Arsenaufnahme von Wildpflanzen auf einem kampfstoffkontaminierten Rüstungsaltlastenstandort

The risk assessment of former ammunition factories, where chemical weapons consisting of diphenylarsenic compounds have been produced or stored is difficult because of the lack of data concerning bioavailability and metabolism of the residues of these sternutators. In order to estimate the contamination of fodder plants by typical pollutants of the former Heeresmunitionsanstalt Löcknitz, the total concentration of arsenic was determined in 186 samples of wild plants. The total arsenic concentration in plants of high feed value did not exceed 1 ppm, whereas 15% of the samples of plants of middle and little value in regard to animal fodder showed arsenic concentrations above 1ppm. The uptake of arsenic by wild plants, however, appears to be comparably low taken the high-grade contamination of the soil into account. A final toxicological evaluation of the risk potential is not yet possible because it requires the characterization of the anorganic and organic arsenic compounds in these plants.     

PAHs in the urban air of Sarajevo: levels,sources, day/night variation,and human inhalation risk

Polycyclic aromatic hydrocarbons (PAHs) are organic pollutants derived from pyrolysis and pyrosynthesis processes. Industrial activity, motor vehicle emission, and domestic combustion are the main sources of PAHs in the urban atmosphere. In this work, samples collected during the day and night in the urban area of Sarajevo are analyzed separately for gaseous and particle-bound PAHs; the possible origin of PAHs at the receptor site was suggested using different methods applied to the solid phase and to the total PAHs (gaseous + particulate phase). Finally, the risk level in Sarajevo associated to the carcinogenic character of the studied PAHs has been assessed. The result of this study suggests that (a) the total PAH concentrations were higher than those reported in other European cities; (b) the PAH daytime concentrations are higher than nocturnal concentrations: the sum of the PAH day/night ratios is 1.52 (gas) and 1.45 (particle phase); (c) stationary combustion and traffic were suggested to be the main sources of PAHs; (d) the average particle-bound benzo(a)pyrene (BaP) concentration (5.4 ng/m³) is higher than EU target annual value (1 ng/m³); and (e) PAH cancer risk exceeds the carcinogenic benchmark level recommended by the EPA mainly due to BaP during both the day and night periods.     

Trust,but verify: social media models for disaster management

A lack of trust in the information exchanged via social media may significantly hinder decisionmaking by community members and emergency services during disasters. The need for timely information at such times, though, challenges traditional ways of establishing trust. This paper, building on a multi‐year research project that combined social media data analysis and participant observation within an emergency management organisation and in‐depth engagement with stakeholders across the sector, pinpoints and examines assumptions governing trust and trusting relationships in social media disaster management. It assesses three models for using social media in disaster management—information gathering, quasi‐journalistic verification, and crowdsourcing—in relation to the guardianship of trust to highlight the verification process for content and source and to identify the role of power and responsibilities. The conclusions contain important implications for emergency management organisations seeking to enhance their mechanisms for incorporating user‐generated information from social media sources in their disaster response efforts.     

A Top-Down Regional Assessment of Urban Greenhouse Gas Emissions in Europe

This paper provides an account of urban greenhouse gas (GHG) emissions from 40 countries in Europe and examines covariates of emissions levels. We use a “top-down” analysis of emissions as spatially reported in the Emission Dataset for Global Atmospheric Research supplemented by Carbon Monitoring for Action from 1153 European cities larger than 50 000 population in 2000 (comprising >81 % of the total European urban population). Urban areas are defined spatially and demographically by the Global Rural Urban Mapping Project. We compare these results with “bottom-up” carbon accounting method results for cities in the region. Our results suggest that direct (Scopes 1 and 2) GHG emissions from urban areas range between 44 and 54 % of total anthropogenic emissions for the region. While individual urban GHG footprints vary from bottom-up studies, both the mean differences and the regional energy-related GHG emission share support previous findings. Correlation analysis indicates that the urban GHG emissions in Europe are mainly influenced by population size, density, and income and not by biophysical conditions. We argue that these data and methods of analysis are best used at the regional or higher scales.     

Towards a renewed research agenda in ecotoxicology

New concerns about biodiversity, ecosystem services and human health triggered several new regulations increasing the need for sound ecotoxicological risk assessment. The PEER network aims to share its view on the research issues that this challenges. PEER scientists call for an improved biologically relevant exposure assessment. They promote comprehensive effect assessment at several biological levels. Biological traits should be used for Environmental risk assessment (ERA) as promising tools to better understand relationships between structure and functioning of ecosystems. The use of modern high throughput methods could also enhance the amount of data for a better risk assessment. Improved models coping with multiple stressors or biological levels are necessary to answer for a more scientifically based risk assessment. Those methods must be embedded within life cycle analysis or economical models for efficient regulations. Joint research programmes involving humanities with ecological sciences should be developed for a sound risk management.     

Neutral poly- and perfluoroalkyl substances in air and seawater of the North Sea

Concentrations of neutral poly- and perfluoroalkyl substances (PFASs), such as fluorotelomer alcohols (FTOHs), perfluoroalkane sulfonamides (FASAs), perfluoroalkane sufonamidoethanols (FASEs), and fluorotelomer acrylates (FTACs), have been simultaneously determined in surface seawater and the atmosphere of the North Sea. Seawater and air samples were taken aboard the German research vessel Heincke on the cruise 303 from 15 to 24 May 2009. The concentrations of FTOHs, FASAs, FASEs, and FTACs in the dissolved phase were 2.6–74, <0.1–19, <0.1–63, and <1.0–9.0 pg L^?1, respectively. The highest concentrations were determined in the estuary of the Weser and Elbe rivers and a decreasing concentration profile appeared with increasing distance from the coast toward the central part of the North Sea. Gaseous FTOHs, FASAs, FASEs, and FTACs were in the range of 36–126, 3.1–26, 3.7–19, and 0.8–5.6 pg m^?3, which were consistent with the concentrations determined in 2007 in the North Sea, and approximately five times lower than those reported for an urban area of Northern Germany. These results suggested continuous continental emissions of neutral PFASs followed by transport toward the marine environment. Air–seawater gas exchanges of neutral PFASs were estimated using fugacity ratios and the two-film resistance model based upon paired air–seawater concentrations and estimated Henry's law constant values. Volatilization dominated for all neutral PFASs in the North Sea. The air–seawater gas exchange fluxes were in the range of 2.5?×?10³–3.6?×?10⁵ pg m^?2 for FTOHs, 1.8?×?10²–1.0?×?10⁵ pg m^?2 for FASAs, 1.1?×?10²–3.0?×?10⁵ pg m^?2 for FASEs and 6.3?×?10²–2.0?×?10⁴ pg m^?2 for FTACs, respectively. These results suggest that the air–seawater gas exchange is an important process that intervenes in the transport and fate for neutral PFASs in the marine environment.     

Using radon-222 as indicator for the evaluation of the efficiency of groundwater remediation by in situ air sparging

A common approach for remediation of groundwater contamination with volatile organic compounds (VOCs) is contaminant stripping by means of in situ air sparging (IAS). For VOC stripping, pressurized air is injected into the contaminated groundwater volume, followed by the extraction of the contaminant-loaded exhaust gas from the vadose soil zone and its immediate on-site treatment. Progress assessment of such remediation measure necessitates information (i) on the spatial range of the IAS influence and (ii) on temporal variations of the IAS efficiency. In the present study it was shown that the naturally occurring noble gas radon can be used as suitable environmental tracer for achieving the related spatial and temporal information. Due to the distinct water/air partitioning behaviour of radon and due to its straightforward on-site detectability, the radon distribution pattern in the groundwater can be used as appropriate measure for assessing the progression of an IAS measure as a function of space and time. The presented paper discusses both the theoretical background of the approach and the results of an IAS treatment accomplished at a VOC contaminated site lasting six months, during which radon was applied as efficiency indicator.     

The varying roles of the dimensions of affluence in air pollution: a regional STIRPAT analysis for Germany

Environmental Science and Pollution Research - STIRPAT models investigate the impacts of population, affluence, and technology on the environment, with most STIRPAT studies revealing positive...     

Factorial validity of the Maslach burnout inventory—Dutch version (MBI‐NL) among dentists

Burnout is considered to be a long‐term reaction to occupational stress. It is characterized by emotional exhaustion, depersonalization, and diminished personal accomplishment. The most widely used instrument to measure burnout is the Maslach Burnout Inventory (MBI), developed by Maslach and Jackson (1986). From this instrument, Schaufeli and van Dierendonck (1995a) developed a somewhat modified Dutch version: the MBI‐NL. Burnout among dentists has hardly been studied. Since the professions that the MBI‐NL was developed upon are quite different from dentistry, the aim of this study was to test the three‐factor structure of the MBI‐NL against alternative structures among dentists. Both principal components analysis (PCA) and confirmatory factor analysis (CFA) were examined in a representative sample of 709 Dutch general dental practitioners (75 per cent response rate). The three‐factor structure shows the best fit to the underlying data, while other psychometric qualities are very satisfactory. It is concluded that the three‐factor structure of the MBI‐NL is superior to alternative structures, and that the MBI‐NL is a highly suitable instrument to measure burnout among dentists. Copyright © 1999 John Wiley & Sons, Ltd.     

Concentrations of polybrominated diphenyl ethers, organochlorine compounds and nitro musks in mother's milk from Germany (Bavaria)

The aim of this study was to determine a new spectrum of substances that will be selected for future breast milk monitoring in Bavaria, Germany. Up to now, the analysis of breast milk in Bavaria was limited to selected organochlorine pesticides (OCP) and polychlorinated biphenyls (PCB). Information on background levels of toxicologically interesting substances, such as dioxins and dioxin-like polychlorinated biphenyls (dl-PCB) or on flame retardants, such as polybrominated diphenyl ethers (PBDE) are very limited or not available for Bavaria. We present here levels on OCP, some nitro musks, indicator PCB, polychlorinated dibenzo-p-dioxins (PCDD), polychlorinated dibenzofurans (PCDF) and dl-PCB concentrations in breast milk collected at 12 weeks post-partum of 43 primiparous mothers living in Bavaria. The average concentrations of PCDD, PCDF and dl-PCB were 4.98, 4.93 and 9.92 pg WHO-TEQ g(-1) lipid, respectively. The mean contribution of PCDD, PCDF, non-ortho and mono-ortho PCB to the total WHO-TEQ is consistently about 25% each. Furthermore the concentration on PBDE in breast milk at two sampling points, 12 weeks and 16 weeks after delivery, were determined. Overall, 19 PBDE congeners were analysed, however the level of 12 PBDE congeners were below the limit of detection. BDE-153 and BDE-47 were the predominant congeners accounting for about 66% of the total PBDE. The means of the total concentrations of PBDE (five congeners) at the first and second sampling point were 1.90 and 2.03 ng g(-1) lipid, respectively. Based on our results the overall concentrations of the analysed substances in milk samples from Bavaria are consistent with the levels of breast milk samples of other European countries reflecting the low background body burden of these compounds.