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621.
622.
G. Van Houte B. Delmon J.C. Maon Ph. Dumont 《Journal of the Air & Waste Management Association (1995)》2013,63(10):1030-1033
This publication concerns the dry removal of SO2 from gases using limestone absorbents. It reports bench-scale experiments made with commercial samples of powdered limestone (CaCO3) activated by addition of a cheap substance, namely CaCl2. The absorption was carried out in a fluidized bed traversed by the flue gases, between 600° and 900° C. The degree and rate of transformation of CaCO3 to CaSO4 in the presence of SO2 and air have been compared for unmodified and modified absorbents. Initial rates of reaction, and the variation of the rate of absorption with time have been measured. The influence of the SO2 content of the gas has been assessed. At 700° C, the maximum degree of transformation of activated limestone to sulfate exceeds 90%, whereas untreated CaCO3 transforms only to 16–20%. At the same temperature, more than 90% of SO2 contained In a gas carrying 0.35% SO2 is removed. Because of the much smaller quantity of solid absorbent required, dry absorption processes based on the modified absorbents might get renewed interest. The modified absorbents might also be used for in situ absorption in fluidized bed combustion, in which the temperatures are in the range studied in the present paper. 相似文献
623.
Richard G. Phelps 《Journal of the Air & Waste Management Association (1995)》2013,63(9):908-912
The problem of coke oven door leakage is generally recognized as one for which no proven solution exists. In 1974 the United States Environmental Protection Agency and the American Iron and Steel Institute entered into a jointly funded research project with Battelle Columbus Laboratories. The initial project was to define the problem by literature search, operator interviews and profile measurements of jambs and doors. Numerous concepts of seal designs were developed and then rated by industry and Battelle reviews. It was determined that a metal-to-metal seal offered the greatest probability of success. It was felt that jamb warpage was the most serious problem to be solved. In the fall of 1976 another contract was signed by EPA and AISI assigning Battelle the task of developing to the point of fabrication a system to eliminate or significantly reduce leakage from coke oven end closures. This program included mathematical modeling, physical modeling, field data collecting, analysis, and full scale unit design. A retrofittable door seal design has been developed and preparations are underway for operating evaluation at eight steel plants. The design is retrofittable to the two principal coke oven doors in service and should accommodate the worst jamb warpage usually found. 相似文献
624.
Larry G. Anderson 《Journal of the Air & Waste Management Association (1995)》2013,63(9):970-973
It has been recognized for several years that ozone in rural areas can exceed the National Ambient Air Quality Standard (NAAQS) for photochemical oxidant whirh was 0.08 ppm for one hour, not to be exceeded more than once per year. During the summer of 1973, the NAAQS was exceeded from 15 to 37% of the time at four rural monitoring sites in Maryland, Pennsylvania, Ohio, and West Virginia.1 This is a greater violation rate than is found in many urban areas. Dimitriades and Altshuller2 have enumerated four possible sources for this rural ozone: (a) transport from urban areas, (b) local photochemical generation from urban ozone precursors, (c) local photochemical generation from precursors of rural origin which may be man-made or natural, and (d) injection of stratospheric ozone into the rural area. This paper considers the chemistry pertinent to the first two of these possible sources of rural ozone, namely the long distance (overnight) transport of ozone and ozone precursors. 相似文献
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G. P. Greiner D. A. Furlong D. W. VanOsdell L. S. Hovis 《Journal of the Air & Waste Management Association (1995)》2013,63(10):1125-1130
The concept of electrostatic stimulation of fabric filtration (ESFF) has been investigated at pilot scale. The pilot unit consisted of a conventional baghouse in parallel with an ESFF baghouse, allowing direct comparison. All results reported in this paper are for pulse-cleaned bags in which the electric field was maintained parallel to the fabric surface. The performance of the ESFF baghouse has been superior to the parallel conventional baghouse by several measures. The ESFF baghouse demonstrated: (1) a reduced rate of pressure drop increase during a filtration cycle, (2) lower residual pressure drop, (3) stable operation at higher face velocities, and (4) improved particle removal efficiency. These benefits can be obtained with only minor modifications to conventional pulse-jet hardware and at low electrical power consumption. The indicated ability to operate at increased face velocities with only modest expenditure for electrical hardware leads to very favorable economic projections. 相似文献
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