Validation of QuEChERS method for the determination of 36 pesticide residues in fruits and vegetables from Ghana,using gas chromatography with electron capture and pulsed flame photometric detectors

In this study, “Quick, Easy, Cheap, Effective, Rugged and Safe” ‘QuEChERS’ method was modified for the determination of 36 pesticides fortified at (0.01–1.0) mg kg^?1 in three vegetables and a fruit (lettuce, carrot, tomatoes and pineapples respectively) from Ghana. The method involved extraction with acetonitrile, phase separation with primary secondary amine and magnesium sulfate; the final injection solution was reconstituted in ethyl acetate. Organochlorine and synthetic pyrethroids residues were detected with electron capture detector whereas organophosphorus, pulsed flame photometric detector was used. The recoveries at different concentration levels (0.01, 0.1 and 1.0 mg kg^?1) were in the range of 83% and 93% with relative standard deviation ranging from 2% to 10% (n = 5) and the coefficient of determination (R²) was greater than 0.99 for all the 36 pesticides. The method was successfully tested on 120 real samples from Accra markets and this proved to be useful for monitoring purposes particularly in laboratories that have no gas chromatography-mass spectrometry and liquid chromatography-mass spectrometry.     

Effect of silica additive on the thermal stability of catalysts for NOx abatement

The aim of the plesent investigation was to study the effect of SiO₂ addition on the thermal deactivation of V₂O₅/WO₃/TiO₂ catalysts used for NOx pollution abatement. The results suggest that the degradation of the catalytic properties is strongly correlated to the structural ageing which is, in turn, mainly related to the anatase–rutile phase transformation and to the WO₃ phase segregation. The addition of SiO₂ strongly influences the temperature at which these phenomena occur. In fact, it was found that the introduction of this oxide stabilizes the material, retarding the collapse of surface area, and increases the temperature of the anatase to rutile phase transition.     

Particle Size Distributions of Kraft Paper Mill Aerosols Obtained by Airborne Sampling

Size distributions of particles at several downwind points in a Kraft paper mill plume have been determined by means of airborne sampling. Size distributions from samples close to the stack were found to have a log normal frequency distribution, but significant deviations from the log normal were found farther downwind. Several possible physical mechanisms are postulated as causes for this behavior. Plume dilution with background particles appears to be the most likely mechanism. The airborne sampling system is described, and electron micrographs of sampled particles are presented.     

HYDROLOGIC ENGINEERING TECHNIQUES FOR REGIONAL WATER RESOURCES PLANNING1

The emphasis upon comprehensive regional water resources planning in the past decade has encouraged the hydrologic engineer to take advantage of improvements in technology to develop new hydrologic engineering techniques for use in regional planning studies. The new techniques are necessary because the traditional hydro-logic engineering techniques are not always consistent with the increased scope and diversified objectives of regional planning studies. The Hydrologic Engineering Center has been involved in aiding in the development of some of these new techniques as the result of studies that have been made in cooperation with other Corps of Engineers offices. Most of the new techniques being developed emphasize computational procedures developed specifically for use with electronic computers. Applications of new techniques range from framework studies to planning of day-to-day operation criteria. Studies recently completed or in progress include: (1) development of a regional flood control site screening plan for the North Atlantic Region study; (2) use of streamflow simulation for planning and operation of the Missouri River mainstem projects; (3) development of an operation plan for the Arkansas-White-Red Rivers Reservoir System; (4) standard project flood and flood frequency estimates for the Colorado River Basin Framework Study; and several other projects which are described in more detail in the following paragraphs. One of the initial efforts in regional analysis was the formulation of procedures for determining standard project flood estimates for southern California coastal streams using generalized criteria. Techniques were developed that were readily adaptable to the computer and which would determine representative unit hydrographs, losses and standard project precipitation for any location in the study area. The resulting standard project flood estimates were consistent with the accuracy required for framework studies; however, they could be refined easily for design studies. As a result of the recent drought in the Northeastern United States, a study was made to evaluate both present and future water supply reservoirs in that region. The study consisted of computerized studies of the hypothetical operation of a large number of reservoirs as a system. The reservoirs were on many different streams throughout the region and had varying constraints, depending upon the stream and the state in which the reservoir was located. Since only preliminary data was available on the proposed reservoirs, it was not possible to refine the studies to a large degree. However, the models of each system can be easily refined as more accurate design data become available. The development of a computer-aided screening procedure for use in evaluating several hundred potential reservoir sites for the Missouri River Basin Comprehensive Framework Study is a third example of regional analysis. The adopted procedures used available physical, hydrologic, and climatologic data in estimating reservoir storage requirements throughout the basin. Because the procedure is based upon the techniques often used in more refined studies, it is expected that the results of the screening study will be very useful in future planning and design work. Shortcomings of some of the traditional techniques have helped in the development of new techniques. For maximum usefulness the new techniques should: (1) be consistent with the scope, objectives, and requirements of the overall study; (2) use all available physical, hydrologic, and climatologic data without requiring extensive data which may not be available; (3) take full advantage of the capabilities of the computer and associated data processing systems; and (4) produce results which form a firm basis for future, more detailed, planning and design studies instead of being limited in usefulness largely to the study at hand.     

Pesticide residues in fruits and vegetables in Ghana: a review

Pesticides are known to improve agriculture yield considerably leading to an increase in its application over the years. The use of pesticides has shown varying detrimental effects in humans as well as the environment. Presently, enough evidence is available to suggest their misuse and overuse in the last few decades in most developing nations primarily due to lack of education, endangering the lives of farmers as well as the entire population and environment. However, there is paucity of data especially over long durations in Ghana resulting in the absence of effective monitoring programs regarding pesticide application and subsequent contamination in fruits and vegetables. Therefore, this review discusses comprehensively pesticide type and use, importation, presence in fruits and vegetables, human exposure, and poisoning in Ghana. This is to alert the scientific community in Ghana of the need to further research into the potential implications of pesticide residues in food commodities in order to generate a comprehensive and reliable database which is key in drafting policies simultaneous with food regulation, suitable monitoring initiatives, assessment, and education to minimize their effects thereon.