Photocatalytic degradation of the herbicide chloridazon on mesoporous titania/zirconia nanopowders

Advanced oxidation processes using semiconducting photocatalysts for the degradation of organic pollutants are a promising approach for the remediation of pesticide-contaminated wastewater. High photodegradation efficiency and stability of the photocatalyst are of key importance for practical application of the semiconductor. In this study, mesoporous TiO₂/ZrO₂ nanopowders were synthesized via two techniques; evaporation-induced self-assembly (EISA) and sol-gel using triblock copolymers Pluronic P123 and F127. The photodegradation activities of the composites were determined by employing the herbicide chloridazon as a model compound. Due to well-developed mesoporosity, the TiO₂/ZrO₂ nanocomposite synthesized by EISA displays high surface area and small crystallite sizes leading to higher photocatalytic activity than pristine TiO₂ prepared under similar condition and commercial Degussa P25 nanopowder. The optimum amount of zirconium required for the highest activities was identified and found to be 0.14 and 0.05 mol% for the EISA and sol-gel-prepared samples, respectively. Systematic studies of the post-thermal treatment step for both samples show that Zr inhibits an anatase-to-rutile phase transition only up to 600 °C, at higher temperature phase separation occurs. Samples synthesized by EISA method showed enhanced degradation activity than sol-gel-synthesized samples.     

Fetal fibrochondrogenesis at 26 weeks' gestation

An Erratum has been published for this article in Prenatal Diagnosis 22(13) 2002, 1241. Fibrochondrogenesis is a rare and lethal osteochondrodysplasia with an autosomal recessive mode of inheritance. We report a male fetus in which the diagnosis of lethal osteochondrodysplasia was suspected on prenatal ultrasound and radiological examinations during the second trimester of pregnancy. After termination of pregnancy, fibrochondrogenesis was diagnosed by radiological examination and histological study of fetal bones. Interwoven fibrous septa and fibroblastic degeneration of chondrocytes are pathognomonic. The recurrence rate is 25% and accurate diagnosis is necessary to enable genetic counselling. Copyright © 2002 John Wiley & Sons, Ltd.     

Hazardous chemical site remediation through capping: Problems with long-term protection

The capping of waste management units and contaminated soils is receiving increasing attention as a low-cost method for hazardous chemical site remediation. Capping is used to prevent further groundwater pollution by existing waste management units and contaminated soils through limiting the moisture that enters the wastes. In principle, for wastes located above the water table, the construction of an impermeable cap can prevent leaching of the wastes (leachate generation) and groundwater pollution. In practice, appropriately designed and constructed RCRA caps can provide for only short-term prevention of groundwater pollution. Alternative approaches are available for capping of wastes that can be effective in preventing moisture from entering the wastes and concomitant groundwater pollution. These approaches recognize the inability of the typical RCRA cap to keep wastes dry for as long as waste constituents will be a threat and, most importantly, provide the necessary funds to effectively address all plausible worst-case scenario failures that could occur at a capped waste management unit or contaminated soil area.     

DROUGHT INDICATORS AND TRIGGERS: A STOCHASTIC APPROACH TO EVALUATION1

ABSTRACT: Drought management depends on indicators to detect drought conditions, and triggers to activate drought responses. But determining those indicators and triggers presents challenges. Indicators often lack spatial and temporal transferability, comparability among scales, and relevance to critical drought impacts. Triggers often lack statistical integrity, consistency among drought categories, and correspondence with desired management goals. This article presents an approach for developing and evaluating drought indicators and triggers, using a probabilistic framework that offers comparability, consistency, and applicability. From that, a multistate Markov model investigates the stochastic behavior of indicators and triggers, including transitioning, duration, and frequency within drought categories. This model is applied to the analysis of drought in the Apalachicola‐Chattahoochee‐Flint River Basin in the southeastern United States, using indicators of the Standardized Precipitation Index (for 3, 6, 9, and 12 months), the Palmer Drought Severity Index, and the Palmer Hydrologic Drought Index. The analysis revealed differences among the performance of indicators and their trigger thresholds, which can influence drought responses. Results contribute to improved understanding of drought phenomena, statistical methods for indicators and triggers, and insights for drought management.     

Progress in teenage crash risk during the last decade

OBJECTIVE: The purpose of the present study was to examine the most recent data on teenagers' fatal and nonfatal crashes in the United States to determine current crash rates as well as changes in crash rates during the past decade METHODS: Data for calendar years 1996 and 2005 were extracted for fatal crashes from the Fatality Analysis Reporting System and for police-reported crashes from the National Automotive Sampling System/General Estimates System. To calculate crash rates, population data were obtained from the Census Bureau, and mileage data were obtained from the 2001 National Household Travel Survey RESULTS: During 2001-02, the latest year for which mileage data are available, 16 year-old drivers had higher fatal and nonfatal crash rates per mile traveled than all but the very oldest drivers. However, fewer 16 year-olds typically are licensed to drive and they drive fewer miles per year than all but the oldest drivers. Thus, their fatal and nonfatal crash rates per population in 2005 were lower than among other teenagers and among drivers 20-29. During the past decade the most progress has been made in reducing crashes among the youngest drivers. Between 1996 and 2005 both fatal and police-reported crashes per population declined about 40% for 16 year-old drivers, compared with about 25% for 17 year-old drivers and 15-19% for 18 year-old drivers. The greatest reductions for 16 year-olds occurred in nighttime crashes, alcohol-related fatal crashes, and fatal crashes involving multiple teenage passengers. CONCLUSIONS: Substantial progress has been made in reducing fatal and nonfatal crashes per population among 16 year-old drivers. Although this study was not designed to examine the role of graduated licensing, the results are consistent with the increased presence of such laws, many of which restrict nighttime driving and driving with teenage passengers. IMPACT ON INDUSTRY: Restrictions on nighttime driving and driving with teenage passengers should be made a part of all states' graduated licensing systems. Historically, 16 year-olds have had the highest crash risk per licensed driver and per mile traveled. Given the dramatic reductions in per population crash rates among 16 year-olds, it is possible that their per mile and per licensed driver rates also have declined and may no longer be as elevated relative to other ages. However, shortcomings in the licensed driver data and a lack of recent mileage data hamper our ability to examine these issues. If we are to continue to provide a yardstick against which we can measure progress among the youngest drivers, immediate steps need to be taken to restore the availability of reliable exposure data.     

Age of licensure and monitoring teenagers' driving: survey of parents of novice teenage drivers

OBJECTIVE: To assess parental decision making regarding the timing of teenagers initiating driving and monitoring teenagers' driving after licensure. METHODS: About 300 parents were interviewed during spring 2006 in Minnesota, North Carolina, and Rhode Island, states with varying licensing provisions, while teenagers took their first on-road driving tests. RESULTS: States' differences in ages of obtaining learner's permits and licenses reflected different licensing laws, but most teenagers obtained permits and took road tests within the first few months after they became eligible. Common reasons for delaying obtaining permits were fulfilling driver education requirements and lack of readiness/immaturity. Insufficient practice driving most often delayed licensure. Among the parents interviewed, 33-49% believed the minimum licensure age should be 17 or older. Almost all parents planned to supervise teenagers' driving after licensure, and most wanted to know about speeding or distractions. When asked about in-vehicle devices to monitor teenagers' driving, 37-59% of parents had heard of them. Parents were least interested in using video cameras and about equally interested in computer chips and cell-phone-based GPS systems. Disinterest in monitoring devices most often was attributed to trusting teenagers or respecting their privacy. CONCLUSIONS: Licensing laws influence ages of initiating driving. Although many parents support licensing at 17 or older - higher than in all but one state - most teenagers initiate driving soon after reaching the minimum age. Parents plan to supervise teenagers' driving, and many say they are open to using in-vehicle monitoring devices. IMPACT ON INDUSTRY: Many parents support a minimum licensing age of 17 or older and would consider in-vehicle devices to extend their supervision of teenager's driving.     

Understanding non-industrialized workers' approaches to safety: How do commercial fishermen “stay safe”?

BACKGROUND: Commercial fishing is carried out worldwide, often in non-industrialized forms, and is associated with high rates of fatal and non-fatal occupational injury. PROBLEM: Fishermen who work independently in non-industrialized settings do not have access to union or industry sponsored safety services and must make their own decisions about safety practices. Learning the meaning of safety for them and the safety measures they employ is important before developing interventions. METHODS: Two fieldworkers conducted in-depth ethnographic interviews with 31 commercial fishermen in North Carolina. Interviews and fieldnotes were analyzed using QSR N5. RESULTS: Fishermen primarily related staying safe to work practices and attitudes. They identified specific safety measures, appropriate gear and boat maintenance, weather decisions, and working cooperatively when ocean fishing. DISCUSSION: The ethnographic research process can produce information about a group's norms of preventive behavior and safety concerns. Knowledge of workers' concepts and practices will inform researchers' inquiries.     

Public engagement and climate adaptation: insights from three local governments in Australia

Public participation in decision making is a central component of the planning process; however, implementing effective engagement initiatives to resolve complex planning and policy problems, such as climate change, is challenging for planners. These challenges are particularly acute in coastal communities throughout Australia, where many settlements are at risk of future climate perturbations. Using the International Association for Public Participation framework for public participation, we analyse three local government led public participation initiatives in New South Wales, Victoria and Tasmania, Australia. Our analysis suggests there are three critical factors that can influence the level of public participation in the context of climate change adaptation: the technocratic approach to decision making; absent high order government support; and the lack of evaluation mechanisms for public participation.