Base-neutral extractable organic pollutants in biota and sediments from Lake Pontchartrain

A study was conducted to screen the three passes that link Lake Pontchartrain to the Gulf of Mexico via Lake Borne for the presence of EPA base-neutral (BN) priority pollutants and any other pollutants detected in significant concentration. Biota and sediment samples were collected and analytical procedures were developed for the trace analysis of BN organics in these matrices. Compounds identified include alkanes (normal, branched, cyclic), alkenes, aromatics, alkylated aromatics, polynuclear aromatic hydrocarbons and their alkylated derivatives, phthalates, ketones, furans, thiophenes, phenols, amines, nitriles, thiazoles, amides, aldehydes, alcohols, free fatty acids, fatty acid methyl and ethyl esters, phosphates, sterols. Concentrations were in the parts-per-billion range.     

Discussion of Chicgoua Noubactep on “Removal of thiobencarb in aqueous solution by zero valent iron” by Md. Nurul Amin et al. [Chemosphere 70 (3) (2008) 511–515]

The following comments are proposed to clarify some related issues on the use of zero valent iron micrometric particles for the treatment of a thiobencarb pesticide solution published in a recent article by Nurul Amin et al., [Nurul Amin Md., Kaneco, S., Kato, T., Katsumata, H., Susuki, T., Otha, K., 2008. Removal of thiobencarb in aqueous solution by zero valent iron. Chemosphere 70 (3), 511–515], and discussed later by Chicgoua Noubactep.     

Environmental impacts of residual Municipal Solid Waste incineration: A comparison of 110 French incinerators using a life cycle approach

Incineration is the main option for residual Municipal Solid Waste treatment in France. This study compares the environmental performances of 110 French incinerators (i.e. 85% of the total number of plants currently in activity in France) in a Life Cycle Assessment perspective, considering 5 non-toxic impact categories: climate change, photochemical oxidant formation, particulate matter formation, terrestrial acidification and marine eutrophication. Mean, median and lower/upper impact potentials are determined considering the incineration of 1 tonne of French residual Municipal Solid Waste. The results highlight the relatively large variability of the impact potentials as a function of the plant technical performances. In particular, the climate change impact potential of the incineration of 1 tonne of waste ranges from a benefit of ?58 kg CO₂-eq to a relatively large burden of 408 kg CO₂-eq, with 294 kg CO₂-eq as the average impact. Two main plant-specific parameters drive the impact potentials regarding the 5 non-toxic impact categories under study: the energy recovery and delivery rate and the NO_x process-specific emissions. The variability of the impact potentials as a function of incinerator characteristics therefore calls for the use of site-specific data when required by the LCA goal and scope definition phase, in particular when the study focuses on a specific incinerator or on a local waste management plan, and when these data are available.     

Sorption of Isoproturon and Dimetomorph on lignocellulose from wheat

The adsorption of toxic chemicals on solid substates is a potential means to clean polluted waters. Here, the adsorption of two pesticides, isoproturon and dimetomorph, on lignocellulose extracted from wheat straw is investigated at 20 °C using batch adsorption experiments. Here, we show that the sorption of both pesticides is independent of pH. The sorption capacity of lignocellulose is evaluated. We show that the presence of metallic cations has no influence on the retention capacity of lignocellulose towards pesticides.     

Remediation of s-triazines contaminated water in a laboratory scale apparatus using zero-valent iron powder

Atrazine, propazine and simazine were tested separately and in mixture by batch procedure in a laboratory-constructed apparatus. 3.75 l of a buffered s-triazines pesticide solution was treated at room temperature by 325-mesh zero-valent iron powder (ZVIP) (20 g/l). High performance liquid chromatography was used to separate by-products and study the decline in the pesticide’s concentrations. Results obtained show that the order of degradation was simazine, atrazine and then propazine. The half-lives (t_1/2) of the s-triazines pesticides are, respectively, 7.4, 9.0 and 10.6 min when they are treated separately, and 9.8, 11.2 and 13.7 min when they are treated together under the same conditions. The final by-product obtained after 50 min of contact of simazine with ZVIP shows a shift to longer wavelength in its UV spectrum. A similar phenomenon is shown for atrazine and propazine. Identical primary by-products are produced and subsequently degraded to 4,6-(diamino)-s-triazine, which seems to be the major by-product of the reductive treatment process. Pathways for the degradation of the studied s-triazines by ZVIP are proposed.     

Kinetic study of phytotoxicity induced by foliar lead uptake for vegetables exposed to fine particles and implications for sustainable urban agriculture

At the global scale, foliar metal transfer occurs for consumed vegetables cultivated in numerous urban or industrial areas with a polluted atmosphere. However, the kinetics of metal uptake, translocation and involved phytotoxicity was never jointly studied with vegetables exposed to micronic and sub-micronic particles (PM). Different leafy vegetables (lettuces and cabbages) cultivated in RHIZOtest® devices were, therefore, exposed in a greenhouse for 5, 10 and 15 days to various PbO PM doses. The kinetics of transfer and phytotoxicity was assessed in relation to lead concentration and exposure duration. A significant Pb accumulation in leaves (up to 7392 mg/kg dry weight (DW) in lettuce) with translocation to roots was observed. Lead foliar exposure resulted in significant phytotoxicity, lipid composition change, a decrease of plant shoot growth (up to 68.2% in lettuce) and net photosynthesis (up to 58% in lettuce). The phytotoxicity results indicated plant adaptation to Pb and a higher sensitivity of lettuce in comparison with cabbage. Air quality needs, therefore, to be considered for the health and quality of vegetables grown in polluted areas, such as certain megacities (in China, Pakistan, Europe, etc.) and furthermore, to assess the health risks associated with their consumption.