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201.
Occupational exposure of farm workers to pesticides: biochemical parameters and evaluation of genotoxicity 总被引:2,自引:0,他引:2
Remor AP Totti CC Moreira DA Dutra GP Heuser VD Boeira JM 《Environment international》2009,35(2):273-278
To assess the effects of exposure to complex mixtures of pesticides in farm workers from two communities from Rio Grande do Sul, Brazil, we evaluated the activities of butyrylcholinesterase (BChE) and delta-aminolevulinic acid dehydratase (ALA-D) enzymes, hematological, lipid parameters, and genotoxicity using two tests to detect DNA damage, the Comet assay in peripheral blood leukocytes and the micronucleus (MN) test in oral mucosa cells. The use of personal protective equipment (PPE), age and smoke habits were considered in the analysis. There was a significant decrease in the BChE and ALA-D activities in farm workers (n=37) relative to the control group (n=20) (P< or =0.05 and P< or =0.001, respectively). The Comet assay in peripheral blood leukocytes showed that the Damage index and Damage frequency observed in the exposed group were significantly higher in relation to the controls (P< or =0.001, and P< or =0.05, respectively). No differences were detected regarding the hematological parameters, lipids profile, and MN frequencies. In addition, no significant differences were observed between younger (< or =38 years) and older subjects (>38 years), or between smokers and non-smokers within the groups, either by Comet assay or MN test. However, the use of PPE seems to be important in the prevention of contamination, as suggested by BChE levels and Comet assay results. 相似文献
202.
Defining Chlorophyll-a Reference Conditions in European Lakes 总被引:2,自引:0,他引:2
Sandra Poikāne Maria Helena Alves Christine Argillier Marcel van den Berg Fabio Buzzi Eberhard Hoehn Caridad de Hoyos Ivan Karottki Christophe Laplace-Treyture Anne Lyche Solheim José Ortiz-Casas Ingmar Ott Geoff Phillips Ansa Pilke João Pádua Spela Remec-Rekar Ursula Riedmüller Jochen Schaumburg Maria Luisa Serrano Hanna Soszka Deirdre Tierney Gorazd Urbanič Georg Wolfram 《Environmental management》2010,45(6):1286-1298
The concept of “reference conditions” describes the benchmark against which current conditions are compared when assessing the status of water bodies. In this paper we focus on the establishment of reference conditions for European lakes according to a phytoplankton biomass indicator—the concentration of chlorophyll-a. A mostly spatial approach (selection of existing lakes with no or minor human impact) was used to set the reference conditions for chlorophyll-a values, supplemented by historical data, paleolimnological investigations and modelling. The work resulted in definition of reference conditions and the boundary between “high” and “good” status for 15 main lake types and five ecoregions of Europe: Alpine, Atlantic, Central/Baltic, Mediterranean, and Northern. Additionally, empirical models were developed for estimating site-specific reference chlorophyll-a concentrations from a set of potential predictor variables. The results were recently formulated into the EU legislation, marking the first attempt in international water policy to move from chemical quality standards to ecological quality targets. 相似文献
203.
C.A. Alves C. Gonçalves M. Evtyugina C.A. Pio F. Mirante H. Puxbaum 《Atmospheric environment (Oxford, England : 1994)》2010,44(23):2750-2759
Fine (PM2.5) and coarse (PM2.5–10) smoke particles from controlled biomass burnings of a shrub-dominated forest in Lousã Mountain, Portugal, enabled the quantification by chromatographic techniques of several molecular tracers for the combustion of Mediterranean forest ecosystems, which could be conducive to source apportionment studies. The major organic components in the smoke samples were pyrolysates of vegetation cuticles, mainly comprising steradienes and sterol derivatives, carbohydrates from the breakdown of cellulose, aliphatic lipids from vegetation waxes and methoxyphenols from the lignin thermal degradation. Most of these compounds are chiefly found in fine particles. Polycyclic aromatic hydrocarbons (PAH) were also present as minor constituents. Anhydrosugar and PAH molecular diagnostic ratios were applied as source assignment tools. Some biomarkers are reported for the first time in biomass burning smoke. 相似文献
204.
Needles of three pine species (Pinus halepensis, Pinus pinea and Pinus nigra) were analysed to assess the occurrence of polycyclic aromatic hydrocarbons (PAHs) in 34 sites located throughout the Ebro
River, in Northeast Spain. Overall, the concentration varied between 55 and 808 ng g − 1 (dry weight). The three- and four-ring PAHs were the most representative, with phenanthrene having 43% of the total PAH load
and naphthalene showing a high incidence in rural areas. Despite matrix apparent similarities, P. halepensis needles revealed higher entrapment levels than P. nigra and P. pinea, the latter showing the lowest levels. The assessment of possible sources using PAH ratios (phenanthrene/anthracene and fluoranthene/pyrene)
did not reveal a clear tendency regarding the distinction of petrogenic and pyrogenic sources in general, reflecting heterogeneous
sources of PAHs in the Ebro area. 相似文献
205.
Water quality of the Ribeirão Preto Stream, a watercourse under anthropogenic influence in the southeast of Brazil 总被引:1,自引:0,他引:1
Renato I. da Silva Alves Osmar de Oliveira Cardoso Karina A. de Abreu Tonani Fabiana C. Julião Tânia M. B. Trevilato Susana I. Segura-Muñoz 《Environmental monitoring and assessment》2013,185(2):1151-1161
It is known that Brazil still has a privileged position of water quantity and quality, but water use has not proceeded in a responsible manner and often results in impairment of quality. This study aims to evaluate limnological parameters, parasites and bacteria, and concentrations of heavy metals (Cd, Pb, Cu, Cr, Mn, Hg, and Zn) in surface water of Ribeirão Preto Stream. The Ribeirão Preto Stream is located in urban areas under anthropogenic influence. The results showed that the levels of dissolved oxygen values were lower than those established by the National Environmental Council (CONAMA Resolution No 357/2005). The reading of electrical conductivity showed values typical of impacted environments. The parasitological analysis revealed the presence of nematode larvae. The bacteriological analysis showed higher values for total coliform and Escherichia coli than those set by the Brazilian National Environment Council (CONAMA). The heavy metals Cd, Pb, Cu, Cr, Mn, Hg, and Zn showed concentrations in accordance with the guidelines established by CONAMA. The results provide data on the quality of these waters and showed the necessity to protect the watercourse from point sources of contamination, recommending their continued monitoring. 相似文献
206.
Mobility and ecological risk assessment of trace metals in polluted estuarine sediments using a sequential extraction scheme 总被引:2,自引:0,他引:2
F. A. B. Canuto C. A. B. Garcia J. P. H. Alves E. A. Passos 《Environmental monitoring and assessment》2013,185(7):6173-6185
The three-stage sequential extraction procedure for the fractionation of Cd, Cr, Cu, Ni, Pb, and Zn, proposed by the Commission of the European Communities Bureau of Reference, was applied to sediment five samples collected from the Sal estuary, Sergipe State, northeast Brazil, in September 2009. The method showed satisfactory recoveries, detection limits, and standard deviations for determinations of trace metals in the sediments. Cd and Pb were the metals most prevalent in the bioavailable fractions (carbonates, Fe and Mn oxides, organic matter, and sulfides), while Ni, Zn, Cu, and Cr showed higher percentages in the inert fraction. The order of mobility of the metals was Cd (66 %) > Pb (65 %) > Zn (59 %) > Ni (57 %) = Cr (57 %) > Cu (56 %). Possible toxicity related to these metals was examined using the risk assessment code, and by comparing the chemical data with sediment quality guideline ERL-ERM values. Results obtained using the two methods were in agreement, and showed low to medium risk for all metals, indicating that adverse effects on aquatic biota should rarely occur. 相似文献
207.
Influence of composition on the biomethanation potential of restaurant waste at mesophilic temperatures 总被引:2,自引:0,他引:2
A synthetic waste was used to study the effect of waste composition on anaerobic degradation of restaurant waste. It was made by blending melted pork lard, white cabbage, chicken breast, and potato flakes, to simulate lipids, cellulose, protein, and carbohydrates, respectively. Four blends of the four constituents with an excess of each component were assayed and compared with a fifth blend containing an equal amount of chemical oxygen demand (COD) of each of the four components. The methane production and the time course of soluble COD and volatile fatty acids were assessed in batch assays. A high reduction of volatile solids (between 94% and 99.6%) was obtained in all the assays. The methane yield was between 0.40 m(3) CH(4)/kg VS(initial) (excess of carbohydrates) and 0.49 m(3) CH(4)/kg VS(initial) (excess of lipids). The degradation of the lipid-rich assays differed from the others. Fifty percent of the biochemical methane potential was obtained after 3-6 days for all of the assays, except for the one with excess of lipids which achieved 50% methanation only after 14.7 days of incubation. In the assay with excess of lipids, a considerable fraction of COD remained in the liquid phase, suggesting an inhibition of the methanogenic process that was likely due to the accumulation of long chain fatty acids. The hydrolysis rate constants, assuming first order kinetics, over the first 6 days were between 0.12d(-1) (excess of lipids) and 0.32 d(-1) (excess of carbohydrates). The results indicate that anaerobic digestion facilities with large variations in lipid input could have significant changes in process performance that merit further examination. 相似文献
208.
Corrêa Furtini Ana Carolina Silva Brito Flávia Maria Guimarães Junior Mario Anteveli Osajima Furtini Josy de Matos Alves Pinto Luciana de Paula Protásio Thiago Mendes Lourival Marin Guimarães Junior José Benedito 《Environmental science and pollution research international》2022,29(44):66562-66577
Environmental Science and Pollution Research - In recent years, research has been conducted in search of alternative adhesives that are less harmful to human health and the environment. Cardanol... 相似文献