Evidence for short-range transport of atmospheric mercury to a rural,inland site

Atmospheric mercury (Hg) species, including gaseous elemental mercury (GEM), reactive gaseous mercury (RGM) and particulate-bound mercury (Hg_p), were monitored near three sites, including a cement plant (monitored in 2007 and 2008), an urban site and a rural site (both monitored in 2005 and 2008). Although the cement plant was a significant source of Hg emissions (for 2008, GEM: 2.20 ± 1.39 ng m^?3, RGM: 25.2 ± 52.8 pg m^?3, Hg_p 80.8 ± 283 pg m^?3), average GEM levels and daytime average dry depositional RGM flux were highest at the rural site, when all three sites were monitored sequentially in 2008 (rural site, GEM: 2.37 ± 1.26 ng m^?3, daytime RGM flux: 29 ± 40 ng m^?2 day^?1). Photochemical conversion of GEM was not the primary RGM source, as highest net RGM gains (75.9 pg m^?3, 99.0 pg m^?3, 149 m^?3) occurred within 3.0–5.3 h, while the theoretical time required was 14–23 h. Instead, simultaneous peaks in RGM, Hg_p, ozone (O₃), nitrogen oxides, and sulfur dioxide in the late afternoon suggested short-range transport of RGM from the urban center to the rural site. The rural site was located more inland, where the average water vapor mixing ratio was lower compared to the other two sites (in 2008, rural: 5.6 ± 1.4 g kg^?1, urban: 9.0 ± 1.1 g kg^?1, cement plant: 8.3 ± 2.2 g kg^?1). Together, these findings suggested short-range transport of O₃ from an urban area contributed to higher RGM deposition at the rural site, while drier conditions helped sustain elevated RGM levels. Results suggested less urbanized environments may be equally or perhaps more impacted by industrial atmospheric Hg emissions, compared to the urban areas from where Hg emissions originated.     

Removal of imidazolium- and pyridinium-based ionic liquids by Fenton oxidation

The oxidation of imidazolium (1-hexyl-3-methylimidazolium chloride, HmimCl) and pyridinium (1-butyl-4-methylpyridinium chloride, BmpyrCl) ionic liquids (ILs) by Fenton’s reagent has been studied. Complete conversion was achieved for both ILs using the stoichiometric H₂O₂ dose at 70 °C, reaching final TOC conversion values around 45 and 55% for HmimCl and BmpyrCl, respectively. The decrease in hydrogen peroxide dose to substoichiometric concentrations (20–80% stoichiometric dose) caused a decrease in TOC conversion and COD removal and the appearance of hydroxylated oxidation by-products. Working at these substoichiometric H₂O₂ doses allowed the depiction of a possible degradation pathway for the oxidation of both imidazolium and pyridinium ILs. The first step of the oxidation process consisted in the hydroxylation of the ionic liquid by the attack of the ·OH radicals, followed by the ring-opening and the formation of short-chain organic acids, which could be partially oxidized up to CO₂ and H₂O. At H₂O₂ doses near stoichiometric values (80%), the resulting effluents showed non-ecotoxic behaviour and more biodegradable character (BOD₅/COD ratio around 0.38 and 0.58 for HmimCl and BmpyrCl, respectively) due to the formation of short-chain organic acids.

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Polymer nanoparticles containing essential oils: new options for mosquito control

Environmental Science and Pollution Research - Mosquitoes (Diptera: Culicidae) are vectors of important parasites and pathogens causing death, poverty and social disability worldwide. The overuse...     

Assessing Satellite and Ground‐Based Potential Evapotranspiration for Hydrologic Applications in the Colorado River Basin

This study evaluates a remotely sensed and two ground‐based potential evapotranspiration (PET) products for hydrologic application in the Upper Colorado River Basin (UCRB). The remotely sensed Moderate Resolution Imaging Spectroradiometer product (MODIS‐PET) is a continuous, daily time series with 250 m resolution derived using the Priestley‐Taylor (P‐T) equation. The MODIS‐PET is evaluated against regional flux tower data as well as a synthetic pan product (Epan; 0.125°, daily) derived from the North American Land Data Assimilation System (NLDAS) and a Hargreaves PET derived from DAYMET variables (DAYMET‐PET; 1 km, daily). Compared to point‐scale PET computed using regional flux tower data, the MODIS‐PET had lower errors, with RMSE values ranging from 2.24 to 2.85 mm/day. Epan RMSE values ranged from 3.70 to 3.76 mm/day and DAYMET‐PET RMSE values ranged from 3.55 to 4.58 mm/day. Further investigation showed biases in temperature and radiation data contribute to uncertainty in the MODIS‐PET values, while bias in NLDAS temperature, downward shortwave (SW↓), and downward longwave (LW↓) propagate in the Epan estimates. Larger discrepancies between methods were observed in the warmer, drier regions of the UCRB, however, the MODIS‐PET was more responsive to landcover transitions and better captured basin heterogeneity. Results indicate the satellite‐based MODIS product can serve as a viable option for obtaining spatial PET values across the UCRB.     

Critical Review of Exposure and Effects: Implications for Setting Regulatory Health Criteria for Ingested Copper

Environmental Management - Decades of study indicate that copper oral exposures are typically not a human health concern. Ingesting high levels of soluble copper salts can cause acute...     

Hydrologic Resilience from Summertime Fog and Recharge: A Case Study for Coho Salmon Recovery Planning

Fog and low cloud cover (FLCC) and late summer recharge increase stream baseflow and decrease stream temperature during arid Mediterranean climate summers, which benefits salmon especially under climate warming conditions. The potential to discharge cool water to streams during the late summer (hydrologic capacity; HC) furnished by FLCC and recharge were mapped for the 299 subwatersheds ranked Core, Phase 1, or Phase 2 under the National Marine Fisheries Service Recovery Plan that prioritized restoration and threat abatement action for endangered Central California Coast Coho Salmon evolutionarily significant unit. Two spatially continuous gridded datasets were merged to compare HC: average hrs/day FLCC, a new dataset derived from a decade of hourly National Weather Satellite data, and annual average mm recharge from the USGS Basin Characterization Model. Two use‐case scenarios provide examples of incorporating FLCC‐driven HC indices into long‐term recovery planning. The first, a thermal analysis under future climate, projected 65% of the watershed area for 8–19 coho population units as thermally inhospitable under two global climate models and identified several units with high resilience (high HC under the range of projected warming conditions). The second use case investigated HC by subwatershed rank and coho population, and identified three population units with high HC in areas ranked Phase 1 and 2 and low HC in Core. Recovery planning for cold‐water fish species would benefit by including FLCC in vulnerability analyses.     

Polycyclic aromatic hydrocarbon concentrations,mutagenicity, and Microtox® acute toxicity testing of Peruvian crude oil and oil-contaminated water and sediment

The oil industry is a major source of contamination in Peru, and wastewater and sediments containing oil include harmful substances that may have acute and chronic effects. This study determined polycyclic aromatic hydrocarbon (PAH) concentrations by GC/MS, mutagenicity using TA98 and TA100 bacterial strains with and without metabolic activation in the Muta-ChromoPlate? test, and Microtox® 5-min EC₅₀ values of Peruvian crude oil, and water and sediment pore water from the vicinity of San José de Saramuro on the Marañón River and Villa Trompeteros on the Corrientes River in Loreto, Peru. The highest total PAH concentration in both areas was found in water (Saramuro?=?210.15 μg/ml, Trompeteros?=?204.66 μg/ml). Total PAH concentrations in water from San José de Saramuro ranged from 9.90 to 210.15 μg/ml (mean?=?66.48 μg/ml), while sediment pore water concentrations ranged from 2.19 to 70.41 μg/ml (mean?=?24.33 μg/ml). All water samples tested from Saramuro and Trompeteros sites, and one out of four sediment pore water samples from Trompeteros, were found to be mutagenic (P?<?0.001). One sediment pore water sample in Saramuro was determined to have a measurable toxicity (Microtox EC₅₀?=?335.1 mg/l), and in Trompeteros, the EC₅₀ in water and sediment pore water ranged from 25.67 to 133.86 mg/l. Peruvian crude oil was mutagenic using the TA98 strain with metabolic activation, and the EC₅₀ was 17.18 mg/l. The two areas sampled had very high PAH concentrations that were most likely associated with oil activities, but did not lead to acute toxic effects. However, since most of the samples were mutagenic, it is thought that there is a greater potential for chronic effects.     

Per- and polyfluoroalkyl substances and obesity,type 2 diabetes and non-alcoholic fatty liver disease: a review of epidemiologic findings

Abstract

Per- and polyfluoroalkyl substances, a group of fluoro-surfactants widely detected in the environment, wildlife, and humans, have been linked to adverse health effects. A growing body of literature has addressed their effects on obesity, diabetes and non-alcoholic fatty liver disease/non-alcoholic steatohepatitis. This review summarizes the brief historical use and chemistry of per- and polyfluoroalkyl substances, routes of human exposure, as well as the epidemiologic evidence for associations between exposure to per- and polyfluoroalkyl substances and the development of obesity, diabetes and non-alcoholic fatty liver disease/non-alcoholic steatohepatitis. We identified 22 studies on obesity and 32 studies on diabetes, while only 1 study was found for non-alcoholic fatty liver disease/non-alcoholic steatohepatitis by searching PubMed for human studies. Approximately two-third of studies reported positive associations between per- and polyfluoroalkyl substances exposure and the prevalence of obesity and/or type 2 diabetes. Causal links between per- and polyfluoroalkyl substances and obesity, diabetes and non-alcoholic fatty liver disease/non-alcoholic steatohepatitis, however, require further large-scale prospective cohort studies combined with mechanistic laboratory studies to better assess these associations.     

Chemical depolymerisation of PET complex waste: hydrolysis vs. glycolysis

The huge increase in the generation of post-consumer plastic waste has produced a growing interest in eco-efficient strategies and technologies for their appropriate management and recycling. In response to this, PROQUIPOL Project is focused on developing, optimizing and adapting feedstock recycling technologies as an alternative for management for the treatment of complex plastic waste. Among the different plastic wastes studied, PROQUIPOL Project is working on providing a suitable treatment to the highly colored and complex multilayered post-consumer waste fractions of polyethylene terephthalate (PET) by chemical depolymerisation methods. Glycolysis and alkali hydrolysis processes have been studied with the aim of promoting the transformation of PET into the bis(2-hydroxyethyl) terephthalate monomer and terephthalic acid, respectively. In both cases operational conditions such as temperature, reaction time, catalyst to PET rate and solvent to PET rate have been considered to optimize product yield, achieving values near to 90 % and monomer purities over 95 % in both processes. This paper presents results obtained for each treatment as well as a simplified comparison of technical, economic and environmental issues.     

Biochemical and genotoxic effects in women exposed to pesticides in Southern Ecuador

Environmental Science and Pollution Research - Toxicity refers to the potential of a substance such as a pesticide to cause damage to the structure or functions of an exposed organism. Pesticides...