Magnitude of anthropogenic phosphorus storage in the agricultural production and the waste management systems at the regional and country scales

Based on a systematic review of 17 recent substance flow analyses of phosphorus (P) at the regional and country scales, this study presents an assessment of the magnitude of anthropogenic P storage in the agricultural production and the waste management systems to identify the potential for minimizing unnecessary P storage to reduce the input of P as mineral fertilizer and the loss of P. The assessment indicates that in case of all (6) P flow analyses at the regional scale, the combined mass of annual P storage in the agricultural production and the waste management systems is greater than 50 % of the mass of annual P inflow as mineral fertilizer in the agricultural production system, while this is close to or more than 100 % in case of half of these analyses. At the country scale, in case of the majority (7 out of 11) of analyses, the combined mass of annual P storage in the agricultural production and the waste management systems has been found to be roughly equivalent or greater than 100 % of the mass of annual P inflow as mineral fertilizer in the agricultural production system, while it ranged from 30 to 60 % in the remaining analyses. A simple scenario analysis has revealed that the annual storage of P in this manner over 100 years could result in the accumulation of a massive amount of P in the agricultural production and the waste management systems at both the regional and country scales. This study suggests that sustainable P management initiatives at the regional and country scales should put more emphasis on minimizing unwanted P storage in the agricultural production and the waste management systems.     

Social constraints before sanitation improvement in tea gardens of Sylhet, Bangladesh

Sylhet, the northeastern divisional city of Bangladesh, is the major tea-producing region of the country where a large number of low-income workers completely depending on extremely labor-intensive economic activity for their bread and butter, live in and around the tea gardens. The living conditions of these communities are remarkably meager due to the lack of proper utility facilities, especially in water supply and sanitation sectors. A study was conducted at Lakkatura and Ali Bahar Tea Estates to assess the deteriorated sanitation condition of the tea garden workers community and to determine the constraints before the improvement of the condition. It was found that the existing sanitary condition of both of the tea garden slums is very poor because of the same topographical condition and socioeconomic and cultural status of the dwellers. About 50% to 60% tea garden workers still are used to open defecation causing various excreta related diseases and not practiced with washing hand after defecation. Lack of knowledge and awareness about health and hygiene, unwillingness, poverty, superstitions, etc. are responsible for the deteriorated condition of the sanitation system. Based on the analysis, providing latrines free of costs, undertaking extensive motivational and awareness programs and publicity, regular consultation of tea garden workers with the health specialists, and vector control staff of concerned utilities as well as an integrated water supply, sanitation, and hygiene promotion programs should be considered as the priority in order to improve the deteriorated sanitary conditions in two tea gardens.     

Fine particles and carbon monoxide from wood burning in 17th–19th century Danish kitchens: Measurements at two reconstructed farm houses at the Lejre Historical–Archaeological Experimental Center

Carbon monoxide (CO) and particulate matter (PM_2.5) were measured in two reconstructed Danish farmhouses (17–19th century) during two weeks of summer. During the first week intensive measurements were performed while test cooking fires were burned, during the second week the houses were monitored while occupied by guest families. A masonry hearth was located in the middle of each house for open cooking fires and with heating stoves. One house had a chimney leading to the outside over the hearth; in the other, a brickwork hood led the smoke into an attic and through holes in the roof. During the first week the concentration of PM_2.5 averaged daily between 138 and 1650 μg m^?3 inside the hearths and 21–160 μg m^?3 in adjacent living rooms. CO averaged daily between 0.21 and 1.9 ppm in living areas, and up to 12 ppm in the hearths. Highest concentrations were measured when two fires were lit at the same time, which would cause high personal exposure for someone working in the kitchens. 15 min averages of up to 25 400 μg m^?3 (PM_2.5) and 260 ppm CO were recorded. WHO air quality guidelines were occasionally exceeded for CO and constantly for PM_2.5. However, air exchange and air distribution measurements revealed a large draw in the chimney, which ensured a fast removal of wood smoke from the hearth area. The guest families were in average exposed to no more than 0.21 ppm CO during 48 h. Based on a hypothetical time-activity pattern, however, a woman living in this type of house during the 17–19th century would be exposed to daily averages of 1.1 ppm CO and 196 μg m^?3 PM_2.5, which exceeds WHO guideline for PM_2.5, and is comparable to what is today observed for women in rural areas of developing countries.     

Bacterial extracellular polymeric substance (EPS): a carrier of heavy metals in the marine food-chain

The ecological implications of metal binding properties of bacterial EPS and its possible role in the bioaccumulation of pollutants in the marine food-chain was investigated using a partially purified and chemically characterized microbial EPS isolated from a species of Marinobacter. Various factors influencing metal sorption by the EPS including the influence of initial metal concentrations, incubation time, pH and sodium chloride concentrations on binding of lead (Pb2+) and copper (Cu2+) were evaluated. The bacterial EPS selectively bound more amount of Cu2+ per mg of EPS than Pb2+. Both copper and lead were sorbed more at near neutral pH than acidic pH. The sorption of Cu2+ increased with increasing copper concentration. The estimated maximum binding ability (MBA) of the EPS was 182 nmol copper and 13 nmol lead mg(-1) EPS. However, the sorption of these metals decreased with the increase in sodium chloride concentration. Furthermore, up to 35% of 14C-labeled Marinobacter was ingested by a benthic polychaete Hediste diversicolor. On an average, 29% of the ingested EPS was absorbed into tissues and 49% of the EPS was respired. It was apparent that the animals used the EPS as a source of energy and nutrition. The labile nature of the bacterial EPS and its ability to bind heavy metals might route the bound metals through the marine food chain, thereby transferring and aiding bioaccumulation of metal pollutants in the higher trophic animals.     

Agricultural livelihood transition in the southern Yucatán region: diverging paths and their accompanying land changes

Land change science has demonstrated that rural livelihoods around the world both drive and reflect changing environmental regimes and political economic/structural transformations. This article explores the relationship between increasingly globalized rural livelihoods and in-place land change, assessing results from social surveys of smallholding households in the southern Yucatán region. We examine evidence for a transition in agricultural livelihood strategies as smallholders adjust to changing political economic and institutional conditions, and link these transitioning strategies to land use changes. Based on household surveys in 1997 and 2003, we comparatively assess both changes in the selection of livelihood strategies and in the land use and cover impacts of those strategies. Our results indicate that although impacts of given strategies have changed little over this period, there are increasing proportions of households pursuing two divergent adjustment paths—one of agricultural withdrawal and one of agricultural intensification and commercialization. We investigate what sociodemographic characteristics differentiate the groups of households following distinct livelihood strategies. Our findings point to the possibility of simultaneous and contradictory land change outcomes as smallholders adjust in different ways to their intensified incorporation into global economies.     

Identifying the source and accessing the spatial variations,contamination status,conservation threats of heavy metal pollution in the river waters of Sunderban biosphere reserve,India

This study emphasizes on identification of source and accessing the spatial variation of dissolved heavy metals (Cu, Cd, Fe, Ni, Pb and Zn) in the rivers of Sundarban Biosphere Reserve India, the UNESCO world heritage site. ANOVA (Analysis of Variance), PCA (Principal Component Analysis) as well as FA (Factor Analysis) are used for assessing the significant difference in means of metals concentration among the sites and understanding the sources of these pollutants. Three principal components with cumulative variance of 32, 55, and 73 %, show that Pb, Ni and Cd are closely associated with each other indicating an anthropogenic origin of these metals. Heavy metal evaluation index (HEI) values indicate that areas close to densely populated sites are affected by elevated metals concentration due to anthropogenic activities. The ratio between the concentration of Cd, Ni and Pb in sites and the maximum respective permissible limit for these metals for conserved habitat is Log₁₀ normalized to understand the threats of these pollutants over the distributaries of Sundarbans. Pb pollution is prevalent in the areas that rely on the fossil fuel-operated boats, for transport, whereas higher Cd concentration is found in the areas dependent on rechargeable batteries to meet their energy demand. So these anthropogenic activities and mal-practices may be responsible for the heavy metal pollution in this region. The study concludes that gradual increase in metal pollution in river water due to anthropogenic activities, particularly Pb and Cd, could have a negative impact on the conserved flora and fauna of this ecosystem.     

Probabilistic approach for health hazard assessment of trihalomethanes through successive showering events

Environmental Science and Pollution Research - Trihalomethanes (THMs) are common disinfection by-products in chlorinated tap waters. They can cause various cancers and non-cancer health hazards....     

Coastal and riverine ecosystems as adaptive flood defenses under a changing climate

Adaptation planning for flood risk forms a significant part of global climate change response. Engineering responses to higher water levels can be prohibitively costly. Several recent studies emphasize the potential role of ecosystems in flood protection as adaptive risk reduction measures while also contributing to carbon fixation. Here, we use a conceptual model study to illustrate the built-in adaptive capability of ecosystems to reduce a wide range of wave heights, occurring at different water levels, to a narrower range. Our model shows that wave height of waves running through a forested section is independent of initial height or of water level. Although the underlying phenomenon of non-linear wave attenuation within coastal vegetation is well studied, implications of reducing variability in wave heights for design of ecosystem and levee combinations have not yet been properly outlined. Narrowing the range of wave heights by a vegetation field generates an adaptive levee that is robust to a whole range of external conditions rather than only to a maximum wave height. This feature can substantially reduce costs for retrofitting of levees under changing future wave climates. Thereby, in wave prone areas, inclusion of ecosystems into flood defense schemes constitutes an adaptive and safe alternative to only hard engineered flood risk measures.     

Variability and predictability of sea-level extremes in the Hawaiian and U.S.-Trust Islands—a knowledge base for coastal hazards management

The objective of this study is to provide an improved climatology of sea level extremes on seasonal and long-term time scales for Hawaii and the U.S-Trust islands. Observations revealed that the Hawaiian and U.S.-Trust islands, by and large, display a strong annual cycle. For estimating the statistics of return period, the three-parameter generalized extreme value (GEV) distribution is fitted using the method of L-moments. In the context of extremes (20- to 100-year return periods), the deviations in most of the Hawaiian Islands (except at Nawiliwili and Hilo) displayed a moderate sea-level rise (i.e., close to 200 mm), but the deviations in the U.S.-Trust islands displayed a considerably higher rise (i.e., more than 300 mm) in some seasons due to typhoon-related storm surges. This rise may cause damage to roads, harbors, and unstable sandy beaches. Correlations between the El Niño-Southern Oscillation (ENSO) climate cycle and the variability of seasonal sea level have been investigated. Results show that correlation for the station located west of the International Date Line (DL) is strong, but it is moderate or even weaker for stations east of the DL. The skill of SST-based Canonical Correlation Analyses (CCA) forecasts was found to be weak to moderate (0.4–0.6 for Honolulu, Kahului, Hilo, and Wake, and 0.3 or below for Kahului, Mokuoloe, and Johnston). Finally, these findings are synthesized for evaluating the potential implications of sea level variability in these islands.     

Simulated use and wash-off release of decamethylcyclopentasiloxane used in anti-perspirants

The cyclic volatile methylsiloxane, decamethylcyclopentasiloxane (D₅) is used in a large variety of personal care products. Based on the physical–chemical properties of D₅, it is likely that losses due to volatilisation may strongly influence the levels entering the aquatic environment. The aim of this study was to quantify the amount of D₅ in waste wash water, after typical application and use in a range of deodorant and anti-perspirant (AP) products. Results implied significant losses after a 24 h period (>99.9%), and suggest that the use of D₅ in leave-on products, such as deodorants/AP is not likely to contribute a significant down-the-drain emission source. An illustrative example is presented, based on data reporting the use of D₅ in a range of personal care products (both wash-off and leave-on), which suggests that the contribution of D₅ used in wash-off products to the aquatic environment may be considerably more significant. Limitations associated with our understanding of the actual D₅ inclusion levels in the products, the market share of the products containing D₅, and the variability of consumer habits, are identified as data gaps that need to be addressed in order to better refine down-the-drain emission estimates.