Untersuchungen über die Aufnahme organischer Substanzen durch die Wurzeln höherer Pflanzen. III. Alkaloide

The Science of Nature -     

A simple voltammetric procedure for speciation and evaluation of As removal from water

Here, we show a fast and sensitive method for the determination of inorganic arsenic in natural waters using differential pulse cathodic stripping voltammetry. All the arsenite determinations were done in 2.0 mol L⁻¹ HCl + 3.15 × 10⁻⁴ mol L⁻¹ Cu(II) supporting electrolyte. 1 × 10⁻³ mol L⁻¹ sodium thiosulphate was used as As(V) reducing agent. The detection limit was 0.5 μg L⁻¹ for both species. The method has been applied to water samples collected in an arsenic-contaminated region of Brazil, in particular, to verify the efficiency of the solar oxidation and removal of arsenic process applied to these waters.     

Industrial age anthropogenic inputs of heavy metals into the pedosphere

Heavy metals have been increasingly released into our environment. We present here, for the first time, the global industrial age production of Cd, Cu, Cr, Hg, Ni, Pb, and Zn, and their potential accumulation and environmental effects in the pedosphere. World soils have been seriously polluted by Pb and Cd and slightly by Zn. The potential industrial age anthropogenic Pb, Hg, and Cd inputs in the pedosphere are 9.6, 6.1, and 5.2 times those in the lithosphere, respectively. The potential anthropogenic heavy metal inputs in the pedosphere increased tremendously after the 1950s, especially for Cr and Ni. In 2000, the cumulative industrial age anthropogenic global production of Cd, Cr, Cu, Hg, Ni, Pb, and Zn was 1.1, 105, 451, 0.64, 36, 235, and 354 million tonnes, respectively. The global industrial age metal burdens per capita (in 2000) were 0.18, 17.3, 74.2, 0.10, 5.9, 38.6, and 58.2 kg for Cd, Cr, Cu, Hg, Ni, Pb, and Zn, respectively. Acidification may increase the bioavailability and toxicity of heavy metals in the pedosphere. The improvement of industrial processing technology reducing the metal dispersion rate, the recycling of metal-containing outdated products, by-products and wastes, and the development of new substitute materials for heavy metals are possible strategies to minimize the effects of heavy metals on our environment.     

Temperate reefs in a changing ocean: skeletal carbonate mineralogy of serpulids

We present a review of the published data about serpulid skeletal carbonate geochemistry, augmented with new data from the Southern Hemisphere. We know something about skeletal carbonate mineralogy of 15 % of extant species (n = 52); and about half of extant genera (n = 25). Serpulid worm tubes vary in their skeletal mineralogy from entirely aragonitic (about 24 % of species) to entirely high-Mg calcite (40 %) to mixtures of the two. Mg in calcite ranges from 7 to 15 wt% MgCO₃, with a mean of 11 wt% MgCO₃. Little mineralogical variation within individuals or species can be found in aragonitic specimens, whereas high-Mg calcitic species show somewhat more variability in both calcite and Mg content, and those with mixed mineralogies are highly variable. These three groups correspond broadly with currently accepted clades. Given this strong phylogenetic signal, we analysed the data using phylogenetically independent contrasts, a statistical approach that separates genotypic from phenotypic variability; we found that variations which might be ascribed to environment were generally weak. The mineralogy of serpulid tubes makes them particularly vulnerable to ocean chemistry changes. While some serpulids appear to be able to adjust their tube mineralogy in order to adapt to sea-water chemistry, overall strength and elasticity may be sacrificed when they do. The biodiverse reef habitat provided by serpulids in some temperate regions may be the only complex solid habitat available, and loss or compromise of these temperate reefs will most likely have deleterious flow-on effects on temperate benthic communities.     

Impacts of golf courses on macroinvertebrate community structure in Precambrian shield streams

The influence of golf course operation on benthic macroinvertebrate communities in Precambrian Shield streams was evaluated using rapid bioassessment and the reference condition approach. Streams were sampled for water chemistry and invertebrates in 1999 and 2000, six on operational golf courses, and seven in forested reference locations. Correspondence analysis (CA) was used to determine the major patterns in the macroinvertebrate taxa, and canonical correspondence analysis (CCA) was used to evaluate relationships with environmental variables. The reference streams were used to define the normal range of variation for a variety of summary indices to evaluate the golf course streams. In all cases, golf course streams were higher in nutrients and dissolved ions and more alkaline than the forested reference streams. There was considerable variability in the macroinvertebrate fauna from the golf course streams, which was related to differences in golf course land management practices and to the potential influence of highway runoff. Of the management practices evaluated, fertilizer application rates in particular were important, as was the presence of ponds upstream on the course. Invertebrate taxa with higher abundances in golf course streams included Turbellaria, Isopoda, Amphipoda, Zygoptera, and Trombidiformes. Taxa more common in the reference streams included Ephemeroptera, Megaloptera, Culicidae, and Plecoptera. There were marked differences in the overall benthic macroinvertebrate community in three of the six golf course streams studied relative to the forested reference streams, suggesting that golf course land management on the Precambrian Shield can be associated with significant differences in macroinvertebrate community structure.     

The town and country planning act 1947

The 1947 Town & Country Planning Act is regarded as the statutory foundation of physical planning in post‐war Britain. This paper looks at the Act in context and assesses its effectiveness from the vantage point of forty years since its implementation.     

Delineation and evaluation of hydrologic-landscape regions in the United States using geographic information system tools and multivariate statistical analyses

Hydrologic-landscape regions in the United States were delineated by using geographic information system (GIS) tools combined with principal components and cluster analyses. The GIS and statistical analyses were applied to land-surface form, geologic texture (permeability of the soil and bedrock), and climate variables that describe the physical and climatic setting of 43,931 small (approximately 200 km2) watersheds in the United States. (The term "watersheds" is defined in this paper as the drainage areas of tributary streams, headwater streams, and stream segments lying between two confluences.) The analyses grouped the watersheds into 20 noncontiguous regions based on similarities in land-surface form, geologic texture, and climate characteristics. The percentage of explained variance (R-squared value) in an analysis of variance was used to compare the hydrologic-landscape regions to 19 square geometric regions and the 21 U.S. Environmental Protection Agency level-II ecoregions. Hydrologic-landscape regions generally were better than ecoregions at delineating regions of distinct land-surface form and geologic texture. Hydrologic-landscape regions and ecoregions were equally effective at defining regions in terms of climate, land cover, and water-quality characteristics. For about half of the landscape, climate, and water-quality characteristics, the R-squared values of square geometric regions were as high as hydrologic-landscape regions or ecoregions.     

Coccolithophores: a major phytoplankton component in mature upwelled waters off the Cape Peninsula,South Africa in March, 1983

Coccolithophores, together with other phytoplankton, were sampled at ten stations along a transect following the general orientation of the Cape Peninsula upwelling plume in March, 1983. Thirteen coccolithophore species were identified with Emiliania huxleyi dominating the assemblages. Coccolithophores and other microflagellates were more abundant than diatoms along the transect except at one station in mature upwelled water. Very high populations (2 340×10³ cells l^-1) of coccolithophores were found in mature upwelled water adjacent to the oceanic front. This count is one of the highest counts ever recorded in an upwelling area. The anomalous warm event prior to sampling may have had a residual effect on seeding, contributing towards the predominance of small-celled phytoplankton over chain-forming diatoms.     

Gender differences in the perception of organizational influence tactics

A short incident describing a political influence attempt was given to 152 management level and professional employees. Subjects were then asked to complete short attitude scales pertaining to the characteristics of the actor and the incident. The experimental factorial design included three factors (1) sex of subject, (2) sex of influencing party, (3) sex of target of influence. The results suggest that males are more tolerant of political behavior than women. Subjects view political manipulators of their own sex more favorably than manipulators of the opposite sex. Subjects of both sexes are more tolerant of political behavior when the victim of the behavior is a member of the opposite sex rather than of their own sex. The results may suggest a growing inclination on the part of both genders to identify with members of their own sex as a meaningful coalition and react to organizational events in view of the implications to members of their own gender. Possible implications for research and intervention are suggested.