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41.
Intrageneric differences in the four stereoisomers of stenusine in the rove beetle genus, Stenus (Coleoptera, Staphylinidae) 总被引:1,自引:1,他引:0
Lusebrink I Burkhardt D Gedig T Dettner K Mosandl A Seifert K 《Die Naturwissenschaften》2007,94(2):143-147
Most species of the rove beetle genus Stenus employ the spreading alkaloid stenusine as an escape mechanism on water surfaces. In the case of danger, they emit stenusine
from their pygidial glands, and it propels them over the water very quickly. Stenusine is a chiral molecule with four stereoisomers:
(2′R,3R)-, (2′S,3R)-, (2′S,3S)-, and (2′R,3S)-stenusine. The percentile ratio of these four isomers is only known for the most common species of the genus: Stenus comma. With the intention of determining the stereoisomer ratios of five additional species from the two subgenera, Stenus and Hypostenus, we used GC/mass spectrometry measurements with a chiral phase. The results showed that the ratio differs among the genus. These findings can be a basis for chemotaxonomy. It is also possible
that the biological function of stenusine, e.g., as antibiotic or fungicide, varies with changing stereoisomer composition.
相似文献
Inka LusebrinkEmail: |
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Armin Scholz 《Die Naturwissenschaften》1960,47(20):465-465
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Dietmar Glindemann Ulrich Stottmeister Armin Bergmann 《Environmental science and pollution research international》1996,3(1):17-19
The possible liberation of highly toxic and mutagenic phosphine from putrefying media raises the question of its significance as a problem of hygiene. Free phosphine was established by gas chromatography as a universal trace component in gas emitted from the anaerobic biosphere. Sources of phosphine include landfills, compost processing, sewage sludge, animal slurry and river sediments. We detected maximum concentrations in the order of 20 ppb(v/v). 相似文献
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Armin Weiß 《Environmental science and pollution research international》1996,3(2):112-114
Atmospheric mixing ratios of chlorinated C1 and C2 hydrocarbons (CHCs) were measured at the mountain Wank (Garmisch-Partenkirchen, Bavarian Alps) in autumn 1992. The data lead to the assumption that at least part of the observed CC14 originates from a source different to the other CHCs measured (C2HCL3, C2C14, CHCl3 and CH3CCl3). The nature of this source is discussed. 相似文献
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Hawes AK Solomon S Portmann RW Daniel JS Langford AO Miller HL Eubank CS Goldan P Wiedinmyer C Atlas E Hansel A Wisthaler A 《Journal of environmental monitoring : JEM》2003,5(6):977-983
Measuring hydrocarbons from aircraft represents one way to infer biogenic emissions at the surface. The focus of this paper is to show that complementary remote sensing information can be provided by optical measurements of a vegetation index, which is readily measured with high temporal coverage using reflectance data. We examine the similarities between the vegetation index and in situ measurements of the chemicals isoprene, methacrolein, and alpha-pinene to estimate whether the temporal behavior of the in situ measurements of these chemicals could be better understood by the addition of the vegetation index. Data were compared for flights conducted around Houston in August and September 2000. The three independent sets of chemical measurements examined correspond reasonably well with the vegetation index curves for the majority of flight days. While low values of the vegetation index always correspond to low values of the in situ chemical measurements, high values of the index correspond to both high and low values of the chemical measurements. In this sense it represents an upper limit when compared with in situ data (assuming the calibration constant is adequately chosen). This result suggests that while the vegetation index cannot represent a purely predictive quantity for the in situ measurements, it represents a complementary measurement that can be useful in understanding comparisons of various in situ observations, particularly when these observations occur with relatively low temporal frequency. In situ isoprene measurements and the vegetation index were also compared to an isoprene emission inventory to provide additional insight on broad issues relating to the use of vegetation indices in emission database development. 相似文献
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