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71.
Alicia Fernández Cirelli Carlos Ojeda Mariano J. L. Castro Miquel Salgot 《Environmental Chemistry Letters》2008,6(3):135-148
Surfactants are included in different detergent formulations and are one of the most ubiquitous and important families of
organic compounds. Although the generic term applies to a great number of products, 80% of their demand is covered by only
ten types of compounds. The global surfactant market volume size is more than 18 million tons per year. Large quantities of
surfactants are continuously released into the environment, where they can or cannot be degraded depending on their structure.
The alkylbenzenesulphonate (LAS) is the most widely used surfactant. LAS can be degraded under aerobic conditions but is persistent
in the environment under anaerobic conditions. Surfactants may enter the terrestrial environment through several routes, with
the use of sewage sludge as fertiliser on agricultural land being by far the most important. High concentrations of surfactants
and their degradation products may affect the biota. On the other hand, due to their amphiphilic nature, surfactants may interact
both with inorganic as well as organic contaminants affecting their bioavailability. 相似文献
72.
Michael P. Labare J. Timothy Bays Michael A. Butkus Teresa Snyder-Leiby Alicia Smith Amanda Goldstein Jenna D. Schwartz Kristopher C. Wilson Melody R. Ginter Elizabeth A. Bare Robert E. Watts Elizabeth Michealson Nicole Miller Rachel LaBranche 《Environmental science and pollution research international》2010,17(4):1009-1015
Introduction
The effect of oceanic CO2 sequestration was examined exposing a deep-sea bacterium identified as Vibrio alginolyticus (9NA) to elevated levels of carbon dioxide and monitoring its growth at 2,750 psi (1,846 m depth).Findings
The wild-type strain of 9NA could not grow in acidified marine broth below a pH of 5. The pH of marine broth did not drop below this level until at least 20.8 mM of CO2 was injected into the medium. 9NA did not grow at this CO2 concentration or higher concentrations (31.2 and 41.6 mM) for at least 72 h. Carbon dioxide at 10.4 mM also inhibited growth, but the bacterium was able to recover and grow. Exposure to CO2 caused the cell to undergo a morphological change and form a dimple-like structure. The membrane was also damaged but with no protein leakage. 相似文献73.
Sarah E. Rothenberg Lester McKee Alicia Gilbreath Donald Yee Mike Connor Xuewu Fu 《Atmospheric environment (Oxford, England : 1994)》2010,44(10):1263-1273
Atmospheric mercury (Hg) species, including gaseous elemental mercury (GEM), reactive gaseous mercury (RGM) and particulate-bound mercury (Hgp), were monitored near three sites, including a cement plant (monitored in 2007 and 2008), an urban site and a rural site (both monitored in 2005 and 2008). Although the cement plant was a significant source of Hg emissions (for 2008, GEM: 2.20 ± 1.39 ng m?3, RGM: 25.2 ± 52.8 pg m?3, Hgp 80.8 ± 283 pg m?3), average GEM levels and daytime average dry depositional RGM flux were highest at the rural site, when all three sites were monitored sequentially in 2008 (rural site, GEM: 2.37 ± 1.26 ng m?3, daytime RGM flux: 29 ± 40 ng m?2 day?1). Photochemical conversion of GEM was not the primary RGM source, as highest net RGM gains (75.9 pg m?3, 99.0 pg m?3, 149 m?3) occurred within 3.0–5.3 h, while the theoretical time required was 14–23 h. Instead, simultaneous peaks in RGM, Hgp, ozone (O3), nitrogen oxides, and sulfur dioxide in the late afternoon suggested short-range transport of RGM from the urban center to the rural site. The rural site was located more inland, where the average water vapor mixing ratio was lower compared to the other two sites (in 2008, rural: 5.6 ± 1.4 g kg?1, urban: 9.0 ± 1.1 g kg?1, cement plant: 8.3 ± 2.2 g kg?1). Together, these findings suggested short-range transport of O3 from an urban area contributed to higher RGM deposition at the rural site, while drier conditions helped sustain elevated RGM levels. Results suggested less urbanized environments may be equally or perhaps more impacted by industrial atmospheric Hg emissions, compared to the urban areas from where Hg emissions originated. 相似文献
74.
Esther Gomez-Herrero Montserrat Tobajas Alicia Polo Juan J. Rodriguez Angel F. Mohedano 《Environmental science and pollution research international》2018,25(35):34930-34937
The oxidation of imidazolium (1-hexyl-3-methylimidazolium chloride, HmimCl) and pyridinium (1-butyl-4-methylpyridinium chloride, BmpyrCl) ionic liquids (ILs) by Fenton’s reagent has been studied. Complete conversion was achieved for both ILs using the stoichiometric H2O2 dose at 70 °C, reaching final TOC conversion values around 45 and 55% for HmimCl and BmpyrCl, respectively. The decrease in hydrogen peroxide dose to substoichiometric concentrations (20–80% stoichiometric dose) caused a decrease in TOC conversion and COD removal and the appearance of hydroxylated oxidation by-products. Working at these substoichiometric H2O2 doses allowed the depiction of a possible degradation pathway for the oxidation of both imidazolium and pyridinium ILs. The first step of the oxidation process consisted in the hydroxylation of the ionic liquid by the attack of the ·OH radicals, followed by the ring-opening and the formation of short-chain organic acids, which could be partially oxidized up to CO2 and H2O. At H2O2 doses near stoichiometric values (80%), the resulting effluents showed non-ecotoxic behaviour and more biodegradable character (BOD5/COD ratio around 0.38 and 0.58 for HmimCl and BmpyrCl, respectively) due to the formation of short-chain organic acids. 相似文献
75.
Werdin González Jorge Omar Jesser Emiliano Nicolás Yeguerman Cristhian Alan Ferrero Adriana Alicia Fernández Band Beatriz 《Environmental science and pollution research international》2017,24(20):17006-17015
Environmental Science and Pollution Research - Mosquitoes (Diptera: Culicidae) are vectors of important parasites and pathogens causing death, poverty and social disability worldwide. The overuse... 相似文献
76.
Taylor Alicia A. Tsuji Joyce S. Garry Michael R. McArdle Margaret E. Goodfellow William L. Adams William J. Menzie Charles A. 《Environmental management》2020,65(1):131-159
Environmental Management - Decades of study indicate that copper oral exposures are typically not a human health concern. Ingesting high levels of soluble copper salts can cause acute... 相似文献
77.
Alicia Aguado L. Martínez L. Becerra M. Arieta-araunabeña S. Arnaiz A. Asueta I. Robertson 《Journal of Material Cycles and Waste Management》2014,16(2):201-210
The huge increase in the generation of post-consumer plastic waste has produced a growing interest in eco-efficient strategies and technologies for their appropriate management and recycling. In response to this, PROQUIPOL Project is focused on developing, optimizing and adapting feedstock recycling technologies as an alternative for management for the treatment of complex plastic waste. Among the different plastic wastes studied, PROQUIPOL Project is working on providing a suitable treatment to the highly colored and complex multilayered post-consumer waste fractions of polyethylene terephthalate (PET) by chemical depolymerisation methods. Glycolysis and alkali hydrolysis processes have been studied with the aim of promoting the transformation of PET into the bis(2-hydroxyethyl) terephthalate monomer and terephthalic acid, respectively. In both cases operational conditions such as temperature, reaction time, catalyst to PET rate and solvent to PET rate have been considered to optimize product yield, achieving values near to 90 % and monomer purities over 95 % in both processes. This paper presents results obtained for each treatment as well as a simplified comparison of technical, economic and environmental issues. 相似文献
78.
Assessing Satellite and Ground‐Based Potential Evapotranspiration for Hydrologic Applications in the Colorado River Basin 下载免费PDF全文
Muhammad G. Barik Terri S. Hogue Kristie J. Franz Alicia M. Kinoshita 《Journal of the American Water Resources Association》2016,52(1):48-66
This study evaluates a remotely sensed and two ground‐based potential evapotranspiration (PET) products for hydrologic application in the Upper Colorado River Basin (UCRB). The remotely sensed Moderate Resolution Imaging Spectroradiometer product (MODIS‐PET) is a continuous, daily time series with 250 m resolution derived using the Priestley‐Taylor (P‐T) equation. The MODIS‐PET is evaluated against regional flux tower data as well as a synthetic pan product (Epan; 0.125°, daily) derived from the North American Land Data Assimilation System (NLDAS) and a Hargreaves PET derived from DAYMET variables (DAYMET‐PET; 1 km, daily). Compared to point‐scale PET computed using regional flux tower data, the MODIS‐PET had lower errors, with RMSE values ranging from 2.24 to 2.85 mm/day. Epan RMSE values ranged from 3.70 to 3.76 mm/day and DAYMET‐PET RMSE values ranged from 3.55 to 4.58 mm/day. Further investigation showed biases in temperature and radiation data contribute to uncertainty in the MODIS‐PET values, while bias in NLDAS temperature, downward shortwave (SW↓), and downward longwave (LW↓) propagate in the Epan estimates. Larger discrepancies between methods were observed in the warmer, drier regions of the UCRB, however, the MODIS‐PET was more responsive to landcover transitions and better captured basin heterogeneity. Results indicate the satellite‐based MODIS product can serve as a viable option for obtaining spatial PET values across the UCRB. 相似文献
79.
80.
Mansour AA Motte A Pallier V Feuillade-Cathalifaud G Ponthieux A 《Waste management (New York, N.Y.)》2012,32(10):1864-1872
This work focuses on assessing the impact of two types of waste pretreatment: addition of bottom ashes and aerobic pretreatment on both the onset and kinetics of methanogenesis and the evolution of different parameters in the leachate. It also studies the correlation between methane production and the different parameters measured in the leachate produced. A total of six 68-L pilots were thus used with fresh municipal solid waste (MSW) shredded to a 40-mm size. After 14months of landfilling, the control has produced less than 10NLkg(-1)DM, which corresponds to around 7% of its biochemical methane potential (BMP). Nevertheless, on one hand for aerobically pretreated waste, the lag phase before the onset of methanogenesis is significantly reduced to 0.9month compared to more than 1year for the control. In addition to that, on average 110NLkg(-1)DM (90% of the BMP) is produced within around 6.5months. On the other hand, the waste with added bottom ash shows a slight improvement of the lag phase over the control for one of the duplicate: 6.1months of lag phase. At this stage, on average of 26NLkg(-1)DM waste are detected (22% of the BMP) no final conclusion concerning the impact of bottom ashes could be made. The data obtained for the leachate parameters agrees with the observations on methane production. Statistical correlation study shows that the two components of the corrected PCA interpret 76% of the variability of the data: SUVA (specific UV absorbance at 254nm) and HPI(*) (% of hydrophilic compounds) are identified as interesting parameters for following up the biodegradation in landfill conditions. 相似文献