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671.
672.
Juan Peris-Vicente Ana Marzo-Mas Pasqual Roca-Genovés Samuel Carda-Broch Josep Esteve-Romero 《环境科学学报(英文版)》2016,28(4):284-292
A method based on micellar liquid chromatography has been developed to simultaneously monitor four pesticides largely post-harvest applied to citrus:thiabendazole,pyrimethanil,o-phenylphenol and imazalil.Water samples were filtered and directly injected without other treatment,thus avoiding extraction steps.The composition of the mobile phase was optimized using a chemometrical approach to achieve and excellent resolution to 0.07 mol/L SDS/5%,V/V 1-pentanol buffered at p H 3.Mobile phase run through a C18 column at 1 m L/min at room temperature.The detection was performing by UV–Visible absorbance using a wavelength program:0–10 min,305 nm(for thiabendazole);10–12;265 nm(for pyrimethanil)and 12–18,220 nm(o-phenylphenol and imazalil).The developed method was validated following the guidelines of the US Environmental Protection Agency in terms of:quantitation range,(0.5–4 to 15μg/m L),linearity(r20.9995),sensitivity(LOD,0.18–1.4μg/m L),precision(9.2%),trueness(93.9%–103.7%),and ruggedness(9.9%).It was found that the fungicides remain up to eight days in surface water at outdoor conditions.The method was used to screen the presence of the analytes in several waste water samples,and was proved to be useful in routine analysis. 相似文献
673.
Silvestre García de Jalón Ana Iglesias Andrew P. Barnes 《Mitigation and Adaptation Strategies for Global Change》2016,21(5):779-798
Over recent decades, there has been increasing levels of research dedicated to assess drivers of farm-level uptake of adaptation strategies to climate change. The main purpose of this research being to determine how policy intervention can most effectively increase adoption. This paper aims to synthesise this past research in order to scale up uptake of farm-level adaptation strategies through a composite index of potential adoption in Africa. In doing so, we review the estimated coefficients of econometric regressions in 42 case studies published in peer-review journals to identify the factors that regularly explain adoption. We find that these common factors can be grouped into seven components, that is human capital, financial resources, infrastructure and technology, social interaction and governance, food security, dependence on agriculture and attitudes towards the environment. Using national-level indicators of these seven categories, we develop a composite index to inform potential adoption and test the robustness of the index in an in-depth sensitivity analysis. The results show that the highest likelihood of adoption of farm-level adaptation strategies is in Northern African countries namely Tunisia, Egypt, Algeria and Morocco and in Southern African countries such as South Africa and Botswana. Conversely, they indicate that the lowest likelihood of adoption is situated in nations of the Sahel and Horn of Africa and in nations that have recently experienced conflict. We conclude that adoption is associated predominantly with governance, civil rights, financial resources and education. However, it is not necessarily driven by the magnitude of climate change impacts on agricultural production. 相似文献
674.
Marcelo Benetti Correa da Silva Ana Paula Graciola Gabriel Sperandio Milan Sulen Bebber Suane de Atayde Moschen Deonir De Toni 《环境质量管理》2019,28(4):75-84
Service quality in a construction technology laboratory can result in an improvement in construction companies’ competitiveness. This research aims to evaluate the service quality provided by a construction technology laboratory, specifically in the segment of performing testing through the rupturing of concrete samples. For this research, a survey was conducted using a structured questionnaire that was created based on a literature review regarding the surveying of laboratory customers at a university in the south of Brazil. Our research was both exploratory and quantitative, and the data were analyzed by applying multivariate data analysis. The conclusions of this study show that the dimensions of quality services are: communication, reliability, responsiveness, credibility, and tangibility. These five dimensions together provide a high explained variance standard of 79.75%. Having a suitable number of attendants available to serve customers and presenting agility in the construction laboratory is one of the managerial research contributions. Moreover, through information availability, this research generates greater traceability that can be used both by customers and by institutional management. Constantly and thoroughly monitoring the customer service cycle is another relevant factor that can improve the quality of the services provided. 相似文献
675.
Idalina Dias-Sardinha David Ross Ana Calapez Gomes 《Journal of Environmental Planning and Management》2018,61(4):635-655
The paper discusses conditions and format of a cluster model to support the management of a potential creative tourism destination in a setting where regional cross-sectoral collaboration is lacking. Creative tourism development requires a flexible framework and a healthy collaboration environment, more so when associated with resources shared by several stakeholders. This article focuses on the tourism potential of archaeological knowledge discovered during the environmental impact assessment of the Alqueva dam (Alentejo, Portugal). Interviews were conducted with 38 regional actors in the tourism and heritage sectors, as well as the dam developers and the companies responsible for archaeological interventions. Findings indicate that the lack of specific local policy addressing archaeological heritage hampers its potential use for tourism development, which is further aggravated by the absence of stakeholder communication and cooperation. A conceptual cluster model for the management of creative tourism destinations based on heritage resources and other local resources is proposed. 相似文献
676.
Mourad Boulaid Ana Aguilera Valentina Busonera Francisco Camacho Antonio V. Monterreal Antonio Valverde 《Journal of environmental science and health. Part. B》2013,48(7):809-815
An analytical method, using supercritical fluid extraction (SFE), was assessed for residue analysis of the insecticides fipronil, acrinathrin and pyridaben and the fungicide kresoxim-methyl in melons. Extraction conditions were optimized on glass beads, as inert material, evaluating different pressures, temperatures, and CO2 volumes. Also, the extractability of pesticides from hydromatrix and anhydrous magnesium sulfate was evaluated. Both adsorbents were evaluated for the preparation of SFE-spiked melon samples. Extractions of fortified samples were done using 20 mL of CO2, 300 atm, and 50°C. Different extraction conditions, including the addition of water and methanol as a static modifier, were used to assess the extractability of these pesticides, and the addition of methanol was demonstrated to improve the extraction of all the studied pesticides. 相似文献
677.
Ana Mendon?a Concei??o Juana Fortes Rui Capit?o Maria da Gra?a Neves Theo Moura José Sim?o Antunes do Carmo 《Journal of Coastal Conservation》2012,16(4):543-553
This paper describes an application of the Boussinesq-type COULWAVE model to study the wave hydrodynamics in the vicinity of a multi-functional artificial reef (MFAR). This reef is under investigation and consists of a supplementary protection solution for the Leirosa sand dune system located at South of Figueira da Foz, on the Portuguese West coast. Such installation near the coastline is expected to contribute to enhance the surfing conditions in the area, protect the sand dune system in the surroundings of Leirosa beach, and increase its environmental value. Numerical calculations with the COULWAVE model were performed for four test cases, considering two reef geometries (differing in the reef angle) and two incident wave conditions (storm condition and a common wave condition). Comparisons between the results obtained, in terms of wave heights and breaking line positions allow us to assess the influence of the reef on the hydrodynamics near the beach and around the reef. Moreover, the reef performance was analysed in terms of surfability and coastal protection. The surfability parameters (breaker height, Iribarren number and peel angle) were calculated for each test case using the numerical wave heights, wave directions and wave breaking positions. Comparisons of parameters allow characterizing the most appropriate configuration of the reef to improve the surfing conditions in the study area. A methodology based on numerical free surface elevations and horizontal velocity components was developed to calculate wave directions, since this is not a direct output of the COULWAVE model. Concerning coastal protection, analyses of the mean currents around the reef were used together with observations of the velocity cells near the shoreline as an indication of the sediment transport. 相似文献
678.
Hrvoje Kusic Natalija Koprivanac Ana Loncaric Bozic 《Environmental Modeling and Assessment》2012,17(6):653-671
The prediction of the system behavior is of significant interest when evaluating appropriate technologies for wastewater treatment. The robust prediction could be achieved by empirical mathematical modeling techniques, but they do not include steps in degradation of organic pollutants. Mechanistic models (MM) include chemical/physical phenomena, but may also include numerous reactions resulting with the complicated kinetic expressions with large number of parameters. This modeling approach can be challenging for complex system such as advanced oxidation processes. With the goal to reduce the number of reactions involved in developed MM, keeping the high prediction power, sensitivity, and flux analyses was employed. The results showed that MM describing the degradation of organic dye in water matrix by photooxidation processes can be significantly simplified, by reducing the number of reactions included without affecting the predictive power. The calculated root mean square deviation values between data predicted by MM and reduced MMR differ insignificantly (≤1.4 %). 相似文献
679.
680.
Nicholas J. Minter Ana B. Sendova-Franks Nigel R. Franks 《Behavioral ecology and sociobiology》2013,67(11):1745-1756
We investigated excavation and nest site choice across sediment-filled cavities in the ant Temnothorax albipennis. Colonies were presented with sediment-filled cavities, covering a spectrum from ones that should be quick to excavate but will form a weak enclosing wall to those that should be slow to excavate but form a strong wall. Overall, colonies only showed a significant preference for cavities that were fastest to excavate over those that were slowest. The speed of decision making and moving appears paramount over the suitability of the sediment for forming an enclosing wall. The mechanism behind the choice is the differential between the rates at which alternatives are excavated and accumulate ants. The rates for a particular type of cavity were unaffected by the type with which it was paired. This suggests that there is no significant competition between sites during the decision-making process. Certain colonies were able consistently to discriminate across more closely matched alternatives. These colonies required a greater number of ants to be present and took longer before beginning to move. A race is run between alternatives to become habitable but the process may be tuned across colonies such that it may run for longer and an incorrect or split decision is less likely. 相似文献