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511.
512.
Solorzano-Ochoa G de la Rosa DA Maiz-Larralde P Gullett BK Tabor DG Touati A Wyrzykowska-Ceradini B Fiedler H Abel T Carroll WF 《Chemosphere》2012,87(9):1003-1008
Open burning for waste disposal is, in many countries, the dominant source of polychlorinated dibenzodioxins, dibenzofurans and biphenyls (PCDD/PCDF/PCB) release to the environment. To generate emission factors for open burning, experimental pile burns of about 100 kg of household waste were conducted with emissions sampling. From these experiments and others conducted by the same authors it is found that less compaction of waste or active mixing during the fire - “stirring” - promotes better combustion (as evidenced by lower CO/CO2 ratio) and reduces emissions of PCDD/PCDF/PCB; an intuitive but previously undemonstrated result. These experiments also support previous results suggesting PCDD/PCDF/PCB generation in open burning - while still highly variable - tends to be greater in the later (smoldering) phases of burning when the CO/CO2 ratio increases. 相似文献
513.
Sholtz RI McLaughlin KR Cirillo PM Petreas M Park JS Wolff MS Factor-Litvak P Eskenazi B Krigbaum N Cohn BA 《Environment international》2011,37(4):709-714
Conserving irreplaceable, archived serum samples may sometimes conflict with the objective of minimizing measurement error due to laboratory effects. We sought to determine whether we could successfully combine assay results for DDT-related compounds and polychlorinated biphenyls (PCBs) in serum from the same birth cohort obtained from different laboratories over time. Using the Child Health and Development Studies (CHDS) serum archive, we compared variability for assays of a quality control pool to variability for assays of subject serum. The quality control pool was created from native archived serum samples that were pooled, then aliquoted, blinded and inserted pair-wise into assay batches along with the subject serum for 5 studies using CHDS samples conducted over a 13year period by three different laboratories. We found that the variability between laboratory and over time within laboratory was small relative to inter-individual variability for p,p'-DDT (1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane), p,p'-DDE (1,1'-dichloro-2,2'-bis(p-chlorophenyl)ethylene) and o,p'-DDT (1,1,1-trichloro-2-(p-chlorophenyl)-2-(o-chlorophenyl)-ethane). Results were also consistent for most PCB congeners which were detectable in 85% or more of samples. Our results suggest that it is possible to combine assays for DDT and PCB congeners measured at positive levels as they are accumulated for cohort subjects without risking meaningful misclassification due to variation stemming from laboratory or time period. This has significant implications for future study costs, conservation of irreplaceable archived samples and for leveraging past investments for future research. For PCB congeners with very low levels, findings caution against pooling of assays without further exploration. 相似文献
514.
Kochy K. Fung Barbara J. Wright 《Journal of the Air & Waste Management Association (1995)》2013,63(7):819-821
The original Texas Intersection Model (TEXIN) for air quality near street intersections has been widely adopted across the nation. At the request of transportation agencies from several states, the TEXIN model was revised to improve its performance and flexibility. The new capabilities include T-intersections, one-way streets, four-way stops, inspection/maintenance capabilities, anti-tampering programs and a short-cut emissions algorithm. TEXIN2 uses the CMA procedures for estimating traffic flow parameters, MOBILE3 to determine free flowing traffic cruise emissions, and CALINE3 to model the pollutant distribution downwind of an intersection. The new model, TEXIN2, offers the user more accurate simulations with enhanced versatility while still requiring a minimal amount of input data. 相似文献
515.
Barbara L. Durso Joe G. Moore Jr. Jerry W. Crowder 《Journal of the Air & Waste Management Association (1995)》2013,63(4):386-387
ABSTRACT This study utilized a biotrickling filter with blast-furnace slag packings (sizes = 20-40 mm; specific surface area = 120 m2/m3) to treat toluene in an air stream. Also studied were the effects of volumetric loading (L), nutrient addition, and superficial gas velocity (Ug) or gas retention time on toluene elimination capacity. Experimental results indicate that, for a test period of 121 days, with no excess biomass removal, toluene removal efficiencies of over 90% were obtained with Ug < 80 m/hr and L < 30 g/m3.hr. For a test period of 49 days, with Ug < 80 m/hr and L increased from 1.2 to 81 g/m3.hr, the absence of nutrient supplementation did not limit the toluene elimination capacity. Nutrients stored in the biofilm could adequately support the microbial activity for the toluene elimination. According to data regression, a simplified mass-transfer model is proposed, which correlates the contaminant concentration with the packing height or gas empty bed retention time. As verified, the model proposed herein can be applied to cases involving low influent contaminant concentrations or loadings to the extent that none or only a trace amount of the contaminant can be found in the recirculation liquid. Although small media with larger specific surface areas can achieve a better mass transfer, the problems of frequent backwashing and relatively greater gas resistance in using this type of media probably outweigh the advantages, particularly for full-scale systems that would not be watched as closely as laboratory test systems. 相似文献
516.
Peter A. Scheff Richard A. Wadden Barbara A. Bates Paul F. Aronian 《Journal of the Air & Waste Management Association (1995)》2013,63(4):469-478
The development of receptor models for the determination of the sources of an ambient air pollutant requires that the composition of the pollutant at the point of emission be known. For this study, composition information for 10 sources of volatile organic compounds (VOC) were evaluated and source fingerprints developed. The source categories include motor vehicles, gasoline vapor, petroleum refineries, architectural coatings, graphic arts, waste-water treatment, vapor degreasing, drycleaning, automobile assembly (including body painting), and polyethylene production. The fingerprints are presented for a group of 23 compounds. These compounds were selected for a variety of reasons including ease of measurement in the ambient environment, compound toxicity, reactivity, and usefulness in previous receptor modeling applications. In general, the data for sources of VOC are remarkably consistent from study to study. Because the profiles for many of the sources of VOC are controlled by physical and chemical processes (e.g. combustion) and not raw material composition, the fingerprints have general applicability. 相似文献
517.
Alla Zelenyuk Michael J. Ezell Véronique Perraud Stanley N. Johnson Emily A. Bruns Yong Yu Dan Imre M. Liz Alexander Barbara J. Finlayson-Pitts 《Atmospheric environment (Oxford, England : 1994)》2010,44(9):1209-1218
The photooxidation of α-pinene in the presence of NO2, with and without added NaNO3 seed particles, has been studied in a large-diameter flow tube. Particles formed by homogeneous nucleation and by condensation on the pre-existing seeds were sampled at various stages of the reaction, dried using four diffusion dryers, size selected at different mobility diameters (dm) using a differential mobility analyzer (DMA), and characterized with a single particle mass spectrometer (SPLAT II). It was found that homogeneously nucleated particles are spherical, have a density (ρ) of 1.25 ± 0.02 g cm?3 (±2σ) and contain a significant amount of organic nitrates. The mass spectra of the low volatility products condensed on the NaNO3 seed particles were found to be virtually the same as in the case of homogeneous nucleation. The data show that the presence of even a submonolayer of organics on the NaNO3 particles causes water retention that leads to a decrease in particle density and that the amount of water retained increases with organic coating thickness. Thicker coatings appear to inhibit water evaporation from the particle seeds altogether. This suggests that in the atmosphere, where low volatility organics are plentiful, some hygroscopic salts will retain water and have different densities and refractive indices than expected in the absence of the organic coating. This water retention combined with the organic shell on the particles can potentially impact light scattering by these particles and activity as cloud condensation nuclei (CCN), as well as heterogeneous chemistry and photochemistry on the particles. 相似文献
518.
Shar Samy Lynn R. Mazzoleni Subhashree Mishra Barbara Zielinska Anna G. Hallar 《Atmospheric environment (Oxford, England : 1994)》2010,44(13):1663-1671
Water extracts of atmospheric particulate matter (PM2.5) collected at the Storm Peak Laboratory (SPL) (3210 MSL, 40.45° N, 106.74° W) were analyzed for a wide variety of polar organic compounds. The unique geographical character of SPL allows for extended observations/sampling of the free tropospheric interface. Under variable meteorological conditions between January 9th and January14th 2007, the most abundant compounds were levoglucosan (9–72 ng m?3), palmitic acid (10–40 ng m?3) and succinic acid (18–27 ng m?3). Of 84 analytes included in the GC–MS method, over 50 individual water extractable polar organic compounds (POC) were present at concentrations greater than 0.1 ng m?3. During a snow event (Jan. 11th–13th), the concentrations of several presumed atmospheric transformation compounds (dicarboxylic acids) were reduced. Lower actinic flux, reduced transport distance, and ice crystal scavenging may explain this variability. Diurnal averages over the sampling period revealed a higher total concentration of water extractable POC at night, 211 ng m?3 (105–265 ng m?3), versus day, 160 ng m?3 (137–205 ng m?3), which suggests a more aged nighttime aerosol character. This may be due to the increased daytime convective mixing of local primary emissions from the Yampa Valley. XAD resin extracts revealed a gas-phase partitioning of several compounds, and analysis of cloud water collected at this site in 2002 revealed a similar compound abundance trend. Levoglucosan, a wood smoke tracer was generally found to be the most abundant compound in both aerosol and cloud water samples. Variations in meteorological parameters and local/regional transport analysis play an important interpretive role in understanding these results. 相似文献
519.
Isabelle Coll Cécile Rousseau Barbara Barletta Simone Meinardi Donald R. Blake 《Atmospheric environment (Oxford, England : 1994)》2010,44(31):3843-3855
This paper presents an evaluation of the consistency of an urban state-of-the-art hydrocarbon (HC) emission inventory. The evaluation was conducted through the comparison of this inventory with hourly HC measurements during two summer months in the centre of Marseille, on the Mediterranean French coast. Factors of under or overestimation could be calculated for each compound on the basis of a systematic HC to HC ratio analysis. These results, associated with a deep analysis of the speciation profiles, show that most of the common and highly concentrated hydrocarbons (such as butanes) are too much predominant in the emission speciation, while the heavy and less common species (branched alkanes, substituted aromatics) are under-represented in the inventory. The urban diffuse sources appear here as one critical point of the inventories. The disagreements were shown to have a strong incidence on the representation of the air mass reactivity. In a last step, the identified uncertainties in emissions were implemented in an air-quality model for sensitivity studies. It was shown that the observed biases in the inventory could affect the regional ozone production, with a probable impact on ozone peaks of 2–10 ppbv over the area. 相似文献
520.
Occurrence and toxicity of antimicrobial triclosan and by-products in the environment 总被引:1,自引:0,他引:1
Bedoux G Roig B Thomas O Dupont V Le Bot B 《Environmental science and pollution research international》2012,19(4):1044-1065