用GC-三级四极杆MS/MS一次进样筛选鱼和飞灰样品基质中四至八氯代PCDD/Fs的方法

用高分离能力的气相色谱-高分辨质谱(HRGC-HRMS)核实二噁英/呋喃是一项昂贵又费时的分析工作,需要高素质的仪器操作人员,而在认证分析前采用筛选法检查样品是检测不出还是浓度超出HRGC-HRMS方法定量范围,可以大大地减少HRGC-HRMS实验室的工作负荷.最新提供的信息表明约10%筛选过的样品需用HRGC-HRMS认证/核实.有些GC/MS/MS方法需要多次进样以获得有毒和无毒的PCDD/Fs,或用功能变换法[1-4]可以确保检测出所有的有毒的2,3,7,8-氯代PCDD/Fs,但损失某些无毒的PCDD/Fs(2,3,7,8氯代PCDD/Fs除外).     

Comparative study of cadmium levels of shellfish and finfish species

This study indicates that the concentration of cadmium in shellfish species may often be higher than it is in their environment as a result of formation of stable biological chelate complexes. This study also indicates that the concentration of cadmium in finfish species is less than the shellfish species. It was found that cadmium levels in shellfish were relatively higher in oysters and shrimps, moderately high in scallops and squids, and less in crabs and clams. It seems that cadmium levels are surprisingly elevated in shellfish than other saltwater finfish. It also seems that larger shellfish had higher Cd content levels than the smaller shellfish of the same species.     

Policies towards proposals for large-scale natural resource projects: Attenuation versus postponement

The authors examine the problem of dealing with the environmental impact of uranium mining in Australia and consider its wider implications. Government, faced with unknown environmental and social damage from the initiation of uranium mining in northern Australia, has initiated an environmental impact assessment procedure. This requires the appellant company to provide information about the proposed project and its alternatives and is often followed by a period of ‘postponement’. This is compared with an alternative procedure, ‘attenuation’, allowing the project to proceed on a reduced scale in order to obtain information. Comparisons are made between the information which might be obtained by the two alternative procedures and the expected relative benefits and costs from a postponed project and an attenuated project.     

Weekend–weekday aerosols and geographic variability in cloud-to-ground lightning for the urban region of Atlanta, Georgia, USA

We characterized the differences in warm-season weekday and weekend aerosol conditions and cloud-to-ground (CG) flashes (1995–2008) for an 80,000 square kilometer region around Atlanta, Georgia, a city of 5.5 million in the humid subtropics of the southeastern United States. An integration of distance-based multivariate techniques (hierarchical agglomerative clustering, multiresponse permutation procedures, fuzzy kappa statistics, and Mantel tests) indicated a greater concentration of CG flash activity within a 100 km radius around Atlanta under weekday aerosol concentrations. On weekends, these effects contracted toward the city. This minimized any weekly anthropogenic cycle over the more densely populated urban center even though this location had a higher flash density, a higher percentage of days with flashes, and stronger peak currents over the course of a week compared to the surrounding region. The sharper contrasts in weekday and weekend lightning regime developed outside the perimeter of the city over nonurban land uses. Here, lightning on weekend and weekdays differed more in its density, frequency, polarity, and peak current. Across the full extent of the study region, weekday peak currents were stronger and flash days more frequent, suggesting that weekly CG lightning signals have a regional component not tied to a single city source. We integrate these findings in a conceptual model that illustrates the dependency of weekly anthropogenic weather signals on spatial and temporal extent.     

Field Exposure Study of Polylactic Acid (PLA) Plastic Films in the Banana Fields of Costa Rica

For use by the banana industry of Costa Rica, polylactic acid (PLA) plastic ropes and banana finger shrouds must remain operational for 14 to 16 weeks, and they also must be able to break down in the soil after serving their purposes. The banana field at La Rebusca Farm (Costa Rica) and the experiment station at University of Costa Rica were selected for a field exposure study of Cargill EcoPla Generation II (GII) and Cargill EcoPla monolayer (Ca-I) PLA films. The average monthly temperature, relative humidity, and cumulative rainfall of the La Rebusca Farm and the University of Costa Rica site were 26 and 22°C, 92 and 84%, and 352 and 177 in., respectively. The PLA plastic films at the La Rebusca Farm lost their mechanical properties earlier than at the University of Costa Rica site because of the higher temperature and relative humidity of the banana farm. The Ca-I film meets the 14-week operational time frame and it is recommended for further studies as ropes and banana shrouds.     

Long-term trends in organochlorine and mercury residues in some predatory birds in Britain

Residue levels of organochlorine pesticides (HEOD, DDE), polychlorinated biphenyls (PCBs) and mercury (Hg) in the livers of five predatory bird species were monitored in Britain over a 28-year (1963-1990) period. Of two raptor species, sparrowhawks contained higher levels of most chemicals than did kestrels. Among three fish-eaters, herons and kingfishers contained the highest levels of DDE and HEOD, while herons and great-crested grebes contained the highest levels of PCBs and mercury. Species differences were related partly to diet and habitat. In sparrowhawks and kestrels, residues of HEOD and DDE were higher in eastern, arable districts than elsewhere, especially in the 1960s and 1970s. In the fish-eaters, similar regional differences in residue levels were apparent in herons, especially in the 1970s, but not in the other species, for which samples were smaller. Over the 28 years, most species showed significant downward trends in HEOD, DDE and Hg levels, but only two fish-eaters showed significant declines in PCB levels. The downward trends in DDE and HEOD followed successive restrictions in the use of organochlorine pesticides, and were accompanied by recoveries in the populations and breeding success of affected species. Downward trends in mercury were associated with reductions in both agricultural use and industrial emissions.     

Controls on leaching of N species in upland moorland catchments

Spatial and temporal changes in mobility of N species have been studied for three UK upland river networks, the Etherow in the South Pennines, the Nether Beck in the Lake District and the Dee in NE Scotland. The catchments are subject to N deposition at 35.1, 22.0 and 10.8–15.6 kg N ha^?1 yr^?1, respectively. The NH⁺ ₄ leaching appears to be predominantly regulated by flow path in more polluted upland catchments. It is greatest where water draining acidified peaty soils contributes more to total discharge. Soluble organic matter may provide the dominant counter anion. In the Etherow and Dee catchments, which are dominated by acid mineral and organic soils, at high discharge NO^? ₃ also appears to be associated with greater input of water from acidified soils. In contrast, for the Nether Beck, higher NO^? ₃ concentrations are associated with tributaries draining soils contributing water with higher alkalinity, suggesting nitrification is important. For the Etherow and Dee, dissolved organic N (DON) appears to originate predominantly from acidified, peaty soils. Spiking experiments with peat soil from the Etherow catchment confirmed the limited capacity of these soils to utilize inorganic N inputs, favouring equilibration with NH⁺ ₄ inputs and leaching losses of inorganic N throughout the year.