderpreet Kaur 《Environmental geochemistry and health》2018,40(2):815-831
Radon concentration was measured in water samples of 41 different locations from Udhampur district of Jammu & Kashmir, India, by using RAD7 and Smart RnDuo monitor. The variation of radon concentration in water ranged from 1.44 ± 0.31 to 63.64 ± 2.88 Bq L?1, with a mean value of 28.73 Bq L?1 using RAD7 and 0.64 ± 0.28 to 52.65 ± 2.50 Bq L?1, with a mean value of 20.30 Bq L?1 using Smart RnDuo monitor, respectively. About 17.07% of the studied water samples recorded to display elevated radon concentration above the reference range suggested by United Nation Scientific Committee on the Effects of Atomic Radiations (UNSCEAR). The mean annual effective dose of these samples was determined, and 78.95% samples were found to be within the safe limits set by World Health Organisation (WHO) and European Council (EU). The study revealed good agreement between the values obtained with two methods. Heavy metals (Zn, Cd, Fe, Cu, Ni, As, Hg, Co, Pb and Cr) were determined in water samples by microwave plasma atomic emission spectrometer, and their correlation with radon content was also analysed. 相似文献
62.
Elsayed Elbeshbishy Saad Aldin George Nakhla Ajay Singh Bill Mullin 《Waste management (New York, N.Y.)》2014,34(11):2090-2097
The effect of different Lystek biosolids doses on the anaerobic digestability of thickened waste activated sludge (TWAS) was evaluated in a lab- and full-scale anaerobic digester. The overall findings of this study emphasize the beneficial impact of Lystek addition to the lab- and full-scale anaerobic digesters in terms of enhanced biogas production and increased volatile suspended solids reduction (VSSR) efficiency. Lystek added at 4% by volume to TWAS increased the methane yield from 0.22 to 0.26 L CH4/g VSSadded at an solids retention time (SRT) of 10 days, and from 0.27 to 0.29 L CH4/g VSSadded at an SRT of 15 days. Furthermore, the VSSRs of 37% and 47% were observed for the TWAS, and the TWAS with 4% Lystek, while at an SRT of 15 days, the observed VSSR were 49% and 58%, respectively. The lab-scale study showed that the influence of Lystek addition on methane yield and solids destruction efficiencies was more pronounced at the shorter SRT, 20% enhancement (SRT of 10 d) vs. 9% enhancement (SRT of 15 d) for methane yield, and 27% (SRT of 10 d) vs. 22% (SRT of 15 d) for VSS destruction efficiency improvement. Furthermore, addition of 4% of Lystek to the feed of the full-scale anaerobic digester at St. Marys wastewater treatment plant (WWTP) resulted in a 50% increase in the average specific methanogenic activity and 23% increase in methane yield of the biochemical methane potential tests after eight months. The results showed that Lystek degradation kinetics were 40% faster than the TWAS, as reflected by first order kinetic coefficients of 0.053 d?1 and 0.073 d?1 for TWAS and Lystek at an SRT of 10 days. 相似文献
63.
Distinctiveness theory posits that patterns of social identity and friendship are based on numeric rarity within specific contexts. In ethnically diverse organizations, the theory predicts that members of the smaller ethnic group (relative to members of the larger ethnic group) will: (a) tend to identify and form friendships within their own ethnic group, and (b) lack access to well‐connected individuals in the network of friendship relations. Prior tests have supported these predictions, but they have been unable to rule out the possibility that it was chronic differences in social status and numeric representation in society at large (rather than numeric distinctiveness within specific contexts) that explained the observed patterns of social identity and friendship. In this field‐based study, we examined an organization whose social composition effectively controlled for these confounds. We found that members of the smaller ethnic group tended to identify and form friendships within group, as predicted by distinctiveness theory. However, in contrast to previous work, we found that members of the smaller ethnic group were equally well connected to the center of the friendship network as were the members of the larger ethnic group. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
64.
Kesavachandran Chandrasekharan Nair Prathish Krishna Pillai Sakhre Saurabh Ajay Sundaresan Vasanthi Rahul Chirackal Muraleedharan 《Environmental science and pollution research international》2022,29(21):30802-30807
Environmental Science and Pollution Research - The World Health Organization has proposed the ambient air quality guidelines 2021. The uniqueness of the guidelines of the World Health Organization... 相似文献
65.
Atmospheric deposition studies of heavy metals in Arctic by comparative analysis of lichens and cryoconite 总被引:1,自引:0,他引:1
Shiv Mohan Singh Jagdev Sharma Puja Gawas-Sakhalkar Ajay K. Upadhyay Simantini Naik Shailesh M. Pedneker Rasik Ravindra 《Environmental monitoring and assessment》2013,185(2):1367-1376
Lichens and cryoconite (rounded or granular, brownish-black debris occurring in holes on the glacier surface) from Ny-Ålesund were used for understanding the elemental deposition pattern in the area. Lichen samples collected from low-lying coastal region and cryoconite samples from high altitudinal glacier area were processed and analysed for elements such as aluminium (Al), arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), cesium (Cs), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb), vanadium (V) and zinc (Zn) through inductively coupled plasma mass spectrometry. Results showed that heavy metals, Al and Fe, are present in high concentration in the cryoconite samples. Al was also present in high amounts in seven of the eight lichen samples studied. The general scheme of elements in the decreasing order of their concentrations for most of the cryoconite samples was Al?>?Fe?>?Mn?>?Zn?>?V?>?Pb?>?Cr?>?Ni?>?Cu?>?Co?>?As?>?Cs?>?Cd while that for the lichen samples was Al?>?Fe?>?Zn?>?Mn?>?Pb?>?Cu?>?Cs?>?Cr?>?Ni?>?V?>?Co?>?As?>?Cd. Similarity in trends in the two sample types confirms that the environment indeed contains these elements in that order of concentration which overtime got accumulated in the samples. Overall comparison showed most elements to be present in high concentrations in the cryoconite samples as compared to the lichen samples. Within the lichens, elemental accumulation data suggests that the low-lying site (L-2) from where Cladonia mediterranea sample was collected was the most polluted accumulating a number of elements at high concentrations. The probable reasons for such deposition patterns in the region could be natural (crustal contribution and sea salt spray) and anthropogenic (local and long-distance transmission of dust particles). In the future, this data can form a baseline for monitoring quantum of atmospheric heavy metal deposition in lichens and cryoconite of Svalbard, Arctic. 相似文献
66.
Abhishek Dutt Tripathi Ajay Yadav Alok Jha S. K. Srivastava 《Journal of Polymers and the Environment》2012,20(2):446-453
In the present study, depending upon the availability and cheaper cost, different carbon source were tested for the production of PHAs (Polyhydroxyalkonoates) by soil bacterium Pseudomonas aeruginosa and it was found that sugar refinery waste (cane molasses) produced the maximum PHA (biodegradable polymer) which is precursor for bio-plastic development. Urea served as potent nitrogen source over other inorganic nitrogen sources in bio-plastic synthesis. Effect of different physical parameters viz; pH, temperature and agitation speed were also studied on PHA production. Batch cultivation kinetics under optimized cultural and physical condition showed maximum cell mass and PHA concentration of 7.32?±?0.2 and 5.60?±?0.3?g/L, respectively after 54.0?h of cultivation. Sugar refinery waste (Total sugar 4%) and urea (0.8%) improved the economics of the process which exhibited a yield (YP/X) of 0.70 with productivity of 0.11?g/L/h. PHA was further characterized as PHB by using Fourier Transform Infra-red Spectroscopy (FT-IR). 相似文献
67.
Ajay Kumar Meena Parveen Bansal Sanjiv Kumar M. M. Rao V. K. Garg 《Environmental monitoring and assessment》2010,170(1-4):657-660
Popularity of herbal drugs is increasing all over the world because of lesser side effects as compared to synthetic drugs besides it cost effectiveness and easy availability to poor people particularly in developing countries. Keeping in view the increased market demand of herbal drugs, it is essential to ensure their chemical quality prior to use. Raw drugs and herbs are usually collected from different places, which might be contaminated with various contaminants. It is pertinent to estimate the levels of heavy metals and other micronutrients, which could be affected by their presence in the surrounding environments. Heavy metals are known to pose a potential threat to terrestrial and aquatic biota. Keeping this in view, samples of ten plants or plant parts used in drug making were collected from local markets of Punjab for heavy metal and micronutrient estimation. It was found that the samples were contaminated having cadmium, lead, chromium, iron, manganese, and zinc. The highest mean level of cadmium (23.1 μg/kg) was found in Haritaki sample. Chromium concentration of the plant samples ranged between 7.25 and 1.34 μg/kg with the highest values was in Daruharidra and lowest in Pippali. The levels of these heavy metals were within permissible limits 相似文献
68.
Kinetic assessment of the potassium ferrate(VI) oxidation of antibacterial drug sulfamethoxazole 总被引:1,自引:0,他引:1
Sulfamethoxazole (SMX), a worldwide-applied antibacterial drug, was recently found in surface waters and in secondary wastewater effluents, which may result in ecotoxical effects in the environment. Herein, removal of SMX by environmentally-friendly oxidant, potassium ferrate(VI) (K(2)FeO(4)), is sought by studying the kinetics of the reaction between Fe(VI) and SMX as a function of pH (6.93-9.50) and temperature (15-45 degrees C). The rate law for the oxidation of SMX by Fe(VI) is first-order with respect to each reactant. The observed second-order rate constant decreased non-linearly from 1.33+/-0.08 x 10(3) M(-1)s(-1) to 1.33+/-0.10 x 10(0) M(-1)s(-1) with an increase of pH from 7.00 to 9.50. This is related to protonation of Fe(VI) (HFeO(4)(-) <==> H(+) + FeO(4)(2-); pK(a,HFeO(4)) = 7.23) and sulfamethoxazole (SH <==> H(+) + S(-); pK(a,SH)=5.7). The estimated rate constants were k(11)(HFeO(4)(-) + SH) = 3.0 x 10(4) M(-1)s(-1), k(12)(HFeO(4)(-) + S(-)) = 1.7 x 10(2) M(-1)s(-1), and k(13) (FeO(4)(2-) + SH) = 1.2 x 10(0) M(-1)s(-1). The energy of activation at pH 7.0 was found to be 1.86+/-0.04 kJ mol(-1). If excess potassium ferrate(VI) concentration (10 microM) is used than the SMX in water, the half-life of the reaction using a rate constant obtained in our study would be approximately 2 min at pH 7. The reaction rates are pH dependent; thus, so are the half-lives of the reactions. The results suggest that K(2)FeO(4) has the potential to serve as an oxidative treatment chemical for removing SMX in water. 相似文献
69.
Piscicidal activities of aqueous extracts of Euphorbia tirucalli were very well established, but their ultimate mode of action on fish metabolism was not yet known. Exposure of fishes over 24h or 96h to sub-lethal doses (40% and 80% of LC(50)) of aqueous extract of E. tirucalli stem-bark and latex, significantly (P<0.05) altered the level of total protein, total free amino acids, nucleic acids, glycogen, pyruvate, lactate and activity of protease, alanine aminotransferase, aspartate aminotransferase, acetylcholinesterase and cytochrome oxidase enzyme in liver and muscle tissues of freshwater fish Channa punctatus. The alterations in all these biochemical parameters were significantly (P<0.05) time- and dose-dependent. After 7d of withdrawal of treatment of 80% of LC(50) of E. tirucalli extracts shows that there was a partial recovery in the levels of glycogen but nearly complete recovery in total protein, total free amino acids, pyruvate, lactate, nucleic acids level and activity of protease, aspartate aminotransferase, alanine aminotransferase, acetylcholinesterase and cytochrome oxidase enzyme in both the tissues of fish. Thus aqueous extracts of E. tirucalli adversely affect respiratory pathway of fish and cause energy crisis during stress by suppressing ATP production. The reversibility of the action of the aqueous extracts would be an additional advantage in their use. 相似文献
70.
A simple sol–gel method was employed to prepare gadolinium, nitrogen and sulphur tridoped titania decorated on oxidised multiwalled carbon nanotubes (MWCNT/Gd,N,S-TiO2), using titanium (IV) butoxide and thiourea as titanium and nitrogen and sulphur source, respectively. Samples of varying gadolinium loadings (0.2%, 0.6%, 1.0% and 3.0% Gd3 +) relative to titania were prepared to investigate the effect of gadolinium loading and the amounts of carbon nanotubes, nitrogen and sulphur were kept constant for all the samples. Furthermore, the prepared nanocomposites were evaluated for the degradation of naphthol blue black (NBB) in water under simulated solar light irradiation. Higher degradation efficiency (95.7%) was recorded for the MWCNT/Gd,N,S-TiO2 (0.6% Gd) nanocomposites. The higher photocatalytic activity is attributed to the combined effect of improved visible light absorption and charge separation due to the synergistic effect of Gd, MWCNTs, N, S and TiO2. Total organic carbon (TOC) analysis revealed a higher degree of complete mineralisation of naphthol blue black (78.0% TOC removal) which minimises the possible formation of toxic degradation by-products such as the aromatic amines. The MWCNT/Gd,N,S-TiO2 (0.6% Gd) was fairly stable and could be re-used for five times, reaching a maximum degradation efficiency of 91.8% after the five cycles. 相似文献