Validation of Ucides cordatus as a bioindicator of oil contamination and bioavailability in mangroves by evaluating sediment and crab PAH records

This study is aimed at verifying the relevance of Ucides cordatus as a bioindicator of oil contamination and PAH bioavailability in mangrove sediments. For this, crabs and sediment cores were sampled from five mangroves, including an area suspected of contamination derived from an MF380 oil spillage, and analyzed for the 16 PAH in the USEPA priority list as well as for the five series of alkylated homologues. Concentrations in sediments varied from 35 microg kg-1 in the lower core layer of the control area to 33,000 microg kg-1 in the upper layer of the most contaminated area. Total PAH contents in crabs varied from 206 to 62,000 microg kg-1 and were closely correlated to that in sediments. In general, individual PAH profiles in both matrices were in good agreement. Phenanthrenes, however, were more predominant in crabs making up to 30-46% of the Total PAH. Accumulation factors found in the range of 0.7 to 35 were highly variable even after normalizing concentrations for organic carbon and lipid content. Survival in highly contaminated environment and reliable record of environmental contamination in the tissue provide evidence that U. cordatus is an excellent bioindicator for oil in mangroves.     

Are Toronto’s streams sick? A look at the fish and benthic invertebrate communities in the Toronto region in relation to the urban stream syndrome

Impacts of urbanization on aquatic ecosystems are intensifying as urban sprawl spreads across the global land base. The urban stream syndrome (USS) identifies “symptoms” associated with urban development including changes in biotic communities, hydrology, water chemistry, and channel morphology. Direct relationships between road density (as surrogate of urbanization) and indicators of the USS were identified for streams in the Toronto region. Significant negative relationships were revealed between road density and biological (fish and benthic macroinvertebrate) richness, diversity, and fish Index of Biotic Integrity scores. Significant positive relationships were found between road density and tolerant fish/benthic macroinvertbrates, benthos Family Biotic Index scores, mean summer stream temperature, stream flashiness, and several water quality variables. Analysis of biological data showed that only four fish species and a reduced number of benthic macroinvertebrate families remained at the most urbanized sites. Road density was found to be a major determinant in both the fish and benthic macroinvertebrate community structure.     

Dust explosion incidents and regulations in the United States

The U.S. Chemical Safety and Hazard Investigation Board (CSB) investigated three fatal dust explosions that all occurred in 2003. These explosions caused the deaths of 14 people and injured hundreds more. Two of the facilities were damaged beyond repair, and several hundred employees lost their jobs.

CSB's investigations revealed that the explosions had common causes, despite their geographic and industrial diversity. Consequently, CSB commissioned a study of combustible dust fire and explosion hazards. This paper presents a summary of CSB's findings and recommendations developed during that study.     

Continuous improvement and existing safety systems

This paper highlights some of the issues facing owner/operators when attempting to align personnel, procedures, and equipment to achieve cost effective and safe operating performance. Each issue is presented using simple and practical thoughts toward life, collected from fortune cookies consumed during the technical editing of CCPS's Guidelines for Safe and Reliable Instrumented Protective Systems (2007).     

Low-temperature chromium(VI) biotransformation in soil with varying electron acceptors

Effective and low-cost strategies for remediating chromium (Cr)-contaminated soil are needed. Chromium(VI) leaching from contaminated soil into ground water and surface water threatens water supplies and the environment. This study tested indigenous Cr(VI) microbial transformation in batch systems at 10 degrees C in the presence of various electron acceptors. The effects of carbon addition, spiked Cr(VI), and mixing highly contaminated soil with less contaminated soil were investigated. The results indicated that Cr(VI) can be biotransformed in the presence of different electron acceptors including oxygen, nitrate, sulfate, and iron. Sugar addition had the greatest effect on enhancing Cr(VI) removal. Less dissolved organic carbon (DOC) was consumed per amount of Cr(VI) transformed under anaerobic conditions [0.8-93 mg DOC/mg Cr(VI)] compared with aerobic conditions [1.4-265 mg DOC/mg Cr(VI)]. Toxicity of high concentrations (< 160 mg/L) of spiked Cr(VI) were not evident. At Cr(VI) concentrations > 40 mg/L, aerobic conditions promoted faster Cr(VI) reduction than anaerobic conditions with nitrate or sulfate present. Biotransformation of Cr(VI) in highly contaminated soil (22,000 mg Cr/kg) was facilitated by mixing with less-contaminated soil. The study results provide a framework for evaluating indigenous Cr(VI) microbial transformation and enhance the ability to develop strategies for soil treatment.     

Environmental legislation and contamination: The gap between theory and reality in South Africa

Like many areas of its constitution, South Africa has progressive legislation to both prevent and clean up environmental contamination. However, recent research has highlighted a large gap between legislation and practice. This paper presents the context of the intent of environmental waste legislation in South Africa and highlights a case of mercury contamination in a rural area which illustrates the gap between the theory of legislation and the reality on the ground. Mercury contamination in humans poses well known health threats, yet despite attention from the media, non-governmental organisations and academic researchers, a major pollutant remains and contamination levels remain high, two decades after the original polluting incident took place.     

Life‐cycle assessment of in situ thermal remediation

A detailed cradle‐to‐grave life‐cycle assessment (LCA) of an in situ thermal treatment remedy for a chlorinated‐solvent‐contaminated site was performed using process LCA. The major materials and activities necessary to install, operate, monitor, and deconstruct the remedy were included in the analysis. The analysis was based on an actual site remedy design and implementation to determine the potential environmental impacts, pinpoint major contributors to impacts, and identify opportunities for improvements during future implementation. The Electro‐Thermal Dynamic Stripping Process (ET‐DSP?) in situ thermal technology coupled with a dual‐phase extraction and treatment system was evaluated for the remediation of 4,400 yd³ of tetrachloroethene‐ and trichloroethene‐impacted soil, groundwater, and bedrock. The analysis was based on an actual site with an estimated source mass of 2,200 lbs of chlorinated solvents. The remedy was separated into four stages: remedy installation, remedy operation, monitoring, and remedy deconstruction. Environmental impacts were assessed using Sima Pro software, the ecoinvent database, and the ReCiPe midpoint and endpoint methods. The operation stage of the remedy dominated the environmental impacts across all categories due to the large amount of electricity required by the thermal treatment technology. Alternate sources of electricity could significantly reduce the environmental impacts of the remedy across all impact categories. Other large impacts were observed in the installation stage resulting from the large amount of diesel fuel, steel, activated carbon, and asphalt materials required to implement the technology. These impacts suggest where opportunities for footprint reductions can be found through best management practices such as increased materials reuse, increased recycled‐content materials use, and clean fuels and emission control technologies. Smaller impacts were observed in the monitoring and deconstruction stages. Normalized results show the largest environmental burdens to fossil depletion, human toxicity, particulate matter formation, and climate‐change categories resulting from activities associated with mining of fossil fuels for use in electricity production. In situ thermal treatment can reliably remediate contaminated source areas with contaminants located in low‐permeability zones, providing complete destruction of contaminants in a short amount of time, quick return of the site to productive use, and minimized quantities of hazardous materials stored in landfills for future generations to remediate. However, this remediation strategy can also result in significant emissions over a short period of time. It is difficult to quantify the overall value of short‐term cleanups with intense treatment emissions against longer‐term cleanups with lower treatment emissions because of the environmental, social, and economic trade‐offs that need to be considered and understood. LCA is a robust, quantitative tool to help inform stakeholder discussions related to the remedy selection process, trade‐off considerations, and environmental footprint‐reduction opportunities, and to complement a broader toolbox for the evaluation of sustainable remediation strategies. © 2012 Wiley Periodicals, Inc.     

Manganese nodules and marine technology

This article examines the problems and prospects of manganese nodule mining. The technological requirements for the exploitation of nodule deposits are considered, superimposed on an interdisciplinary policy-oriented approach. The technological dimension is emphasized because its crucial importance is often underrated when deep ocean mining is assessed. This dimension cannot be divorced from the interactions between economics, international law and oceanography. The technological problems and opportunities of nodule mining are diverse. Provided delays at the UN and economic uncertainties do not channel some of the interest into land-based alternatives, this could be an important area of future technical development.     

Overfill protective systems – Complex problem,simple solution

Overfills have resulted in significant process safety incidents. Longford (Australia, 1998), Texas City (United States, 2005), and Buncefield (United Kingdom, 2005) can be traced to loss of level control leading to high level and ultimately to loss of containment. A tower at Longford and a fractionating column at Texas City were overfilled, allowing liquid to pass to downstream equipment that was not designed to receive it. The Buncefield incident occurred when a terminal tank was overfilled releasing hydrocarbons through its conservation vents.The causes of overfill are easy to identify; however, the risk analysis is complicated by the combination of manual and automated actions often necessary to control level and to respond to abnormal level events. This paper provides a brief summary of the Longford, Texas City, and Buncefield incidents from an overfill perspective and highlights 5 common factors that contributed to making these incidents possible. Fortunately, while overfill can be a complex problem, the risk reduction strategy is surprisingly simple.