全文获取类型
收费全文 | 1190篇 |
免费 | 12篇 |
国内免费 | 45篇 |
专业分类
安全科学 | 58篇 |
废物处理 | 119篇 |
环保管理 | 107篇 |
综合类 | 106篇 |
基础理论 | 185篇 |
环境理论 | 1篇 |
污染及防治 | 428篇 |
评价与监测 | 167篇 |
社会与环境 | 66篇 |
灾害及防治 | 10篇 |
出版年
2024年 | 1篇 |
2023年 | 35篇 |
2022年 | 148篇 |
2021年 | 117篇 |
2020年 | 41篇 |
2019年 | 49篇 |
2018年 | 64篇 |
2017年 | 81篇 |
2016年 | 73篇 |
2015年 | 37篇 |
2014年 | 45篇 |
2013年 | 145篇 |
2012年 | 61篇 |
2011年 | 77篇 |
2010年 | 49篇 |
2009年 | 35篇 |
2008年 | 29篇 |
2007年 | 30篇 |
2006年 | 24篇 |
2005年 | 13篇 |
2004年 | 20篇 |
2003年 | 9篇 |
2002年 | 8篇 |
2001年 | 7篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1970年 | 1篇 |
1965年 | 1篇 |
1964年 | 2篇 |
1959年 | 1篇 |
排序方式: 共有1247条查询结果,搜索用时 15 毫秒
941.
Mohammad Ali Taher Nezhat Jandaghi Hamid Fazelirad Hamid Ashkenani 《Environmental monitoring and assessment》2014,186(3):1987-1997
In the present work, a batch preconcentration technique using nanoclay with 5-(4-dimethylaminobenzylidene)rhodanine coupled with electrothermal atomic absorption spectrometry was developed for the separation and determination of trace amounts of palladium. In this method, the sample solution was stirred with nanoclay as an adsorbent. Then, adsorbed palladium was subsequently eluted with HCl in acetone (1.5 mol L?1) and, finally, this eluate was injected to electrothermal atomic absorption spectrometry. Under the optimum conditions, the limit of detection and linear dynamic range were found to be 2.6 and 10.0–133 ng L?1 (in original solution), respectively. Furthermore, the enrichment factor and relative standard deviation of seven replicate determinations were 148 and ±5.1 %, respectively. This suggested method is simple, selective and sensitive and can be applied to the extraction and determination of palladium in water, tea leaves, synthetic sample and certified reference material with satisfactory results. 相似文献
942.
A comparison of radiometric correction techniques in the evaluation of the relationship between LST and NDVI in Landsat imagery 总被引:1,自引:0,他引:1
Atmospheric corrections for multi-temporal optical satellite images are necessary, especially in change detection analyses,
such as normalized difference vegetation index (NDVI) rationing. Abrupt change detection analysis using remote-sensing techniques
requires radiometric congruity and atmospheric correction to monitor terrestrial surfaces over time. Two atmospheric correction
methods were used for this study: relative radiometric normalization and the simplified method for atmospheric correction
(SMAC) in the solar spectrum. A multi-temporal data set consisting of two sets of Landsat images from the period between 1991
and 2002 of Penang Island, Malaysia, was used to compare NDVI maps, which were generated using the proposed atmospheric correction
methods. Land surface temperature (LST) was retrieved using ATCOR3_T in PCI Geomatica 10.1 image processing software. Linear
regression analysis was utilized to analyze the relationship between NDVI and LST. This study reveals that both of the proposed
atmospheric correction methods yielded high accuracy through examination of the linear correlation coefficients. To check
for the accuracy of the equation obtained through linear regression analysis for every single satellite image, 20 points were
randomly chosen. The results showed that the SMAC method yielded a constant value (in terms of error) to predict the NDVI
value from linear regression analysis-derived equation. The errors (average) from both proposed atmospheric correction methods
were less than 10%. 相似文献
943.
Hamid Reza Sobhi Ali Esrafili Hadi Farahani Mitra Gholami Mohammad Mehdi Baneshi 《Environmental monitoring and assessment》2013,185(11):9055-9065
A simple and sensitive method based on a modified hollow-fiber liquid-phase microextraction followed by gas chromatography–mass spectrometry has been successfully developed for the extraction and simultaneous derivatization of some nitrophenols (NPs) in soil and rain samples. Microwave-assisted solvent extraction was used for the extraction of NPs from the soil, while the rain sample was directly applied to the previously mentioned method. Briefly, in this method, the analytes were extracted from aqueous samples into a thin layer of organic solvent (dodecane?+?10 % tri-n-octylphosphine oxide) sustained in the pores of a porous hollow fiber. Then, they were back-extracted using a small volume of organic acceptor solution (25 μl; 10 mg/L N-methyl-N-(trimethylsilyl)trifluoroacetamide, as derivatization reagent, in acetonitrile) that was located inside the lumen of the hollow fiber. Under the optimized extraction conditions, enrichment factors of 255 to 280 and limits of detection of 0.1 to 0.2 μg/L (S/N?=?3) with dynamic linear ranges of 1–100 μg/L were obtained for the analytes. The accuracy of the approach was tested by the relative recovery experiments on spiked samples, with results ranging from 93 to 113 %. The method was shown to be rapid, cost-effective, and potentially interesting for screening purposes. 相似文献
944.
Mahmoud Chamsaz Mohammad Eftekhari Ali Eftekhari Ali Yekkebashi 《Environmental monitoring and assessment》2013,185(11):9067-9075
Highly rapid and selective vortex-assisted liquid–liquid microextraction based on solidification of organic drop has been used for determination of cobalt ion. 2-Nitroso-1-naphthol (2N1N) was used as a selective complexing agent to form stable cobalt–2N1N complex which can be extracted with 1-undecanol at a short time by the assistance of vortex agitator system followed by its determination using flame atomic absorption spectrometry. In vortex assisted, vigorous vortex stream as well as the vibrant effect of vortex system cause very fine droplets of extraction solvent to be produced and extraction occurred at a short time. Some parameters influencing the extraction process such as pH of samples, concentration of 2-nitroso-1-naphthol, extraction solvent volume, extraction time, ionic strength and surfactant addition, as well as interferences were evaluated in detail and optimum conditions were selected. At the optimum conditions, the calibration curve was linear in the range of 15 to 400 μg L?1 of cobalt ions. The relative standard deviation based on ten replicate analysis of sample solution containing 50 μg L?1 of cobalt was 3.4 %. The detection limit (calculated as the concentration equivalent to three times of the standard deviation of the blank divided by the slope of the calibration curve after preconcentration) was 5.4 μg L?1. The accuracy of the proposed method was successfully evaluated by the analysis of certified reference materials. This selective and highly rapid method was used for determination of cobalt ions in different water samples. 相似文献
945.
Soroush Modabberi Ali Alizadegan Hassan Mirnejad Esmat Esmaeilzadeh 《Environmental monitoring and assessment》2013,185(11):9077-9087
This study investigates the possibility of acid mine drainage (AMD) generation in active and derelict mine waste piles in Sarcheshmeh Copper Mine produced in several decades, using static tests including acid–base accounting (ABA) and net acid-generating pH (NAGpH). In this study, 51 composite samples were taken from 11 waste heaps, and static ABA and NAGpH tests were carried out on samples. While some piles are acid producing at present and AMD is discharging from the piles, most of them do not show any indication on their AMD potential, and they were investigated to define their acid-producing potential. The analysis of data indicates that eight waste piles are potentially acid generating with net neutralization potentials (NNPs) of ?56.18 to ?199.3, net acid generating of 2.19–3.31, and NPRs from 0.18 to 0.44. Other waste piles exhibited either a very low sulfur, high carbonate content or excess carbonate over sulfur; hence, they are not capable of acid production or they can be considered as weak acid producers. Consistency between results of ABA and NAGpH tests using a variety of classification criteria validates these tests as powerful means for preliminary evaluation of AMD/ARD possibilities in any mining district. It is also concluded that some of the piles with very negative NNPs are capable to produce AMD naturally, and they can be used in heap leaching process for economic recovery of trace amounts of metals without applying any biostimulation methods. 相似文献
946.
N. Mohd Tahir S. Y. Pang N. A. Abdullah S. Suratman 《Environmental monitoring and assessment》2013,185(12):10209-10216
Near-shore surface sediment was collected from five stations off Redang Island located on the eastern coast of Peninsular Malaysia. Freeze-dried sediments were Soxhlet extracted and then fractionated using column chromatography into aliphatic and polar fractions. Determination of these fractions was carried out using gas chromatography mass spectrometry. The concentration of total resolved aliphatic hydrocarbons in sediments ranged from 157 to 308 ng/g. The distribution of aliphatic fraction showed the presence of n-alkanes ranging from nC15 to nC33 with a minor odd-to-even predominance exhibiting carbon maximum, depending on station, at nC17, nC26, nC29 or nC31. Calculation of Carbon Preference Index (CPI) for CPI15–33 gave values ranging from 1.09 to 1.46. n-Alkanol in all sediment exhibits even-to-odd carbon predominance ranging from nC16 to nC28 and maximising at nC22. n-Fatty acids distribution ranged from nC14 to nC24 with a dominant maximum at nC16 and exhibiting high values of short chain fatty acids (≤nC20) to long chain fatty acids (>nC20) ratios. Unsaturated fatty acids, particularly nC16:1 and nC18:1 is also ubiquitous in all samples. Cholesterol is the most abundant compound amongst the sterol group ranging from 42.8 to 62.6 % of the total sterols. β-Sitosterol, brassicasterol and stigmasterol, are also present but of relatively lower amount. These observations suggest that the aliphatic lipids and sterols in the study area originate, mainly, from biogenic sources of marine microbial with minor contribution from epiticular waxes of terrestrial plants. 相似文献
947.
Riasat Ali Richard Silberstein John Byrne Geoff Hodgson 《Environmental monitoring and assessment》2013,185(11):9619-9637
The use of surface and subsurface drainage to manage waterlogging and salinity in dryland (rainfed) and irrigated agricultural systems is common throughout the world. The drainage systems often discharge into natural streams. The same is true for the wheatbelt drainage systems in south-western Australia, where 11,000 km (ABS 2003) of artificial drains have been constructed within the last two decades. Prior to this study, the likely impacts of this discharge on the streambed chemistry and water quality of receiving streams were largely unknown. The study evaluated these impacts in creeks receiving the drainage discharge from engineering options in four river systems in south-western Australia. This study clearly showed elevated levels of metals ions, EC and pH in the stream water at treated sites relative to their levels at untreated sites. At most sites, impacts of drainage discharge were observed on the streambed electrical conductivity (EC) and pH (both in 1:5 extract) in the receiving streams; however, there was little evidence of impact on metal ion content in the streambed soil. The study found no clear differences in the dynamics of the watertable adjacent to streams whether they received drainage discharge or not, irrespective of the size of the artificial drainage systems. 相似文献
948.
A dissolved oxygen (DO) model is calibrated and verified for a highly polluted River Ravi with large flow variations. The model calibration is done under medium flow conditions (431.5 m3/s), whereas the model verification is done using the data collected during low flow conditions (52.6 m3/s). Biokinetic rate coefficients for carbonaceous biochemical oxygen demand (CBOD) and nitrogenous biochemical oxygen demand (NBOD) (i.e, K cr and K n ) are determined through the measured CBOD and ammonia river profiles. The calculated values of K cr and K n are 0.36 day?1 and 0.34 day?1, respectively. The close agreement between the DO model results and the field values shows that the verified model can be used to develop DO management strategies for the River Ravi. The biokinetic coefficients are known to vary with degree of treatment (DOT) and therefore need to be adjusted for a rational water quality management model. The effect of this variation on level of treatment has been evaluated by using the verified model to attain a DO standard of 4 mg/L in the river using the biokinetic rate coefficients as determined during the model calibration and verification process. The required DOT in this case is found to be 96 %, whereas the DOT is 86 % if adjusted biokinetic rate coefficients are used to reflect the effect of wastewater treatment. The cost of wastewater treatment is known to increase exponentially as the removal efficiency increases; therefore, the use of appropriate biokinetic coefficients to manage the water quality in rivers is important. 相似文献
949.
Assessing implications of land use and land cover changes in forest ecosystems of NE Turkey 总被引:1,自引:0,他引:1
Ali İhsan Kadıoğulları 《Environmental monitoring and assessment》2013,185(3):2095-2106
Monitoring land use and land cover change (LUCC) and understanding forest cover dynamics is extremely important in sustainable development and management of forest ecosystems. This study analyzed the spatial and temporal pattern of LUCC in the Yaln?zçam and U?urlu forest planning units which are located in the northeast corner of Turkey. The investigation also evaluates the temporal changes of the spatial structure of forest conditions through the spatial analysis of forest-cover type maps from 1972 and 2005 using geographical information systems and FRAGSTATSTM. As an overall change between 1972 and 2005, there was a net increase of 1,823 ha in forested areas, and cumulative forest improvement accounted for 2.06 %. In terms of spatial configuration, the landscape structure in the study area changed substantially over the 33-year study period, resulting in fragmentation of the landscape as indicated by large patch numbers and smaller mean patch sizes, owing to heavy grazing, illegal cutting, and uncontrolled stand treatments. 相似文献
950.
Selection of MSW landfill site for Konya, Turkey using GIS and multi-criteria evaluation 总被引:4,自引:0,他引:4
Bilgehan Nas Tayfun Cay Fatih Iscan Ali Berktay 《Environmental monitoring and assessment》2010,160(1-4):491-500
Landfill is a common solution for the final disposal of municipal solid waste (MSW) in Turkey. Landfill siting is an extremely difficult task to accomplish because the site selection process depends on different factors and regulations. To ensure that an appropriate site is chosen, a systematic process should be developed and followed. Unsuccessful landfill siting is typically the result of strong public opposition. In this study, candidate sites for an appropriate landfill area in Cumra County of Konya City are determined by using the integration of geographic information systems (GIS) and multi-criteria evaluation (MCE). ArcGIS 9.0 software and its extensions were used as the GIS tool since it is able to perform suitability analysis using MCE analysis. To identify appropriate landfill areas in the Cumra district, eight input map layers including proximity to municipal and local wells and irrigational canals, distance from transportation routes and rails, distance from archaeological sites, distance from urban areas, land use/land cover, and land slope are used in constraint mapping. A final map was generated which identifies regions showing suitability for the location of the landfill site. According to the map, 6.8% of the study area is most suitable, 15.7% is suitable, 10.4% is moderately suitable, 25.8% is poorly suitable, and 41.3% is unsuitable. At the end of the analyses, three candidate sites are determined. The selection of the final MSW landfill site, however, requires further field research. 相似文献