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31.
Congregado Emilio Feria-Gallardo Julia Golpe Antonio A. Iglesias Jesús 《Environmental science and pollution research international》2016,23(18):18407-18420
Environmental Science and Pollution Research - In this paper, we analyze the existence of the environmental Kuznets curve as reported by Kuznets (Am Econ Rev 5:1–28, 1955) by using the... 相似文献
32.
33.
Lara-Ramos Jose Antonio Constain-Escobar Angela María Rojas-Ortiz Karen Vanessa Diaz-Angulo Jennyfer Machuca-Martínez Fiderman 《Environmental science and pollution research international》2021,28(19):24079-24091
Environmental Science and Pollution Research - This work proposes a novel approach for the coupling of ozonation and Fenton processes using a new prototype of a high rotation bubble reactor (HRBR),... 相似文献
34.
Valverde A Piedra L Aguilera A Boulaid M Camacho F 《Journal of environmental science and health. Part. B》2007,42(7):801-807
This paper describes the application of liquid chromatography-tandem mass spectrometry (LC/MS-MS) for analysis of residues of forchlorfenuron (CPPU), a new plant growth regulator, in watermelons, after a sample preparation step based on the buffered Quick, Easy, Cheap, Effective, Rugged and Safe extraction method. Analytical determinations were carried out in a triple quadrupole system fitted with an electrospray interphase operating in the positive ionisation mode (ESI+). Three simultaneous MS-MS transitions of the quasi-molecular ion m/z 248 (precursor ion) were monitored for data acquisition (248 > 129, 248 > 155, and 248 > 248), using the transition 248 > 129 for quantitation. Recovery studies on watermelons at levels of 1-200 microg/kg, performing five replicates at each level and using bracketing single-level calibration with matrix-matched standards for quantitation, gave forchlorfenuron mean recoveries ranging from 82 to 106% with relative standard deviations (RSD) lower than 18%. The limit of determination was established at 1 microg/kg. The method was applied to evaluate the persistence of forchlorfenuron residues in watermelons grown in plastic greenhouses, after applying an individual spray treatment to the flower ovary at the anthesis stage (45 mu g/flower and 60 mu g/flower for cv "Extazy" and cv "reina de corazones" watermelons, respectively). One month after treatment, 20 "Extazy" watermelon units (1.5-2 kg/unit) and 20 "Reina de corazones" watermelon units (4-5 kg/unit) were collected and analyzed individually. None of the samples contained forchlorfenuron residues higher than 1 microg/kg. 相似文献
35.
The polychlorinated biphenyls (PCBs) and DDT may bioaccumulate in the aquatic food web and have been of great concern due to their toxic effects on wildlife and human health. There is evidence showing that fish in the human diet contributes at a significant proportion to the total intake of PCBs and other organochlorine compounds, particularly fish with higher fat levels. This study investigated the concentration of PCBs and DDTs in muscle tissues of samples of the blue shark (Prionace glauca) and a swordfish (Xiphias gladius) from east Brazilian coast and estimate the human exposure to total DDTs through the consumption of both the species. Samples of the each species were caught between August and September 2001. The mean concentration for summation operator PCBs in P. glauca was 3.15 ng/g w.w. and the summation operator DDTs was 0.93 ng/g w.w. The mean concentration of summation operator PCBs in X. gladius was 6.50 ng/g and the mean of summation operator DDTs was 2.47 ng/g. The estimated daily intake of summation operator DDT through X. gladius or P. glauca consumption can be considered safe since it contributes to less than 0.1% of the limit of acceptable daily intake (ADI) of summation operator DDT proposed by WHO. 相似文献
36.
This work investigated the degradation of a natural estrogen (17beta-estradiol) and the removal of estrogenic activity by the ozonation process in three different pHs (3, 7 and 11). A recombinant yeast assay (YES assay) was employed to determine estrogenic activity of the ozonized samples and of the by-products formed during the ozonation. Ozonation was very efficient for the removal of 17beta-estradiol in aqueous solutions. High removals (>99%) were achieved with low ozone dosages in the three different pHs. Several by-products were formed during the ozonation of 17beta-estradiol. However, only a few compounds could be identified and confirmed. Different by-products are formed at different pHs, which is probably due to different chemical pathways and different oxidants (O(3) and OH radical). The by-products formed at pH 11 were 10epsilon-17beta-dihydroxy-1, 4-estradieno-3-one (DEO) and 2-hydroxyestradiol, which were not formed in pH 3. Only testosterone could be observed in pH 3, whereas at pH 7 all three by-products were found. At pH 7 and 11 the applied ozone dosages were not enough to remove all the estrogenicity from samples, even though the 17beta-estradiol residual concentration for these two pHs was lower than at pH 3. Higher estrogenicity was detected at pH 11. An explanation to this fact may be that oxidation via OH radical forms more by-products with estrogenic activity. Probably, the formation of 2-hydroxyestradiol at pHs 7 and 11 is contributing to the residual estrogenicity of samples ozonized at these pHs. In this work, complete removal of estrogenic activity was only obtained at pH 3. 相似文献
37.
Soil pollution with Cd is an environmental problem common in the world, and it is necessary to establish what Cd concentrations
in soil could be dangerous to its fertility from toxicity effects and the risk of transference of this element to plants and
other organisms of the food chain. In this study, we assessed Cd toxicity on soil microorganisms and plants in two semiarid
soils (uncultivated and cultivated). Soil ATP content, dehydrogenase activity, and plant growth were measured in the two soils
spiked with concentrations ranging from 3 to 8000 mg Cd/kg soil and incubated for 3 h, 20 days, and 60 days. The Cd concentrations
that produced 5%; 10%;, and 50%; inhibition of each of the two soil microbiological parameter studied (ecological dose, ED,
values) were calculated using two different mathematical models. Also, the effect of Cd concentration on plant growth of ryegrass
(Lolium perenne, L.) was studied in the two soils. The Cd ED values calculated for soil dehydrogenase activity and ATP content were higher
in the agricultural soils than in the bare soil. For ATP inhibition, higher ED values were calculated than for dehydrogenase
activity inhibition. The average yields of ryegrass were reduced from 5.03 to 3.56 g in abandoned soil and from 4.21 to 1.15
g in agricultural soil with increasing concentrations of Cd in the soil. Plant growth was totally inhibited in abandoned and
agricultural soils at Cd concentrations above 2000 and 5000 mg/kg soil, respectively. There was a positive correlation between
the concentration of Cd in the plants and the total or DTPA-extractable concentrations of Cd in the soil. 相似文献
38.
Tiago Francisco de Camargo Antonio Zanin Sady Mazzioni Geovanne Dias de Moura Paulo Sérgio Lima Pereira Afonso 《Environment, Development and Sustainability》2018,20(1):65-81
In recent decades, there has been a growing concern about measuring and evaluating the results of intensive production practices, such as the mode of integration practiced on a large scale by agro-industries. The present study discusses the application and the results of a Sustainability Indicators System in the context of the swine industry in the Brazilian State of Santa Catarina. These indicators, focused on the level of sustainability maturity, can be used as a way to diagnose and compare the efficiency of the industry from a broader perspective. The research findings indicate that most of the pig farms that have been studied can be classified as “in search of sustainability or sustainable.” Nevertheless, there are differences among the dimensions and between the most ranked farms and the others which must be considered for a better design and application of public policies and company strategies toward an effective and balanced social, economic and environmental sustainability. 相似文献
39.
Cristina Barazzetti Barbieri Jorge Eduardo Souza Sarkis Luiz Antonio Martinelli Isabella C. A. C. Bordon Horst Mitteregger Jr. Marcos Antônio Hortellani 《Environmental Forensics》2014,15(2):134-146
A forensic approach was used to evaluate sediments from Portão Stream, including analysis of metals, carbon (C) and nitrogen (N) stable isotopes, and C:N ratios. Samples collected at various points located along the stream were tested in order to investigate a possible illegal leachate input. The studied stream is heavily impacted by sewage and industrial discharges from two cities along its course. Among the metals analyzed, chromium (Cr) was noticeably the main pollutant, showing the highest levels, above regulatory limits, downstream from some potential sources of effluents enriched with this metal. Isotope analyses revealed a general trend of depletion in the heavier isotope along the stream for C and N. The exception was one point near a hazardous waste landfill, where relatively more enriched δ13C and δ15N values were found. The isotope and metal analysis results indicated that this site was affected by a particular source, demonstrating the combination of these parameters could be used for the discrimination of sources in a heavily polluted stream. Nevertheless, further investigations are necessary to provide a comprehensive evaluation of the biogeochemical processes involved in the incorporation of leachate in sediments to use this analysis as evidence for the illegal leachate discharge. 相似文献
40.
Flavia Tromboni Lucia Bortolini José Antonio Morábito 《Environment, Development and Sustainability》2014,16(6):1317-1336
This study presents an integrated hydrologic–economic model as decision support system for groundwater use and incorporates uncertainties of climate change. The model was developed with the Vensim software (Ventana Systems) for system dynamic simulations. The software permitted the integration of economic variables along with hydrologic variables, in a unified format with the aim of evaluating the economic impacts of climate change on arid environments. To test the model, we applied it in one of the upper Tunuyán River sub-basin, located in the Mendoza Province (Argentina), where irrigation comes from groundwater. The model defines the best mix of crops and the total land use required to maximize the total river sub-basin monetary income, considering as a limit the amount of water that does not exceed the natural annual aquifer recharge. To estimate the impacts of climatic changes, four scenarios were compared: the business as usual (with the number of existing wells) in a dry year with a temperature increase of 4 °C; the business as usual in a wet year with an increase in temperature of 1.1 °C; an efficient use of wells in a dry year and a temperature increase of 4 °C and an efficient use of wells in a wet year with a temperature increase of 1.1 °C. Outputs calculated by the model were: land use per crop, total sub-basin net benefit, total sub-basin water extraction, water extraction limit depending on river discharge and total number of wells required to irrigate the entire area. Preliminary results showed that the number of existing wells exceeded the optimized number of wells required to sustainably irrigate the entire river sub-basin. Results indicated that in an average river discharge year, if wells were efficiently used, further rural development would be possible, until the limit of 350 million m3 of water extraction per year was reached (650 million m3 for a wet year and 180 million m3 for a dry year). The unified format and the low cost of the software license make the model a useful tool for Water Resources Management Institutions, particularly in developing countries. 相似文献