Simultaneous polarographic determination of 2-nitrophenol and 4-nitrophenol by differential pulse polarography method and support vector regression

A differential pulse polarography (DPP) for the simultaneous determination of 2-nitrophenol and 4-nitrophenol was proposed. It was found that under optimum experimental conditions (pH = 5, scan rate = 5 mV/s, pulse amplitude = −50 mV), 2-nitrophenol and 4-nitrophenol had well-defined polarographic reduction waves with peak potentials at −317 and −406 mV, respectively. In the mixture of two compounds overlapping polarographic peaks were observed. In this study, support vector regression (SVR) was applied to resolve the overlapped polarograms. Furthermore, a comparison was made between the performance of SVR and partial least square (PLS) on data set. The results demonstrated that SVR is a better well-performing alternative for the analysis and modeling of DPP data than the commonly applied PLS technique. The proposed method was used for the determination of 2-nitrophenol and 4-nitrophenol in industrial waste water.     

Assessment of drinking water quality using ICP-MS and microbiological methods in the Bholakpur area,Hyderabad, India

A total of 16 people died and over 500 people were hospitalized due to diarrhoeal illness in the Bholakpur area of Hyderabad, India on 6th May 2009. A study was conducted with immediate effect to evaluate the quality of municipal tap water of the Bholakpur locality. The study consists of the determination of physico-chemical properties, trace metals, heavy metals, rare earth elements and microbiological quality of drinking water. The data showed the variation of the investigated parameters in samples as follows: pH 7.14 to 8.72, EC 455 to 769 μS/cm, TDS 303.51 to 515.23 ppm and DO 1.01 to 6.83 mg/L which are within WHO guidelines for drinking water quality. The water samples were analyzed for 27 elements (Li, Be, B, Na, Mg, Al, Si, K, Ca, V, Cr, Mn, Fe, Ni, Co, Cu, Zn, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Ba and Pb) using inductively coupled plasma-mass spectrometry (ICP-MS). The concentrations of Fe (0.12 to 1.13 mg/L), Pb (0.01 to 0.07 mg/L), Cu (0.01 to 0.19 mg/L), Ni (0.01 to 0.15 mg/L), Al (0.16 to 0.49 mg/L), and Na (38.36 to 68.69 mg/L) were obtained, which exceed the permissible limits of the World Health Organization (WHO) for drinking water quality guidelines. The remaining elements were within the permissible limits. The microbiological quality of water was tested using standard plate count, membrane filtration technique, thermotolerant coliform (TTC), and most probable number (MPN) methods. The total heterotrophic bacteria ranged from 1.0 × 10⁵ to 18 × 10⁷ cfu/ml. Total viable bacteria in all the water samples were found to be too numerable to count and total number of coliform bacteria in all water samples were found to be of order of 1,100 to >2,400 MPN index/100 ml. TTC tested positive for coliform bacteria at 44.2°C. All the water samples of the study area exceeded the permissible counts of WHO and that (zero and minimal counts) of the control site (National Geophysical Research Institute) water samples. Excessively high colony numbers indicate that the water is highly contaminated with microorganisms and is hazardous for drinking purposes. Bacteriological pollution of drinking water supplies caused diarrhoeal illness in Bholakpur, which is due to the infiltration of contaminated water (sewage) through cross connection, leakage points, and back siphoning.     

Hepatic mercury,cadmium, and lead in mink and otter from New York State: monitoring environmental contamination

Many non-linear processes link atmospheric emissions to the bioavailability of metals; consequently, the monitoring of metals in ecosystem components is required to model their ecodynamics. American mink (Neovison vison) and river otter (Lontra canadensis) have the potential to serve as an upper-level-consumer component in monitoring metals bioavailability. However, the relationship of bioaccumulated metals to various environmental factors has not been explored nor have the effects of demographic factors been resolved. To address these limitations, mink and otter, collected throughout New York State during 1998–2002, were analyzed for hepatic concentrations of total mercury (Hg), cadmium (Cd), and lead (Pb). Relationships were investigated between metals concentrations and landscape-level factors (physiographic zone, hydrologic unit, and elevation) and demographic factors (gender and age). Considerable variation in Hg and Cd concentrations was observed relative to both physiographic zone and hydrologic unit for both species. In contrast with Hg, Cd concentration increased predictably with increasing elevation. Mercury concentrations were greater, but for Cd less, in otter than mink. Lead concentrations showed little landscape heterogeneity and were independent of elevation. Age-related bioaccumulation was evident for Hg and Cd, but not for Pb, in both species. Mercury and Cd concentrations were greater in female than male mink; however, Pb concentrations were greater in males than females. Inverse relationships of relative growth (weight/length) to metals concentrations explained gender differences in Hg and Cd in mink. For otter, no gender-related differences in metals concentrations were apparent. The suitability of mink and otter for monitoring programs is discussed.     

Bioaccumulation of trace elements in different tissues of three commonly available fish species regarding their gender,gonadosomatic index,and condition factor in a wetland ecosystem

In the present research, accumulation of Cd, Co, Cr, Cu, Mn, Ni, Pb, V, and Zn were determined in sediments and fillet, liver, kidney, gonads, and gills of three commonly fish species in the largest wetland ecosystem that is located in southwest of Iran; Shadegan wetland. Shadegan is one of the most important wetland that posses various fauna and flora but suffers inputs from agricultural and industrial activities. So, sediment samples and fish species including Barbus grypus, Barbus sharpeyi, and Cyprinus carpio were collected during winter 2009. Results showed that mean concentrations of trace elements (except Ni and Co) were high in liver and gills of B. grypus. Also trace elements had the most accumulation in liver of B. sharpeyi except for Cd (0.26 mg kg^− 1 d.w.) and Mn (13.45 mg kg^− 1 d.w.) that were high in gills. Beside, kidney is determined as target tissue for Ni and V in B. grypus and for Pb in C. carpio, due to their high concentration. Zn levels in all tissues of C. carpio showed the highest concentrations in comparison to other fish species. Generally, accumulations of most of the studied elements in B. grypus and B. sharpeyi were higher in females than in males, while in fillet and gonads of C. carpio, this trend was inverted. Bioaccumulation factors (BAFs) were determined for different tissues of fish species with respect to elemental concentrations in sediment. BAFs results indicated that Zn, Pb, and Cu have higher BAF than other elements. Also this investigation demonstrated that trace elements have different affinities with condition factor of studied fish species. Gonadosomatic index (GSI) and Pb showed positive correlation together in both B. sharpeyi and B. grypus, respectively, in females and males. Moreover, females of C. carpio showed significantly positive relation of GSI and all studied elements.     

Assessment of microcystins in lake water and fish (Mugilidae, <Emphasis Type="Italic">Liza</Emphasis> sp.) in the largest Spanish coastal lake

Cyanobacteria dominance and cyanotoxin production can become major threats to humans and aquatic life, especially in warm shallow lakes, which are often dominated by cyanobacteria. This study investigates the occurrence and distribution of microcystins (MCYST) in water, cell-bound and in the tissues of the commercial mugilid Liza sp. in the largest, coastal, Spanish Mediterranean lake (Albufera of Valencia). This is the first report concerning microcystin accumulation in tissues of mugilid fish species. Considerable amounts of microcystins were found in the water and seston, which correlated with development of Microcystis aeruginosa populations in the lake. The MCYST concentrations found in Lake Albufera (mean 1.7 and 17 μg/L and maximum 16 and 120 μg/L in water and seston, respectively) exceeded by one to two orders of magnitude the guideline levels proposed by the World Health Organization and were higher than that reported in other lakes of the Mediterranean zone. The presence of MCYST was found in all the fishes studied and accumulated differently among tissues of the commercial species Liza sp. Toxin accumulation in fish tissues showed that although the target organ for MCYST was the liver, high concentrations of microcystins were also found in other analysed tissues (liver>intestine>gills>muscle). Human tolerable daily intake for microcystins is assessed relative to the WHO guidelines, and potential toxicological risks for humans, wildlife and related ecosystems of the lake are discussed.     

Occurrence of estrogen hormones in biosolids,animal manure and mushroom compost

The presence of natural estrogen hormones as trace concentrations in the environment has been reported by many researchers and is of growing concern due to its possible adverse effects on the ecosystem. In this study, municipal biosolids, poultry manure (PM) and cow manure (CM), and spent mushroom compost (SMC) were analyzed for the presence of seven estrogen hormones. 17α-estradiol, 17β-estradiol, 17α-dihydroequilin, and estrone were detected in the sampled biosolids and manures at concentrations ranging from 6 to 462 ng/g of dry solids. 17α-estradiol, 17β-estradiol, and estrone were also detected in SMC at concentrations ranging from 4 to 28 ng/g of dry solids. Desorption experiments were simulated in the laboratory using deionized water (milli-Q), and the aqueous phase was examined for the presence of estrogen hormones to determine their desorption potential. Very low desorption of 0.4% and 0.2% estrogen hormones was observed from municipal biosolids and SMC, respectively. An estimate of total estrogen contribution from different solid waste sources is reported. Animal manures (PM and CM) contribute to a significant load of estrogen hormones in the natural environment.     

Assessing the risk posed by high-turbidity water to water supplies

The objective of this study is to assess the risk of insufficient water supply posed by high-turbidity water. Several phenomena can pose risks to the sufficiency of a water supply; this study concerns risks to water treatment plants from particular properties of rainfall and raw water turbidity. High-turbidity water can impede water treatment plant operations; rainfall properties can influence the degree of soil erosion. Thus, water turbidity relates to rainfall characteristics. Exceedance probabilities are presented for different rainfall intensities and turbidities of water. When the turbidity of raw water is higher than 5,000 NTU, it can cause operational problems for a water treatment plant. Calculations show that the turbidity of raw water at the Ban-Sin water treatment plant will be higher than 5,000 NTU if the rainfall intensity is larger than 165 mm/day. The exceedance probability of high turbidity (turbidity >5,000 NTU) in the Ban-Sin water treatment plant is larger than 10%. When any water treatment plant cannot work regularly, its ability to supply water to its customers is at risk.     

Occurrence and characterization of selected organochlorine contaminants in outdoor dust collected from Xinxiang,a fast developing city in North China

As facile “environmental media”, the outdoor dust may reflect the changes of contaminants in environment more promptly. In the present study, selected organochlorine contaminants (OCs) include hexachlorocyclohexanes (HCHs), dichlorodiphenyltrichloroethanes (DDTs), hexachlorobenzene (HCB), and pentachlorobenzene (PeCB) were detected in 20 outdoor dust samples collected from Xinxiang City. The concentrations of ΣHCHs, ΣDDTs, HCB, and PeCB in dust were in the range of 0.18–5.05 ng/g dry weight, 0.44–13.50 ng/g dry weight, 0.13–51.61 ng/g dry weight and ND-0.74 ng/g dry weight, respectively. Long-range transport, historical use, and recent impact of impure pesticides might be the main sources of OCs in the outdoor dust. The results of this study indicated that impure pesticide application maybe an important source of DDTs and HCB in the environment.     

Determination of polychlorinated biphenyls and total mercury in two fish species (<Emphasis Type="Italic">Esox lucius</Emphasis> and <Emphasis Type="Italic">Carassius auratus</Emphasis>) in Anzali Wetland,Iran

The Anzali Wetland is one of the most important ecosystems in the north of Iran, and parts of it were registered as a Ramsar site in 1975. However, even though, due to many problems, including eutrophication produced by inflow of excess nutrients and organic materials, the wetland was also listed on the Montreux Record indicating the need to take urgent remedial action. This study was conducted to study the levels of polychlorinated biphenyls (PCBs) and total mercury (THg) in two fish species (Esox lucius and Carassius auratus) as bio-indicators of the ecosystem condition in eastern part of Anzali Wetland. The sampling was carried out in six different periods between years 2009 and 2010. The results showed that the amounts of PCBs in the muscle of northern pike were below the detection limit of gas chromatography, whereas the average concentration in goldfish was 0.449 mg/kg wet weight. Some possible reasons for the higher levels of PCBs in goldfish in comparison with pike have been discussed. No significant (p < 0.05) correlation was observed between PCBs and biological factors (weight, length, lipid content) for both species. On the other hand, the mean concentration of THg in the muscle of pike and goldfish were 182.22 and 75.27 ng/g dry weight, respectively. Although these concentrations were below US-EPA criterion for human consumption (0.3 mg/kg), it pointed up a significant deterioration of the ecosystem condition during the past years. Finally, statistical analysis revealed a significant correlation between THg with weight and an insignificant correlation with length for pike specimens.     

Evaluating the difference between the normalized difference vegetation index and net primary productivity as the indicators of vegetation vigor assessment at landscape scale

Both the net primary productivity (NPP) and the normalized difference vegetation index (NDVI) are commonly used as indicators to characterize vegetation vigor, and NDVI has been used as a surrogate estimator of NPP in some cases. To evaluate the reliability of such surrogation, here we examined the quantitative difference between NPP and NDVI in their outcomes of vegetation vigor assessment at a landscape scale. Using Landsat ETM+ data and a process model, the Boreal Ecosystem Productivity Simulator, NPP distribution was mapped at a resolution of 90 m, and total NDVI during the growing season was calculated in Heihe River Basin, Northwest China in 2002. The results from a comparison between the NPP and NDVI classification maps show that there existed a substantial difference in terms of both area and spatial distribution between the assessment outcomes of these two indicators, despite that they are strongly correlated. The degree of difference can be influenced by assessment schemes, as well as the type of vegetation and ecozone. Overall, NDVI is not a good surrogate of NPP as the indicators of vegetation vigor assessment in the study area. Nonetheless, NDVI could serve as a fairish surrogate indicator under the condition that the target region has low vegetation cover and the assessment has relatively coarse classification schemes (i.e., the class number is small). It is suggested that the use of NPP and NDVI should be carefully selected in landscape assessment. Their differences need to be further evaluated across geographic areas and biomes.