Characterization of hard- and softwood biochars pyrolyzed at high temperature

A wide range of waste biomass/waste wood feedstocks abundantly available at mine sites provide the opportunity to produce biochars for cost-effective improvement of mine tailings and contaminated land at metal mines. In the present study, soft- and hardwood biochars derived from pine and jarrah woods at high temperature (700 °C) were characterized for their physiochemical properties including chemical components, electrical conductivity, pH, zeta potential, cation-exchange capacity (CEC), alkalinity, BET surface area and surface morphology. Evaluating and comparing these characteristics with available data from the literature have affirmed the strong dictation of precursor type on the physiochemical properties of the biochars. The pine and jarrah wood feedstocks are mainly different in their proportions of cellulose, hemicellulose and lignin, resulting in biochars with heterogeneous physiochemical properties. The hardwood jarrah biochar exhibits much higher microporosity, alkalinity and electrostatic capacity than the softwood pine. Correlation analysis and principal component analysis also show a good correlation between CEC–BET–alkalinity, and alkalinity–ash content. These comprehensive characterization and analysis results on biochars’ properties from feedstocks of hardwood (from forest land clearance at mine construction) and waste pine wood (from mining operations) will provide a good guide for tailoring biochar functionalities for remediating metal mine tailings. The relatively inert high-temperature biochars can be stored for a long term at mine closure after decades of operations.     

A study on the arsenic concentration in groundwater of a coastal aquifer in south-east India: an integrated approach

The occurrence of arsenic in drinking water and its detrimental effects have drawn much attention in recent years. Several studies have been conducted in the deltaic plains of River Ganga, NE part of the India, and in other countries, but no systematic study was conducted in South India on occurrence of arsenic in groundwater. The main aim of this study is to determine the level of arsenic in groundwater and to understand the relation with other geochemical parameters of groundwater in the south-eastern coastal aquifer at Kalpakkam region, India. This region is represented by three different lithologies, viz. charnockites, flood plain alluvium and marine alluvium. Twenty-nine representative samples of groundwater were collected and analysed for major ions, metals and isotopes such as ²H and ¹⁸O. In addition, geophysical method was also attempted to understand the subsurface condition. The spatial variation in arsenic (As) indicates that higher concentration was observed around the landfill sites and irrigated regions, which was supported by geochemical, statistical and isotopic inferences. The variation in the As with depth, lithology and sources has been clearly brought out. Though the values of As does not exceed the drinking water permissible limit (10 mg/l), it has reached a near permissible level of 8.7 ppb. Hence, it is essential to understand the geochemical behaviour of As for a proper future management of the water resource in the study area.     

Effect of rise in spring air temperature on the arrival dates and reproductive success of the Song Thrush, <Emphasis Type="Italic">Turdus philomelos</Emphasis> (C.L. Brehm, 1831) in the forest–steppe of the Russian Plain

The effect of rise in spring air temperature on the breeding phenology and reproductive success of the Song Thrush in the Voronezh Nature Reserve have been studied over the periods of 1987 to 1990 and 2008 to 2012. The results show that relatively high air temperatures provide for earlier arrival of the birds from wintering grounds, earlier and more synchronous breeding of the majority of nesting pairs, and an increase in clutch size and proportion of pairs producing two broods per season. Predation pressure on bird nests decreases under such conditions, which markedly improves reproductive success. Climate warming is conducive to increasing breeding productivity of the Song Thrush population as a whole.     

Effect of temperature and precipitation on linear increment of <Emphasis Type="Italic">Sphagnum fuscum</Emphasis> and <Emphasis Type="Italic">S. magellanicum</Emphasis> in Western Siberia

The linear increment of Sphagnum fuscum and S. magellanicum in ombrotrophic mires of Western Siberia has been measured during two years over a transect about 2500 km long extending from forest–steppe to forest–tundra. Along the latitudinal gradient, the increment of both species has proved to be correlated with annual average air temperature and, in S. magellanicum, also with annual precipitation. The determinants of their growth differ between the southern, central, and northern parts of the study region. At the regional level, the annual and summer precipitation plays a more important role than the average air temperature. The increment of S. fuscum in the southern part is positively correlated with the amount of precipitation and negatively correlated with summer temperature, whereas the situation in the central part is inverse. In S. magellanicum, the linear increment is directly dependent on the annual average temperature and annual and summer precipitation in the south and on the annual and summer precipitation in the north of Western Siberia. The dynamics of linear growth of both species in bog pine forests during the growing season are similar: its rate is the highest in June, when the linear increment of S. fuscum and S. magellanicum amounts to 60 and 85% of the annual total, respectively.     

Dynamic trends of heavy metal contents in plants and soil under different industrial air pollution regimes

Based on 30-year monitoring of Ni²⁺ and Cu²⁺ concentrations in the organic horizon of Albic Rustic Podzols and the foliage of six plant species, a dynamic trend in the level of heavy metal accumulation in the components of forest ecosystems of the Kola Peninsula has been revealed against the background of five- to eightfold reduction of pollutant emissions. The direction of the trend has been found to differ: the size of polluted area and pollution level increase with time, while the concentrations of heavy metals in plants decrease due to reduction in their input from the polluted air.     

Influence of experimental conditions on manifestation of the group effect in the gypsy moth, <Emphasis Type="Italic">Lymantria dispar</Emphasis> L.

The effect of rearing conditions for gypsy moth larvae on parameters of their development (its duration and mortality) was studied in experiments with early instar larvae reared singly or in groups. The manifestation of the group effect was analyzed depending on the choice of experimental unit (the larva or the rearing container) and the amount of volume per larva. The observed effects were evaluated quantitatively.