全文获取类型
收费全文 | 626篇 |
免费 | 32篇 |
国内免费 | 251篇 |
专业分类
安全科学 | 39篇 |
废物处理 | 34篇 |
环保管理 | 59篇 |
综合类 | 342篇 |
基础理论 | 130篇 |
污染及防治 | 189篇 |
评价与监测 | 41篇 |
社会与环境 | 41篇 |
灾害及防治 | 34篇 |
出版年
2023年 | 9篇 |
2022年 | 33篇 |
2021年 | 27篇 |
2020年 | 21篇 |
2019年 | 24篇 |
2018年 | 31篇 |
2017年 | 36篇 |
2016年 | 29篇 |
2015年 | 36篇 |
2014年 | 30篇 |
2013年 | 54篇 |
2012年 | 50篇 |
2011年 | 56篇 |
2010年 | 52篇 |
2009年 | 37篇 |
2008年 | 42篇 |
2007年 | 45篇 |
2006年 | 41篇 |
2005年 | 23篇 |
2004年 | 23篇 |
2003年 | 22篇 |
2002年 | 32篇 |
2001年 | 29篇 |
2000年 | 31篇 |
1999年 | 11篇 |
1998年 | 16篇 |
1997年 | 9篇 |
1996年 | 10篇 |
1995年 | 9篇 |
1994年 | 13篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 9篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有909条查询结果,搜索用时 453 毫秒
271.
272.
Humans have transformed much of Earth’s land surface, giving rise to loss of biodiversity, climate change, and a host of other environmental issues that are affecting human and biophysical systems in unexpected ways. To confront these problems, environmental managers must consider human and landscape systems in integrated ways. This means making use of data obtained from a broad range of methods (e.g., sensors, surveys), while taking into account new findings from the social and biophysical science literatures. New integrative methods (including data fusion, simulation modeling, and participatory approaches) have emerged in recent years to address these challenges, and to allow analysts to provide information that links qualitative and quantitative elements for policymakers. This paper brings attention to these emergent tools while providing an overview of the tools currently in use for analysis of human–landscape interactions. Analysts are now faced with a staggering array of approaches in the human–landscape literature—in an attempt to bring increased clarity to the field, we identify the relative strengths of each tool, and provide guidance to analysts on the areas to which each tool is best applied. We discuss four broad categories of tools: statistical methods (including survival analysis, multi-level modeling, and Bayesian approaches), GIS and spatial analysis methods, simulation approaches (including cellular automata, agent-based modeling, and participatory modeling), and mixed-method techniques (such as alternative futures modeling and integrated assessment). For each tool, we offer an example from the literature of its application in human–landscape research. Among these tools, participatory approaches are gaining prominence for analysts to make the broadest possible array of information available to researchers, environmental managers, and policymakers. Further development of new approaches of data fusion and integration across sites or disciplines pose an important challenge for future work in integrating human and landscape components. 相似文献
273.
探索鄱阳湖血吸虫病典型疫区的社会、经济、环境因子与血吸虫病疫情的相互关系及其相关程度。采用经典统计学中单相关、偏相关和复相关系数研究南昌县43个行政村血吸虫病感染人数与疫水接触指数、耕牛存栏数、行政村水域面积、行政村湖边边界长度和行政村到鄱阳湖边界的距离的内在联系和相互关系。所选5个因子与感染人数的简单相关系数都达到了005置信水平,固定疫水分布各因子计算疫水接触各因子与“感染人数”的偏相关系数,与固定疫水接触各因子计算疫水分布各因子与“感染人数”的偏相关系数,都小于简单相关系数,说明疫水分布因子与疫水接触因子具有内在关联;“感染人数”与所有5个因子的复相关系数为0.948,达到了0.005的极显著置信水平。所选的村级宏观因子都与血吸虫病疫情显著相关 相似文献
274.
275.
276.
Chen Yongzhi Yuan Zhongling Ma Yanhong An Fangjiao Liu Andi Liu Hong Zhao Zhichao Ma Jiao 《Environmental science and pollution research international》2021,28(46):65462-65473
Environmental Science and Pollution Research - Real domestic wastewater was treated initially in a sequencing batch reactor (SBR), with partial nitrification achieved before the effluent was used... 相似文献
277.
安飞 《安全.健康和环境》2021,21(1):13-15
为快速检测H2S泄漏,以一步水热法制备的Fe2O3纳米棒为基础,制备了H2S气体传感器。研究表明,该传感器在300℃工作温度下对10μmol/mol的H2S的灵敏度为2左右,响应时间为12s左右,恢复时间约4s。而且该传感器具有优异的稳定性和选择性,对CH4、CO等多种气体响应较差,适合用于长时间快速检测H2S气体的泄漏。 相似文献
278.
Yongpeng Ji Xingyu Chen Yuqi Xiao Yuemeng Ji Weina Zhang Jiaxin Wang Jiangyao Chen Guiying Li Taicheng An 《环境科学学报(英文版)》2021,33(7):56-63
Mineral particles are ubiquitous in the atmosphere and exhibit an important effect on the photooxidation of volatile organic compounds (VOCs). However, the role of mineral particles in the photochemical oxidation mechanism of VOCs remains unclear. Hence, the photooxidation reactions of acrolein (ARL) with OH radical (OH) in the presence and absence of SiO2 were investigated by theoretical approach. The gas-phase reaction without SiO2 has two distinct pathways (H-abstraction and OH-addition pathways), and carbonyl-H-abstraction is the dominant pathway. In the presence of SiO2, the reaction mechanism is changed, i.e., the dominant pathway from carbonyl-H-abstraction to OH-addition to carbonyl C-atom. The energy barrier of OH-addition to carbonyl C-atom deceases 21.33 kcal/mol when SiO2 is added. Carbonyl H-atom of ARL is occupied by SiO2 via hydrogen bond, and carbonyl C-atom is activated by SiO2. Hence, the main product changes from H-abstraction product to OH-adduct in the presence of SiO2. The OH-adduct exhibits a thermodynamic feasibility to yield HO2 radical and carboxylic acid via the subsequent reactions with O2, with implications for O3 formation and surface acidity of mineral particles. 相似文献
279.
Baocong Zhao Yongpeng Ji Dandan Qin Yuemeng Ji Jiangyao Chen Taicheng An 《环境科学学报(英文版)》2022,34(4):211-220
Methyl-hydroxy-cyclohexadienyl radicals (OTAs) are the key products of the photooxidation of toluene, with implications for the fate of toluene. Hence, we investigated the photooxidation mechanisms and kinetics of three main OTAs (o-OTA, m-OTA, and p-OTA) with NO2 using quantum chemical calculations as well as the fate of OTAs under the different concentration ratios of NO2 and O2. The mechanism results show that the pathway of H-abstraction by NO2 to anti-HONO (anti-H-abstraction) is more favorable than the syn-H-abstraction pathway, because the strong interaction between OTAs and NO2 is formed in the transition states of the anti-H-abstraction pathways. The branching ratios of the anti-H-abstraction pathways are more than 99% in the temperature range of 216−298 K. The total rate constant of the OTA-NO2 reaction is 9.9 × 10−12 cm3/(molecule∙sec) at 298 K, which is contributed about 90% by o-OTA + NO2, and the main products are o-cresol and anti-HONO. The half-lives of the OTA-NO2 reaction in some polluted areas of China are 35 times longer than those of the OTA-O2 reaction. In the atmosphere, the NO2- and O2- initiated reactions of OTAs have the same ability to form cresols as [NO2] is up to 142.1 ppmV, which is impossible to achieve. It implies that under the experimental condition, the [NO2]/[O2] should be controlled to be less than 7.8 × 10−5 to simulate real atmospheric oxidation of toluene. Our results reveal that for the photooxidation of toluene, the yield of cresol is not affected by the concentration of NO2 under the atmospheric environment. 相似文献
280.
Yanpeng Gao Teng Guo Xiaolin Niu Na Luo Jia Chen Junlang Qiu Yuemeng Ji Guiying Li Taicheng An 《环境科学学报(英文版)》2022,34(3):72-80
As a typical class of emerging organic contaminants(EOCs), the environmental transformation and abatement of preservative parabens have raised certain environmental concerns. However, the remediation of parabens-contaminated water using natural matrixes(such as, naturally abundant minerals) is not reported extensively in literature. In this study, the transformation kinetics and the mechanism of ethylparaben using natural sphalerite(NS) were investigated. The results show that around 63% of ethy... 相似文献