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51.
Drybeans (Phaseolus vulgaris L.) are an important subsistence crop in Central America. Future climate change may threaten drybean production and jeopardize smallholder farmers’ food security. We estimated yield changes in drybeans due to changing climate in these countries using downscaled data from global circulation models (GCMs) in El Salvador, Guatemala, Honduras, and Nicaragua. We generated daily weather data, which we used in the Decision Support System for Agrotechnology Transfer (DSSAT) drybean submodel. We compared different cultivars, soils, and fertilizer options in three planting seasons. We analyzed the simulated yields to spatially classify high-impact spots of climate change across the four countries. The results show a corridor of reduced yields from Lake Nicaragua to central Honduras (10–38 % decrease). Yields increased in the Guatemalan highlands, towards the Atlantic coast, and in southern Nicaragua (10–41 % increase). Some farmers will be able to adapt to climate change, but others will have to change crops, which will require external support. Research institutions will need to devise technologies that allow farmers to adapt and provide policy makers with feasible strategies to implement them.  相似文献   
52.
The southeastern United States supports one of two large loggerhead turtle (Caretta caretta) nesting aggregations worldwide and is therefore critical to global conservation and recovery efforts for the species. Previous studies have established the presence of four demographically distinct nesting populations (management units) corresponding to beaches from (1) North Carolina through northeastern Florida, (2) peninsular Florida, (3) the Dry Tortugas, and (4) northwest Florida. Temporal and geographic genetic structure of the nesting aggregation was examined utilizing partial mitochondrial control region haplotype frequencies from 834 samples collected over the 2002 through 2008 nesting seasons from 19 beaches as well as previously published haplotype data. Most rookeries did not exhibit interannual genetic variation. However, the interannual variation detected did significantly impact the interpretation of spatial genetic structure in northeastern Florida. Based on pairwise F ST comparisons, exact tests of population differentiation, and analysis of molecular variance, the present study upholds the distinctiveness of the four currently recognized management units and further supports recognition of discrete central eastern, southern (southeastern and southwestern), and central western Florida management units. Further subdivision may be warranted, but more intensive genetic sampling is required. In addition, tools such as telemetry and mark-recapture are needed to complement genetic data and overcome limitations of genetic markers in resolving loggerhead turtle rookery connectivity in the southeastern USA.  相似文献   
53.
The field of environmental risk management is relatively new and has developed rapidly over the past several years. There has been, however, a significant lack of integration of seemingly dissimilar disciplines into a meaningful context for top management risk decisions—until now. A new holistic approach, centered on the ISO 14001 standard for environmental management systems, addresses many of the issues that have kept environmental risk management focused on technical rather than strategic issues. This article describes the risk management process, illustrates how the ISO 14001 standard can be used by organizations to integrate and assess technical environmental information, and shows how to place this information in a strategic risk management context. It also explains how key ISO 14001 concepts such as policy implementation, operational control, and continuous improvement form the basis of a systems approach, and why the systems approach is the preferred, cost-effective structure for controlling environmental risk.  相似文献   
54.
Fermentation of biomass residues and second generation biomasses is potentially a way to enable a sustainable production of hydrogen. Simulation models which calculate mass and energy balances, developed with Aspen Plus®, are used to integrate the process steps necessary to produce pure hydrogen from biomass in a 2-stage fermentation process. Process and heat integration are introduced to reduce the high water and heat demand of the process, connected to the low substrate concentrations in the involved process streams. The results show that the recirculation of process effluents, together with the use of properly designed heat exchangers, can reduce the water and heat demand up to 90% from a non-integrated process, but is also subject to restrictions due to an increase in osmolality in the system.  相似文献   
55.
In this paper, a process for the fermentative production of hydrogen is analysed with respect to its exergy efficiency. Parametric studies show the influence of used feedstock, applied process parameters as well as process and heat integration measures on exergy efficiency. It is shown that heat integration and recirculation of fermentor effluents reduce process irreversibilites and the amount of exergy leaving the process in waste streams. Nevertheless, depending on the used feedstock, a large amount of exergy leaves the process via by-products. Internal use of by-products and waste materials for providing process heat could increase chemical exergy efficiency up to 74%.  相似文献   
56.
We have performed the photolysis of 2‐methyloxy‐, 2‐ethyloxy‐, 2‐propyloxy‐, 2‐isopropyloxy‐, 2‐(l‐methylbutyl)oxy‐, 2‐cyclohexyloxy‐ and 2‐propargyloxybenzothiazole derivatives. We have studied the influence of polarity of the solvent and presence or absence of oxygen on the course of their photochemical transformations. In general it can be concluded that the cleavage of the substituent‐oxygen bonds occurs preferentially, whereby the main product was identified in most cases to be 2‐benzothiazolinone. The rate of photolysis and the composition of the reaction mixture was dependent upon the presence or absence of oxygen. Photoreactivity of above benzo‐thiazole derivatives was also strongly dependent on the structure of the substituents in the position 2.  相似文献   
57.
Objective: The objective of our study was to determine the prevalence of alcohol and drug intoxication among fatally injured motorcyclists in a wide urban area of Zagreb, Croatia.

Methods: We conducted a single-center observational retrospective study over a 10-year period (2007–2016) in 3 counties covering an area including 1.2 million residents. We reviewed the records on fatally injured motorcyclists, collecting information relating to sex, age, cause of death, time of death in relation to the time of the crash, and the circumstances of the crash (time of day, day of the week, season). Blood alcohol concentration (BAC) and toxicology analysis results were collected and analyzed.

Results: We identified 163 deaths (95.7% males, 4.3% females). Overall, 64.2% of the victims were 20 to 39 years old. The majority (50.9%) of those fatally injured were responsible for causing the traffic crash; the rest were determined not to be responsible or the responsibility could not be determined. The most frequent causes of death were multiple injuries (55.8%) and isolated head trauma (23.3%). The rider’s BAC was above the legal limit for driving (>0.50?g/kg) in 53.8% of cases, with a mean BAC of 1.91?g/kg. There was no difference in riding a motorcycle with a BAC above the legal limit between groups defined as younger (≤39 years of age) and older (≥40 years of age). The number of people with an illegal BAC was significantly higher during weekends than during the work week. The BAC of riders who were responsible for the crash was significantly higher than that of those who were not responsible or whose responsibility could not be determined. Use of illegal drugs or nontherapeutic use of legal drugs was not common and was detected in 10.4% of fatally injured riders.

Conclusions: Alcohol intoxication has a major role in motorcycle crash–related mortality. A significant difference in BAC between fatally injured riders responsible for the accident and those who were not responsible implies that measures directed toward prevention of drinking and driving behavior could lower the number of fatal motorcycle crashes. Weekend measures, especially during spring and summer, could have particularly significant effects.  相似文献   
58.
Oxygen and carbon stable isotope profiles were constructed for two species of large subtropical gastropods of the family Fasciolariidae—Triplofusus giganteus and Fasciolaria tulipa—from the Florida Keys and the Bahamas, to evaluate their life history and to assess their potential as paleoenvironmental proxies. Oxygen isotope profiles revealed T. giganteus and F. tulipa grew their shells for 6 and 3 years, respectively. Both mollusks show faster growth rates during the first half of their lifespan. Mean annual temperatures (MAT) derived from oxygen isotopes for T. giganteus were 26.5 °C and for F. tulipa were 26.7 °C, both matching instrumental MATs of 26.7 and 26.5 °C for the Florida Keys. Both shells, however, failed to record entire mean annual temperature ranges (MART). Fasciolaria tulipa yielded a calculated MART of 5.6 °C compared with a measured MART of 9.3 °C, and T. giganteus showed a calculated MART of 6.9 °C compared with a measured MART of 9.4 °C. Carbon isotopes of T. giganteus were ambiguous and reveal no significant relationships with trends in nutrient concentrations (N and P), dissolved oxygen, and dissolved organic carbon, although they did exhibit more negative values concomitant with landfall of Hurricane Irene and trended to increasing values with ontogeny that could reflect migration. Carbon isotopes in F. tulipa were lower during winters, possibly reflecting seasonal upwelling or seagrass-mediated carbon cycling.  相似文献   
59.
Originally developed within the Mediterranean, a tested coastal management and planning tool was applied outside the region to evaluate its international scope, with particular reference to a less developed country. Seven coastal sites in Pakistan were investigated for their scenic values through a 26 item checklist grouped as physical and human parameters analysed though weighted parameters and fuzzy logic matrices. With respect to a five-class evaluation system, results indicated: Jiwani, Miani Hor and Pasni-Astola Island as extremely attractive natural sites with very high landscape value (classified as Class 1 sites); Mubarak village as an attractive natural site with high landscape value (classified as a Class 2 site); Kaka pir village, Harjana village and Keti Bandar as having little outstanding landscape features or with urban environment and classified as Class 3 sites. Rural and/or urban environmental influences were observed to be critical factors which influenced major human parameters that ultimately affect sites’ scenic classification. However, notwithstanding natural attraction, unless political and social development barriers are tackled in conjunction with recognising areas that possess inherent tourism potential, economic potential is unlikely to be realised.  相似文献   
60.
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