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911.
Nadeem W. Shah Steven F. Thornton Simon H. Bottrell Michael J. Spence 《Journal of contaminant hydrology》2009,103(3-4):119-133
The potential for aerobic biodegradation of MTBE in a fractured chalk aquifer is assessed in microcosm experiments over 450 days, under in situ conditions for a groundwater temperature of 10 °C, MTBE concentration between 0.1 and 1.0 mg/L and dissolved O2 concentration between 2 and 10 mg/L. Following a lag period of up to 120 days, MTBE was biodegraded in uncontaminated aquifer microcosms at concentrations up to 1.2 mg/L, demonstrating that the aquifer has an intrinsic potential to biodegrade MTBE aerobically. The MTBE biodegradation rate increased three-fold from a mean of 6.6 ± 1.6 μg/L/day in uncontaminated aquifer microcosms for subsequent additions of MTBE, suggesting an increasing biodegradation capability, due to microbial cell growth and increased biomass after repeated exposure to MTBE. In contaminated aquifer microcosms which also contained TAME, MTBE biodegradation occurred after a shorter lag of 15 or 33 days and MTBE biodegradation rates were higher (max. 27.5 μg/L/day), probably resulting from an acclimated microbial population due to previous exposure to MTBE in situ. The initial MTBE concentration did not affect the lag period but the biodegradation rate increased with the initial MTBE concentration, indicating that there was no inhibition of MTBE biodegradation related to MTBE concentration up to 1.2 mg/L. No minimum substrate concentration for MTBE biodegradation was observed, indicating that in the presence of dissolved O2 (and absence of inhibitory factors) MTBE biodegradation would occur in the aquifer at MTBE concentrations (ca. 0.1 mg/L) found at the front of the ether oxygenate plume. MTBE biodegradation occurred with concomitant O2 consumption but no other electron acceptor utilisation, indicating biodegradation by aerobic processes only. However, O2 consumption was less than the stoichiometric requirement for complete MTBE mineralization, suggesting that only partial biodegradation of MTBE to intermediate organic metabolites occurred. The availability of dissolved O2 did not affect MTBE biodegradation significantly, with similar MTBE biodegradation behaviour and rates down to ca. 0.7 mg/L dissolved O2 concentration. The results indicate that aerobic MTBE biodegradation could be significant in the plume fringe, during mixing of the contaminant plume and uncontaminated groundwater and that, relative to the plume migration, aerobic biodegradation is important for MTBE attenuation. Moreover, should the groundwater dissolved O2 concentration fall to zero such that MTBE biodegradation was inhibited, an engineered approach to enhance in situ bioremediation could supply O2 at relatively low levels (e.g. 2–3 mg/L) to effectively stimulate MTBE biodegradation, which has significant practical advantages. The study shows that aerobic MTBE biodegradation can occur at environmentally significant rates in this aquifer, and that long-term microcosm experiments (100s days) may be necessary to correctly interpret contaminant biodegradation potential in aquifers to support site management decisions. 相似文献
912.
David W. Ostendorf Baoshan Xing Niki Kallergis 《Journal of contaminant hydrology》2009,106(3-4):118-130
At a former wood preservation plant severely contaminated with coal tar oil, in situ bulk attenuation and biodegradation rate constants for several monoaromatic (BTEX) and polyaromatic hydrocarbons (PAH) were determined using (1) classical first order decay models, (2) Michaelis–Menten degradation kinetics (MM), and (3) stable carbon isotopes, for o-xylene and naphthalene. The first order bulk attenuation rate constant for o-xylene was calculated to be 0.0025 d− 1 and a novel stable isotope-based first order model, which also accounted for the respective redox conditions, resulted in a slightly smaller biodegradation rate constant of 0.0019 d− 1. Based on MM-kinetics, the o-xylene concentration decreased with a maximum rate of kmax = 0.1 µg/L/d. The bulk attenuation rate constant of naphthalene retrieved from the classical first order decay model was 0.0038 d− 1. The stable isotope-based biodegradation rate constant of 0.0027 d− 1 was smaller in the reduced zone, while residual naphthalene in the oxic part of the plume further downgradient was degraded at a higher rate of 0.0038 d− 1. With MM-kinetics a maximum degradation rate of kmax = 12 µg/L/d was determined. Although best fits were obtained by MM-kinetics, we consider the carbon stable isotope-based approach more appropriate as it is specific for biodegradation (not overall attenuation) and at the same time accounts for the dominant electron-accepting process. For o-xylene a field based isotope enrichment factor εfield of − 1.4 could be determined using the Rayleigh model, which closely matched values from laboratory studies of o-xylene degradation under sulfate-reducing conditions. 相似文献
913.
Although the use of tributyltin in antifouling paints has been banned, this compound is still a serious pollutant of the marine environment. This paper describes a unique study in which European flounder (Platichthys flesus) were chronically (8 months) exposed to bis(tri-n-butyltin)oxide (TBTO) in the water under controlled laboratory conditions. Residue levels in selected tissues (liver, muscle) and general health status indices were measured and the effects on several organs (gills, liver, mesonephros, ovary/testis, spleen, and gastrointestinal tract) were examined histopathologically. Additionally, morphometric analysis of the thymus was performed. The major finding is that exposure of flounder to 5 μg TBTO/l over a period of 8 months, resulting in body burdens comparable to high field levels, induced significant reduction of thymus volume, possibly affecting immunocompetence of the animals. Chronic exposure of European flounder to tributyltin is therefore likely to affect the general health status of this species in heavily polluted aquatic environments. 相似文献
914.
Epidemiological studies suggesting the possibility of harmful effects on human (specifically children’s leukaemia) due to
long-term exposure to magnetic fields of extremely low frequency (e.g. 50/60 Hz) and relatively low values (i.e. over the
microtesla range) have stirred high activity in the topic of magnetic field mitigation. To reduce these fields, it is common
to use passive metal screens (e.g. plates made of aluminium or steel). To design them, effective and fast numerical computations
are highly desirable. In this article, a method is presented, which computes various parameters of screens in a given shielding
problem and yields magnetic field distribution and shielding factors. The method takes into consideration the 3D field distribution
and is able to solve systems with large aspect ratios (thin thickness in comparison with its other dimensions); this is a
common problem where other methods such as finite elements often experience difficulties. The presented method computes separately
the field inside and outside the screens. Afterwards, the solutions are “stitched” together along the border of the subregions.
Two practical examples are given of the developed numerical method. 相似文献
915.
On experimental setup in bioelectromagnetics 总被引:1,自引:1,他引:0
Bioeffects created by electromagnetic field (EMF) are the subject of intensive studies. This paper critically considers estimations
of exposure to EMF in bioelectromagnetic experiments. Results of calculations presented herein show the significant role of
the presence of conducting bodies (the exposure system) near an object under test on EMF energy absorption as well as mutual
interactions between simultaneously exposed objects. Our aims herein are twofold: firstly to find a way to refer measurement
results to free-space conditions in order to enable comparison of results obtained in different laboratories, and secondly
to show that EMF energy absorption in any exposed object is different and that this difference is a function of the size of
the exposure system, the number of exposed objects, and the particular properties (i.e., the electromagnetic structure) of
the objects. In the authors’ opinion the existence of interactions caused by the presence of the exposure system and other
exposed objects is a reason why remarkable differences are observed between experiments performed even under supposedly identical
conditions. The presented considerations and conclusion suggest wider participation of physicists and engineers in bioelectromagnetic
experiments in order to ensure the correctness of metrological aspects of these experiments. 相似文献
916.
Forest ecosystems may be actively managed toward heterogeneous stand structures to provide both economic (e.g., wood production
and carbon credits) and environmental benefits (e.g., invasive pest resistance). In order to facilitate wider adoption of
possibly more sustainable forest stand structures, defining growth expectations among alternative management scenarios is
crucial. To estimate the effect of tree size and spatial distributions on growth for forest structures commonly considered
in uneven-aged forest stand management, large (0.2 ha+) plots were established in 14 uneven-aged ponderosa pine stands in
eastern Montana. All study trees were stem-mapped and measured for diameter and 10-year sapwood and basal area increment.
A generalized growth model was developed to predict both total and merchantable 10-year basal area increment for nine hypothetical
stand structures [three diameter distributions (reverse-J, irregular, flat) × three spatial distributions (clumpy, partial
clumpy, uniform)]. Results indicate that the size and spatial distributions of individual trees have a considerable effect
on overall stand growth. The greatest total stand growth was in stands with reverse “J” shaped tree size distributions, while
the greatest merchantable stand growth was in stands with “flat” diameter distributions and uniform spatial distributions.
Through better comprehension of generalized uneven-aged stand growth dynamics, forest managers may better assess the effects
of alternative stand structures on stand growth while providing forest stand structures that may be more resilient in a changing
climate. 相似文献
917.
Urbanization and its impact on groundwater: a remote sensing and GIS-based assessment approach 总被引:1,自引:0,他引:1
The perils of unplanned urbanization and increasing pressure of human activities on hydro-geomorphologic system often result
in modification of the existing recharge mechanism, which leads to many environmental consequences. In the present research,
an attempt has been made to investigate the applicability of remote sensing and geographical information system (GIS) in dealing
with spatial and temporal variability of dynamic phenomena, like urbanization and its impact on groundwater. This paper covers
primarily, quantitative and qualitative impacts of urban growth on the behavior of aquifer in Ajmer city (India). Urban growth
of the Ajmer city in last 17 years has been estimated from the satellite images. Database related to urbanization and groundwater
has been created in GIS. Groundwater recharge has been computed using a water balance approach known as Water Level Fluctuation
Methodology. Recharge estimation methodology has been implemented in GIS to introduce the spatial variability of hydro-geological
characteristics. Further, temporal and spatial variations in groundwater quality and quantity have been correlated with urban
growth using overlay analysis in GIS. The study reveals a general decline in water table and quality with urbanization. Further,
remote sensing and GIS technologies have been found useful in assessment of spatial and temporal phenomena of urbanization
and its impact on groundwater system. 相似文献
918.
How organizational motives and communications affect public trust in organizations: The case of carbon dioxide capture and storage 总被引:1,自引:0,他引:1
Bart W. Terwel Fieke Harinck Naomi Ellemers Dancker D.L. Daamen 《Journal of environmental psychology》2009,29(2):290-299
Preventing climate change is among the greatest environmental challenges facing the world today. Recently developed carbon dioxide capture and storage (CCS) technology is an important strategy to mitigate climate change. Public trust in organizations involved in CCS technology is important for successful implementation of this technology. This work adresses how inferred organizational motives and organizational communications affect public trust in these organizations. Study 1 (N = 264) showed that Dutch citizens generally have less trust in the industrial organizations than in the environmental NGOs involved in CCS. As predicted, inferred organizational motives (organization-serving motives versus public-serving motives) accounted for this difference. In Study 2 (N = 78) and Study 3 (N = 51) we used experimental designs. Both experiments showed that organizations that communicated arguments incongruent with inferred organizational motives instigated less trust than organizations that communicated arguments congruent with inferred organizational motives. Study 3 additionally showed that communicating an incongruent and a congruent argument together diminished the negative effects of the incongruent argument. In both Study 2 and Study 3 the effect of congruency on trust was mediated by perceived honesty of the organizations. 相似文献
919.
920.
Michael J. Paul David W. Bressler Alison H. Purcell Michael T. Barbour Ed T. Rankin Vincent H. Resh 《Journal of the American Water Resources Association》2009,45(2):320-330
Abstract: Urbanization represents a strong and increasingly more prevalent impact on stream quality worldwide. One of the characteristic effects of increased urbanization is a consistent decline in biological stream condition. The characterization of this biological degradation with increasing urbanization presents a number of advantages for the study and management of urban streams and catchments. In this paper, the limitation of biological condition with urbanization, called observed biological potential, is characterized. Using an urban intensity index and a biological index developed specifically for urban systems in the Baltimore, Maryland; Cleveland, Ohio; and San Jose, California regions, two principal techniques were compared (quantile regression and bin regression) to define observed biological potential along urban gradients. Quantile regression was selected as the preferable tool for describing observed biological potential given the consistency with which it can be applied and its statistical efficiency, however, bin quantile regression performed similarly. Having identified a numeric approximation of observed biological potential, two methods for identifying factors related to distance from potential as a way of identifying critical environmental factors affecting biological condition in urban areas were explored. The results of this work can be used for identifying benchmarks for urban stream biological condition, identifying limiting catchment characteristics, and prioritizing urban stream management efforts. 相似文献