Biosorption of copper from aqueous solutions utilizing agricultural wastes

The purpose of this study was to determine the copper (Cu) biosorption capacities of several agricultural wastes from aqueous solutions. Samples of agricultural wastes were tested unaltered and after hydrochloric acid (HCl) treatment. Additional parameters tested include sample dose, contact time, particle size, mixing temperature, and the concentrations and pH of the Cu solutions. Desorption studies were performed to determine if the removed Cu could be recovered. In addition, tests were conducted to determine if the agricultural waste samples (AWS) could be reused for additional Cu biosorption cycles. The results of this study demonstrate a wide range of Cu biosorption proficiencies ranging from 0% to 100% removal. The parameters that resulted in higher Cu removal include higher pH and lower Cu solution concentration. Desorption results showed a 58% to 86% Cu recovery rate. Three of the five reused AWS were effective at removing Cu during subsequent trials. Therefore, these AWS types can be reused for additional Cu biosorption cycles. Hence, it is possible that using those AWS for metal treatment could reduce hazardous waste disposal inefficiencies and costs by avoiding disposing of spent AWS following each Cu biosorption cycle.     

The costs and benefits of working with one's spouse: A two‐sample examination of spousal support,work–family conflict,and emotional exhaustion in work‐linked relationships

Although the prevalence of employees working within the same workplace or occupation with their spouse has increased, relatively little research has examined their experiences. On the basis of the boundary and conservation of resources (COR) theories, we argue that higher levels of work–family role integration among work‐linked couples will lead to higher levels of spousal support resources and lower levels of work–family conflict. This will, in turn, lead to lower emotional exhaustion among employees in a work‐linked relationship. Among two samples of employees in a variety of occupations, we found that being in a work‐linked relationship was associated with both higher spousal instrumental support as well as different forms of work–family conflict. The interaction between spousal support and work–family conflict was associated with emotional exhaustion. We discuss the implications of these findings for boundary and COR theories in terms of movement of resources across work–family boundaries and resource relevance in the strain process. Copyright © 2011 John Wiley & Sons, Ltd.     

Enforcement missions: Targets vs budgets

Enforcement of policy is typically delegated. What sort of mission should the head of an enforcement program be given? When there is more than one firm being regulated the firms’ decision problems—otherwise completely separate—become linked in a way that depends on that mission. Under some sorts of missions firms compete to avoid the attention of the enforcer by competitive reductions in the extent of their non-compliance, in others the interaction encourages competitive expansions. We develop a general model that allows for the ordering of some typical classes of missions. We find that in plausible settings ‘target-driven’ missions (that set a hard target in terms of environmental outcome but flexible budget) achieve the same outcome at lower cost than ‘budget-driven’ ones (that fix the enforcement budget). Inspection of some fixed fraction of firms is never optimal.     

Paternity alone does not predict long-term investment in juveniles by male baboons

Adult male chacma baboons (Papio hamadryas ursinus) form preferential associations, or friendships, with particular lactating females. Males exhibit high levels of affiliative contact with their friends’ infants and defend them from potentially infanticidal attacks (Palombit et al. 1997). Little is known about males’ associations with juveniles once they have passed the period of infanticidal risk. We conducted an observational, experimental, and genetic study of adult male and juvenile chacma baboons in the Moremi Reserve, Botswana. We identified preferential associations between males and juveniles and used behavioral data and a playback experiment to explore whether those associations have potential fitness benefits for juveniles. We determined whether males preferentially invest in care of their own offspring. We also determined how often males invest in care of their former friends’ offspring. The majority of juveniles exhibited preferential associations with one or two males, who had almost always been their mother’s friend during infancy. However, in only a subset of these relationships was the male the actual father, in part because many fathers died or disappeared before their offspring were weaned. Male caretakers intervened on behalf of their juvenile associates in social conflicts more often than they intervened on behalf of unconnected juveniles, and they did not appear to differentiate between genetic offspring and unrelated associates. Playbacks of juveniles’ distress calls elicited a stronger response from their caretakers than from control males. Chacma males may provide care to unrelated offspring of former friends because the costs associated with such care are low compared with the potentially high fitness costs of refusing aid to a juvenile who is a possible offspring.     

Field test of best management practice pollutant removal efficiencies in Shenzhen, China

This paper presents a study on the use of best management practices (BMPs) for controlling nonpoint pollution in the Xikeng Reservoir watershed located in Shenzhen, China. A BMP treatment train design, including a pond, a wetland, and a buffer strip placed in series was implemented at the reservoir location. A separate grass swale was also constructed at the site. Low impact development (LID) BMPs, namely a planter box and bioboxes, were used at the parking lot of the reservoir’s Administration Building. Samples were collected during storm events and were analyzed for total suspended solids (TSS), biochemical oxygen demand (BOD₅), ammonia nitrogen (NH₃—N), and total phosphorus (TP). The removal efficiencies of both BMP systems were evaluated using the Efficiency Ratio (ER) method based on the event mean concentration (EMC) data. In summary, the pond/wetland treatment train removed 70%―90% of TSS, 20%―50% of BOD₅, and 30%―70% of TP and NH₃—N. The swale removed 50%―90% of TSS, 30%―55% of BOD₅, −10%―35% of NH₃—N, and 25%―70% of TP. For the planter box and biobox, the ranges of removal rates were 70%―90%, 20%―50%, and 30%―70% for TSS, BOD₅, and ammonia and phosphorus, respectively.     

Drastic decline of an extensive eelgrass bed in Nova Scotia due to the activity of the invasive green crab (Carcinus maenas)

In 2001–2002, there were severe declines of eelgrass (Zostera marina) in estuaries along the Nova Scotia coast of the southern Gulf of St. Lawrence. We examined the relationship between the recent invasion of European green crabs (Carcinus maenas) and the eelgrass decline in Benoit Cove in Tracadie Harbour. The abnormally abundant eelgrass wrack consisted mainly of entire shoots, not the usual blades. Three separate methods yielded similar estimates of the rate of shoot removal from the eelgrass beds (direct quadrat counts, “mark–recapture” of tagged shoots in the eelgrass bed, and rate of shoot appearance in the shore wrack). From 14 July to 8 September 2002, the shoot density in the bed fell by about 75 %. Similar rates of decline occurred in crab enclosures (4.4 crabs m^?2) placed in the eelgrass bed. Green crab foraging, involving the tearing of shoots and the digging of large pits, was the reason for the drastic decline of the eelgrass bed in Benoit Cove. It is clear that an invasion of green crabs to a region where they had not previously existed can both destroy eelgrass beds and restrict their recovery.     

Confronting coastal morphodynamics with counter-erosion engineering: the emblematic case of Wissant Bay,Dover Strait

Wissant Bay is a picturesque and highly frequented French coastal resort comprising beaches, dunes, marshes, and bold capes facing the Dover Strait. Situated at the southern approaches to the North Sea, the 8 km-long bay has, arguably, the most rapidly eroding shoreline in metropolitan France. Retreat has largely affected much of the bay shoreline west of Wissant town, with parts of this sector having lost up to 250 m in the last 50 years, whereas a much smaller sector east of the town is a zone of accretion. Various dune, beach and nearshore morphodynamic studies conducted over the last decade have identified chronic sand bleeding from the western sector and longshore transport to the east, within a framework of what appears to be an ongoing shoreline rotation process within a dominant longshore sediment transport cell between the headland of Cape Gris Nez to the west and the bold chalk cliffs of Cape Blanc Nez to the east. Retreat of the narrowing beach-dune barrier poses a threat in the coming years, as there is a likelihood of it being breached by storms. The seawall protecting Wissant town has also been repeatedly damaged since 2000 due to the chronic sand deficit. These changes involve interactions between a nearshore sand bank, a complex macrotidal beach comprising multiple subtidal to intertidal bars and troughs subject to strong longshore sand transport especially during storms, and aeolian dunes. The nearshore bank acts as a dissipater of incident storm wave energy and as a sand source for the multi-barred beaches and dunes, and has been strongly impacted by past massive aggregate extraction. The bank is, in turn, part of a larger system of mobile banks reworked by storms and tidal currents within the framework of a sand circulation system between the eastern English Channel and the southern North Sea. The aim of this work is to confront knowledge acquired on the morphodynamics of the bay with an engineering plan proposed to counter erosion and reestablish shoreline stability. The plan is based essentially on the creation of an ‘equilibrium’ beach profile, capable of withstanding storms, comprising an enlarged upper beach berm, and constructed through beach nourishment from a nearshore source located 20 km east of Wissant Bay. The plan has not been implemented because of cost. Even if it were to be implemented, its efficiency seems very doubtful because the beach profile simulations on which it is based neglect the complex multi-barred morphology and the overwhelming dominant longshore transport over bars during storms. The plan is also geared towards resolving a local problem of erosion that is embedded in the larger and rather complex spatiotemporal morphodynamics and sediment transport mechanisms evoked above. Wissant Bay is emblematic of the problems of erosion facing many communes in France, and elsewhere. The fight against shoreline erosion generally starts with the commonly insurmountable hurdle of fund-raising for costly engineering proposals that are not always based on a clear grasp of the embedded scales of change affecting the coast.     

Hele-Shaw beach creation by breaking waves: a mathematics-inspired experiment

Fundamentals of nonlinear wave-particle interactions are studied experimentally in a Hele-Shaw configuration with wave breaking and a dynamic bed. To design this configuration, we determine, mathematically, the gap width which allows inertial flows to survive the viscous damping due to the side walls. Damped wave sloshing experiments compared with simulations confirm that width-averaged potential-flow models with linear momentum damping are adequately capturing the large scale nonlinear wave motion. Subsequently, we show that the four types of wave breaking observed at real-world beaches also emerge on Hele-Shaw laboratory beaches, albeit in idealized forms. Finally, an experimental parameter study is undertaken to quantify the formation of quasi-steady beach morphologies due to nonlinear, breaking waves: berm or dune, beach and bar formation are all classified. Our research reveals that the Hele-Shaw beach configuration allows a wealth of experimental and modelling extensions, including benchmarking of forecast models used in the coastal engineering practice, especially for shingle beaches.     

Temporal, spatial, and between-host comparisons of patterns of parasitism in lake zooplankton

In nature, multiple parasite species infect multiple host species and are influenced by processes operating across different spatial and temporal scales. Data sets incorporating these complexities offer exciting opportunities to examine factors that shape epidemics. We present a method using generalized linear mixed models in a multilevel modeling framework to analyze patterns of variances and correlations in binomially distributed prevalence data. We then apply it to a multi-lake, multiyear data set involving two Daphnia host species and nine microparasite species. We found that the largest source of variation in parasite prevalence was the species identities of host-parasite pairs, indicating strong host-parasite specificity. Within host-parasite combinations, spatial variation (among lakes) exceeded interannual variation. This suggests that factors promoting differences among lakes (e.g., habitat characteristics and species interactions) better explain variation in peak infection prevalence in our data set than factors driving differences among years (e.g., climate). Prevalences of parasites in D. dentifera were more positively correlated than those for D. pulicaria, suggesting that similar factors influenced epidemic size among parasites in D. dentifera. Overall, this study demonstrates a method for parsing patterns of variation and covariation in infection prevalence data, providing greater insight into the relative importance of different underlying drivers of parasitism.     

Facilitating biodiversity conservation through partnerships to achieve transformative outcomes

Conservation biology is a mission-driven discipline that must navigate a new relationship between conservation and science. Because conservation is a social and political as well as an ecological project, conservation biologists must practice interdisciplinarity and collaboration. In a comparative study of 7 cases (Jaguars in the Chaco, Grevy's zebra in Kenya, Beekeeping in Tanzania, Andean cats in Argentina, Jaguars in Mexico, Lobster fishing, and Black bears in Mexico), we examined motivations for collaboration in conservation, who can collaborate in conservation, and how conservation professionals can work well together. In 5 case studies, successful conservation outcomes were prioritized over livelihood benefits. In the other 2 cases, livelihoods were prioritized. All case studies employed participatory approaches. There were multiple external actors, including local and Indigenous communities, nongovernmental organizations, agencies, regional and national governments, and international organizations, which enhanced conservation and wider sustainability outcomes. Key collaboration aspects considered across the case studies were time (mismatch between relationship building and project schedules), trust required for meaningful partnerships, tools employed, and transformative potential for people, nature, and the discipline of conservation biology. We developed guidelines for successful collaboration, including long-term commitment, knowledge integration, multiscalar and plural approaches, cultivation of trust, appropriate engagement, evaluation, supporting students, and efforts for transformation.